The Activation of Dioxygen and Homogeneous Catalytic Oxidation

Front Matter....Pages N1-xv
Introduction: The Dilemmas of O 2 and Hooh Activation....Pages 1-7
A History of Oxygen Activation: 1773–1993....Pages 9-30
Industrial Perspectives on the use of Dioxygen: New Technology to Solve Old Problems....Pages 31-44
Metal Phosphates: New Vistas for Catalysed Oxidations with Hydrogen Peroxide....Pages 45-56
The Destruction of Toxic Aqueous Organic Compounds by H 2 O 2 /Fe ++ /UV/O 2 ....Pages 57-70
Homogeneous Catalyzed Selective Oxidations Based on O 2 or H 2 O 2 . New Systems and Fundamental Studies....Pages 71-83
Electropox: BP’s Novel Oxidation Technology....Pages 85-96
Kinetics of Reaction of Dioxygen with Lithium Nickel Oxide, and the Role of Surface Oxygen in Oxidative Coupling of Methane....Pages 97-114
Oxidation of Olefins to Aldehydes Using a Palladium-Copper Catalyst....Pages 115-122
New Metal Complex Oxygen Absorbents for the Recovery of Oxygen....Pages 123-131
Oxygenation of Olefins with Molecular Oxygen Catalyzed by Low Valent Metal Complexes....Pages 133-146
Formation and Alkene Epoxidation by Higher-Valent Oxo-Metalloporphyrins....Pages 147-169
Models for Horseradish Peroxidase Compound II: Phenol Oxidation with Oxoiron(IV) Porphyrins....Pages 171-182
Non-Porphyrin Iron Complex-Catalyzed Epoxidation of Olefins....Pages 183-198
Bioinspired Catalysis: Hydroperoxidation of Alkylaromatics....Pages 199-208
Mechanism of Dioxygen Addition to Nickel-Bound Thiolates....Pages 209-223
Studies on the Mechanism of Gif Reactions....Pages 225-242
Cyclohexane Oxidation: Can Gif Chemistry Substitute for the Classical Process ?....Pages 243-255
Catalytic Chemistry of Cytochrome P450 and Peroxidases....Pages 257-266
Oxygen-Derived Toxins Generated by Neutrophils and their Microbicidal Mechanisms....Pages 267-286
Metalloporphyrins as Biomimetic Oxidants and Synthetic Ligninases....Pages 287-300
Methane Monooxygenase: Models and Mechanism....Pages 301-320
Alkane Functionalization at Nonheme Iron Centers: Mechanistic Insights....Pages 321-331
Characterization of Page Bands from 3′-Labeled Short DNA Fragments Resulting from Oxidative Cleavage by “Mn-TMPyP/KHSO 5 ”. Drastic Modifications of Band Migrations by 5′-End Sugar Residues....Pages 333-346
New Model Systems for Oxygenases....Pages 347-358
Oxygen Activation by Transition Metal Complexes of Macrobicyclic Cyclidene Ligands....Pages 359-380
Dioxygen Reactivity Models for Cytochrome C Oxidase: Synthesis and Characterization of Oxo and Hydroxo-Bridged Porphyrin-Iron/Copper Dinuclear Complexes....Pages 381-394
Mechanistic Aspects of O 2 -Activation on Nickel(II) Tetrahydrosalen Complexes....Pages 395-409
Singlet Oxygen Dimol-Sensitized Luminescence and Reactions of Singlet Oxygen with Organometallics....Pages 411-422
Evidences for Substrate Activation of Copper Catalyzed Intradiol Cleavage in Catechols....Pages 423-436
Catalytic, Aerobic Oxygenations with Metalloporphyrin Catalysts. New Structural Insights into Stereoselectivity....Pages 437-438
Front Matter....Pages 439-439
Cobalt Bromide Catalysis of the Oxidation of Organic Compounds....Pages 441-441
Homogeneous Catalytic Oxidation of Organic Substrates by Copper-Pyrazolato Complexes....Pages 442-442
Dioxygen Ligand Transfer from Platinum to Molybdenum. Isolation of a Highly Reactive Molybdenum(VI) Oxoperoxo Dimer....Pages 443-443
Copper Imidazole Complexes Catalyze the Oxidative Polymerization of 2,6-Dimethylphenol with Dioxygen....Pages 444-444
Activation of Dioxygen by Chromium and Cobalt Complexes....Pages 445-445
Formation of Isoxazolines and Isoxazoles Via Dipolar Cycloaddition by Catalytic Oxidation of Aldoximes with Hydrogen Peroxide and W(Vi) Peroxo Complexes....Pages 446-446
Oxidation of Amines and Imines by Mo(VI) and W(VI) Peroxopolyoxo Complexes....Pages 447-447
Gif Chemistry....Pages 448-448
Oxidation of Cyclohexane Catalyzed by Polyhalogenated and Perhalogenated Iron Porphyrins....Pages 449-449
Front Matter....Pages 439-439
New Oxidations of Organic Substrates Using Hydrogen Peroxide and Supported Heteropolyacid Catalysts....Pages 450-450
Polymer Bound Manganese Porphyrin Catalysts for Olefin Epoxidations with Hydrogen Peroxide....Pages 451-451
Olefin Epoxidation by PH 4 PHSO 5 Catalyzed by Mn(III)-Porphyrins Under Homogeneous Conditions....Pages 452-452
Synthesis and Electrochemistry of Diaquaruthenium(II) and Diaquairon(II) Complexes of Quaterpyridines and X-Ray Crystal Structures of [Ru(pQP)PPh 3 ) 2 ](ClO 4 ) 2 , [Fe(pQP)(H 2 O)](ClO 4 ) 2 , and [Fe(QP)(H 2 O](ClO 4 ) 2 (pQP = 3′ ,5,5′ 5″′ -Tetramethyl-2-2′ :6′ 2″:6″,2″′ -Quaterpyrine; QP = 2,2′ :6′ ,2′ -6″,2′ ″-Quaterpyridine)....Pages 453-453
Oxidation Of H 2 S To S By Air With Fe(III)-NTA As A Catalyst: Catalyst Degradation....Pages 454-454
CrAPO-5-Catalyzed Liquid Phase Oxidation of Secondary Alcohols with O 2 ....Pages 455-455
Solvent Effects on the Oxygenation of Ni-Bound Thiolates....Pages 456-456
Monooxygenatation of Alkanes and Aromatics Catalyzed by Nonheme-Iron Complex/Hydroquinone/O 2 Systems....Pages 457-457
Effects of Sensitizer and Solvent on Singlet Oxygenation of β-Methylstyrenes....Pages 458-458
Heteropolyperoxo Complexes as Catalysts for Organic Oxidations....Pages 459-459
Iron Complexes of Cyclam and Cyclam-Like Ligands as Models for Non-Heme Iron Enzymes....Pages 460-460
Oxygen Activation by 3d Metal Complexes of Open Chain and Macrocyclic Schiff Base Ligands....Pages 461-461
Selective Monoepoxidation of 1,3-Dienes Catalyzed by Transition-Metal Complexes....Pages 462-462
Hydrocarbon Oxidation by a Polynuclear Iron Sandwich Polyoxotungstate - Hydrogen Peroxide System....Pages 463-463
Thianthrene Oxide as a Mechanistic Probe for Bleach Ingredients....Pages 464-464
The Selective Hydroxylation of Cyclohexane by Alkyl Hydroperoxides a Challenge that Can be Solved ?....Pages 465-465
Dioxygen Oxidation by the Metal-Immobilized Catalyst Derived from Silica and Montmorillonite Modified by Silane Coupling Reagent....Pages 466-466
Biomimetic Oxidation of Cyclohexane Using the Gif-Krict System....Pages 467-467
Non-Symmetric Dinucleating Ligands for Oxidation Catalysts Templates for Realistic Dinuclear Metalloenzyme Mimics....Pages 468-468
Binuclear Cobalt(II) Complexes of Macrocyclic and Macrobicyclic Ligands as Oxygen Carriers....Pages 469-469
Front Matter....Pages 439-439
Reactions of KMnO 4 with Various Schiff Base Ligands in Aprotic Solvents....Pages 470-470
Chromium(VI) Oxide Catalyzed Oxidations by Tert -Butylhydroperoxide: Benzylic Oxidation Versus Tert -Butylhydroperoxide Decomposition....Pages 471-471
Cytochrome P-450 Like Substrate Oxidation Catalyzed by Heme-Undecapeptide, Microperoxidase-11....Pages 472-472
Oxidation of Organic Compounds with Molecular Oxygen Catalyzed by Heteropolyoxometallates....Pages 473-473
Thermodynamic and Kinetic Studies to Elucidate the Amoco Co/Mn/Br Autoxidation (‘MC’) Catalyst....Pages 474-474
Iron(III) and Manganese(III) Tetra-Arylporphyrins Catalyze the Oxidation of Primary Aromatic Amines to the Corresponding Nitro Derivatives....Pages 475-475
Stoichiometric and Catalytic Oxidation by a Binuclear Cu(I) Dioxygen Macrocyclic Complex Derived from Pyridine-2,6-Dicarboxaldehyde and Bisdien....Pages 476-476
Fenton Reagents (1:1 Fe II L x /HOOH) React Via [L x Fe II OOH(BH + ), 1] as Hydroxylases (RH → ROH); NOT as Generators of Free Hydroxyl Radicals (HO·)....Pages 477-477
Iron(II)-Induced Generation of Hydrogen Peroxide from Dioxygen; Induction of Fenton Chemistry and the Activation of O 2 for the Ketonization of Hydrocarbons; Fe II (PA) 2 /(t-BuOOH)-Induced Activation of O 2 ....Pages 478-478
The Unique Role of Iron Cations in the Activation of Molecular Oxygen in the Gas Phase....Pages 479-479
Low Temperature Oxidation of p-xylene to Terephthalic Acid....Pages 480-480
Copper(I)/(t-BuOOH)-Induced Activation of Dioxygen for the Ketonization of Methylenic Carbons....Pages 481-481
Enantioselective Lactonization of Cyclic Ketones with H 2 O 2 Catalyzed by Complexes of Platinum(II)....Pages 482-482
Aerobic Oxygenation of Olefins Catalyzed by Transition-Metal Complexes....Pages 483-483
Oxidation of Phenolic Arylalkenes in the Presence of Molecular Oxygen....Pages 484-484
Oxidation of Hydrocarbons by Oxygen and Hydrogen Over Pd-Containing Titanium Silicalites....Pages 485-485
Preparation, Characterization, and Reaction of an Oxo-Fe(V)-Porphyrin Complex....Pages 486-486
Non-Chlorine Bleaching of Wood Pulps Mediated by Heteropolyoxometalates....Pages 487-487
Erratum....Pages 498-498
Back Matter....Pages 489-497