Heterogeneous Catalysis and Fine Chemicals IV

Content: 
Foreword
Page xiii

Scientific committee
Page xv

Organizing committee
Page xv

Financial support
Page xvi

Homogeneous catalysis for fine chemical synthesiss — New trends and perspectives — Original Research Article
Pages 1-16
Matthias Beller

Catalysis for Agrochemicals:The Case History of the Dual® Herbicide Original Research Article
Pages 17-29
Rolf R. Bader, Hans-Ulrich Blaser

Heterogeneous vs. homogeneous catalysis in manufacturing of terbinafine a case study for route selection of an industrial process Original Research Article
Pages 31-35
Ulrich Beutler, Christian Fleury, Peter C. Fünfschilling, Gerhard Penn, Thomas Ryser, Berthold Schenkel

Multiple use of Palladium in a homogeneous and a consecutive heterogeneous catalytic reaction Original Research Article
Pages 37-39
P. Baumeister, W. Meyer, K. Oertle, G. Seifert, U. Siegrist, H. Steiner

The optimization of the catalytic hydrogenation of hydroxybenzamidines to benzamidines Original Research Article
Pages 41-46
Mike G. Scaros, Peter K. Yonan, Scott A. Laneman

Catalytic hydrogenation reactors for the fine chemicals industries. Their design and operation Original Research Article
Pages 47-57
K.R. Westerterp, E.J. Molga, K.B. van Gelder

Selective catalytic hydrogenation of 2-butyne-1,4-diol to cis-2-butene-1,4-diol in mass transfer efficient slurry reactors Original Research Article
Pages 59-66
J.M. Winterbottom, H. Marwan, J. Viladevall, S. Sharma, S. Raymahasay

Replacing liquid acids in fine chemical synthesis by sulfonated polysiloxanes as solid acids and as supports for precious metal catalysts Original Research Article
Pages 67-74
Stefan Wieland, Peter Panster

Amine functions linked to MCM-41-type silicas as a new class of solid base catalysts for condensation reactions Original Research Article
Pages 75-82
M. Laspéras, T. Llorett, L. Chaves, I. Rodriguez, A. Cauvel, D. Brunel

Modified clay catalysts for acylation of crown compounds Original Research Article
Pages 83-89
S. Békássy, K. Biró, T. Cseri, B. Ágai, F. Figueras

Acylation of aromatics over a HBEA zeolite. Effect of solvent and of acylating agent Original Research Article
Pages 91-98
F. Jayat, M.J. Sabater Picot, D. Rohan, M. Guisnet

Zeolite-catalysed acetylation of alkenes with acetic anhydride Original Research Article
Pages 99-106
Keith Smith, Zhao Zhenhua, Lionel Delaude, Philip K.G. Hodgson

Influence of the acidity and of the pore structure of zeolites on the alkylation of toluene by 1-heptene Original Research Article
Pages 107-114
P. Magnoux, A. Mourran, S. Bernard, M. Guisnet

Reductive O- and N-alkylations. Alternative catalytic methods to nucleophilic substitution Original Research Article
Pages 115-122
F. Fache, V. Bethmont, L. Jacquot, F. Valot, A. Milenkovic, Marc Lemaire

N-methylation of aniline over AlPO4 and AlPO4-metal oxide catalysts Original Research Article
Pages 123-130
F.M. Bautista, J.M. Campelo, A. Garcia, D. Luna, J.M. Marinas, A.A. Romero

Preparation of symmetrical and mixed secondary alkylamines over raney nickel and supported copper catalysts Original Research Article
Pages 131-138
L. Göbölös, M. Hegedüs, E. Tálas, J.L. Margitfalvi

Synthesis of dimethylethylamine from ethylamine and methanol over copper catalysts Original Research Article
Pages 139-147
Y. Pouilloux, V. Doidy, S. Hub, J. Kervennal, J. Barrault

Catalyst acid/base properties regulation to control the selectivity in gas-phase methylation of catechol Original Research Article
Pages 149-156
L. Kiwi-Minsker, S. Porchet, R. Doepper, A. Renken

Enantioselective hydrogenation of ethyl pyruvate and isophorone over modified Pt and Pd catalysts Original Research Article
Pages 157-165
Antal Tungler, Karina Fodor, Tibor Máthé, Roger A. Sheldon

Controlling the enantioselective hydrogenation of ethyl pyruvate using zeolites as catalyst support Original Research Article
Pages 167-174
K. Morgenschweis, E. Polkiehn, W. Reschetilowski

Kinetic modeling of the ligand accelerated catalysis in the enantioselective hydrogenation of ethyl pyruvate: Influence of solvents, catalysts and additives Original Research Article
Pages 175-182
H.U. Blaser, D. Imhof, M. Studer

Modeling of kinetically coupled selective hydrogenation reactions: Kinetic rationalization of pressure effects on enantioselectivity Original Research Article
Pages 183-190
Jian Wang, Carl LeBlond, Charles F. Orella, Yongkui Sun, John S. Bradley, Donna G. Blackmond

Enantioselective hydrogenation of (E)-α-phenylcinnamic acid on cinchonidine-modified palladium catalysts: influence of support Original Research Article
Pages 191-198
Y. Nitta, K. Kobiro, Y. Okamoto

Enantio-differentiating hydrogenation of 3-alkanones with asymmetrically modified fine nickel powder Original Research Article
Pages 199-206
Tsutomu Osawa, Tadao Harada, Akira Tai, Osamu Takayasu, Ikuya Matsuura

Diastereoselective hydrogenation of a prostaglandin intermediate over ru supported on different molecular sieves Original Research Article
Pages 207-214
F. Cocu, S. Coman, C. Tnase, D. Macovei, V.I. Pârvulescu

Diastereoselective hydrogenation of substituted aromatics on supported rhodium catalysts: influence of support and of thermal treatment Original Research Article
Pages 215-222
M. Besson, P. Gallezot, C. Pinel, S. Neto

Stereoselective reductions of aromatic compounds Original Research Article
Pages 223-229
Emmanuel Auer, Andreas Freund, Peter Panster, Gernot Stein, Thomas Tacke

Selective reduction of nitro groups in aromatic azo compounds Original Research Article
Pages 231-238
M. Lauwiner, R. Roth, P. Rys, J. Wissmann

Selective catalytic hydrogenation of 2,4-dinitrotoluene to nitroarylhydroxylamines on supported metal catalysts Original Research Article
Pages 239-246
X.G. Musolino, C. Milone, G. Neri, L. Bonaccorsi, R. Pietropaolo, S. Galvagno

Kinetics and pathways of selective hydrogenation of 1-(4-nitrobenzyl)-1,2,4-triazole Original Research Article
Pages 247-254
C. LeBlond, J. Wang, R.D. Larsen, C.J. Orella, A.L. Forman, F.P. Gortsema, T.R. Verhoeven, Y.-K. Sun

Design of selective 1-ethyl-2-nitromethylenepyrrolidine hydrogenation for pharmaceuticals production Original Research Article
Pages 255-262
V.A. Semikolenov, I.L. Simakova, A.V. Golovin, O.A. Burova, N.M. Smirnova

Kinetic study of a nitroaliphatic compound hydrogenation Original Research Article
Pages 263-271
V. Dubois, G. Jannes, P. Verhasselt

Kinetics of the hydrogenation of citral over supported Ni catalyst Original Research Article
Pages 273-280
Päivi Mäki-Arvela, Lasse-Pekka Tiainen, Rivka Gil, Tapio Salmi

Selective hydrogenation of α,β-unsaturated aldehydes to allylic alcohols over supported monometallic and bimetallic Ag catalysts Original Research Article
Pages 281-288
P. Claus, P. Kraak, R. Schödel

Surface organometallic chemistry on metals; selective hydrogenation of acetophenone on modified rhodium catalyst Original Research Article
Pages 289-295
F. Humblot, M.A. Cordonnier, C. Santini, B. Didillon, J.P. Candy, J.M. Basset

Use of Ni containing anionic clay minerals as precursors of catalysts for the hydrogenation of nitriles Original Research Article
Pages 297-304
D. Tichit, F. Medina, R. Durand, C. Mateo, B. Coq, J.E. Sueiras, P. Salagre

The effect of co-adsorbates on activity/selectivity in the hydrogenation of aromatic alkynes Original Research Article
Pages 305-311
S.D. Jackson, H. Hardy, G.J. Kelly, L.A. Shaw

Simple preparation of bimetallic palladium-copper catalysts for selective liquid phase semihydrogenation of functionalized acetylenes and propargylic alcohols Original Research Article
Pages 313-319
M.P.R. Spee, D.M. Grove, G. van Koten, J.W. Geus

Catalytic hydrogenation by polymer stabilized rhodium Original Research Article
Pages 321-328
G.W. Busser, J.G. van Ommen, J.A. Lercher

Epoxidation of cycloalkenones over amorphous titania-silica aerogels Original Research Article
Pages 329-336
R. Hutter, T. Mallat, A. Baiker

Selective aerobic epoxidation of olefins over NaY and NaZSM-5 zeolites containing transition metal ions Original Research Article
Pages 337-344
O.A. Kholdeeva, A.V. Tkachev, V.N. Romannikov, I.V. Khavrutskii, K.I. Zamaraev

Effect of preparation methods of titania/silicas on their catalytic activities in the oxidation of olefins Original Research Article
Pages 345-352
M. Toba, S. Niwa, H. Shimada, F. Mizukami

Heterogeneous catalysts from organometallic precursors: how to design isolated, stable and active sites. Applications to zirconium catalyzed organic reactions Original Research Article
Pages 353-360
A. Choplin, B. Coutant, C. Dubuisson, P. Leyrit, C. McGill, F. Quignard, R. Teisser

Selective sulfoxidation of thioethers on Ti-containing zeolites under mild conditions Original Research Article
Pages 361-368
V. Hulea, P. Moreau, F. Di Renzo

Allylic oxidation of cyclohexene catalysed by metal exchanged zeolite Y Original Research Article
Pages 369-376
O.B. Ryan, D.E. Akporiaye, K.H. Holm, M. Stöcker

Ammoxidation of methylaromatics over NH4+-containing vanadium phosphate catalysts—New mechanistic insights Original Research Article
Pages 377-384
Andreas Martin, Angelika Brückner, Yue Zhang, Bernhard Lücke

Hydrogen peroxide oxidation of methyl α-d-glucopyranoside, sucrose and α,α-trehalose with Ti-MCM-41 Original Research Article
Pages 385-390
E.J.M. Mombarg, S.J.M. Osnabrug, F. van Rantwijk, H. van Bekkum

On the role of bismuth-based alloys in carbon-supported bimetallic Bi-Pd catalysts for the selective oxidation of gluconic acid Original Research Article
Pages 391-398
M. Wenkin, C. Renard, P. Ruiz, B. Delmon, M. Devillers

Selective oxidation of 5-hydroxymethylfurfural to 2,5-furan-dicarboxaldehyde in the presence of titania supported vanadia catalysts Original Research Article
Pages 399-406
C. Moreau, R. Durand, C. Pourcheron, D. Tichit

Dehydrogenation of methoxyisopropanol to methoxyacetone on supported bimetallic Cu-Zn catalysts Original Research Article
Pages 407-414
M.V. Landau, S.B. Kogan, M. Herskowitz

Butadione synthesis by dehydrogenation and oxidative dehydrogenation of 2,3-butanediol Original Research Article
Pages 415-420
G.V. Isagulyants, I.P. Belomestnykh

Phase transition of crystalline α-Te2MoO7 to the vitreous β-form, surface composition, and activity in the vapor-phase selective oxidation of ethyl lactate to pyruvate over TeO2-MoO3 catalysts Original Research Article
Pages 421-428
H. Hayashi, S. Sugiyama, T. Moriga, N. Masaoka, A. Yamamoto

Selective oxidation with air of glyceric to hydroxypyruvic acid and tartronic to mesoxalic acid on PtBi/C catalysts Original Research Article
Pages 429-436
Peter Fordham, Michèle Besson, Pierre Gallezot

PDMS occluded Ti-MCM-41 as an improved olefin epoxidation catalyst Original Research Article
Pages 437-444
Ivo F.J. Vankelecom, Nancy M.F. Moens, Karen A.L. Vercruysse, Rudy F. Parton, Pierre A. Jacobs

Epoxidation with managanese N,N′-bis(2-pyridinecarboxamide) complexes encapsulated in zeolite Y Original Research Article
Pages 445-452
P.P. Knops-Gerrits, M. L\'abbé, P.A. Jacobs

Selective oxidation of benzyl alcohol on a zeolite ship-in-a-bottle complex Original Research Article
Pages 453-459
Á. Zsigmond, F. Notheisz, Z. Fráter, J.E. Bäckvall

Oxidation of pinane using zeolite encapsulated metal phthalocyanine catalysts Original Research Article
Pages 461-468
A.A. Valente, J. Vital

Hydrogenation of carbonyl groups containing compounds over Pt(II)-salen complexes occluded in zeolites Original Research Article
Pages 469-476
W. Kahlen, A. Janssen, W.F. Hölderich

Novel clay intercalated metal catalysts: a study of the hydrogenation of styrene and 1-octene on clay intercalated Pd catalysts Original Research Article
Pages 477-484
Á. Mastalir, F. Notheisz, Z. Király, M. Bartók, I. Dékány

Catalytic enantioselective addition of diethylzinc to benzaldehyde induced by immobilized ephedrine: comparison of silica and MCM-41 type mesoporous silicates as supports Original Research Article
Pages 485-492
N. Bellocq, D. Brunel, M. Laspéras, P. Moreau

The immobilization of sulfonated Ru-BINAP chloride by anion exchange on layered double hydroxides Original Research Article
Pages 493-500
Diedrik Tas, Dominique Jeanmart, Rudy F. Parton, Pierre A. Jacobs

Regiospecific hydrosilylation of styrene by rhodium complexes heterogenised on modified USY-zeolites Original Research Article
Pages 501-507
A. Corma, M. Isabel de Dios, M. Iglesias, F. Sánchez

Polymer-supported Al and Ti species as catalysts for Diels-Alder reactions Original Research Article
Pages 509-516
B. Altava, M.I. Burguete, J.M. Fraile, J.I. García, S.V. Luis, J.A. Mayoral, A.J. Royo, R.V. Salvador

Molecular imprinting polymerised catalytic complexes in asymmetric catalysis Original Research Article
Pages 517-522
F. Locatelli, P. Gamez, M. Lemaire

Environmentally friendly catalysis of liquid phase organic reactions using chemically modified mesoporous materials Original Research Article
Pages 523-530
A.J. Butterworth, J.H. Clark, A. Lambert, D.J. Macquarrie, S.J. Tavener

Meerwein-Ponndorf-Verley and Oppenauer reactions catalysed by heterogeneous catalysts Original Research Article
Pages 531-537
E.J. Creyghton, J. Huskens, J.C. van der Waal, H. van Bekkum

Selective synthesis of monoglycerides from glycerol and oleic acid in the presence of solid catalysts Original Research Article
Pages 539-546
S. Abro, Y. Pouilloux, J. Barrault

Zeolite-catalysed hydrolysis of aromatic amides Original Research Article
Pages 547-554
B. Gigante, C. Santos, M.J. Marcelo-Curto, C. Couranceau, J.M. Silva, F. Alvarez, M. Guisnet, E. Selli, L. Forni

Hydration of α-pinene and camphene over USY zeolites Original Research Article
Pages 555-562
H. Valente, J. Vital

Dehydration of 2-(2-hydroxyethyl)-pyridine to 2-vinyl-pyridine over solid acid catalysts Original Research Article
Pages 563-570
L. Forni, D. Moscotti, E. Selli, I. Belegridi, M. Guisnet, D. Rohan, B. Gigante, C. Coutanceau, J.M. Silva, F. Alvarez

The use of heterogeneous copper catalysts in cyclopropanation reactions Original Research Article
Pages 571-578
J.M. Fraile, B. García, J.I. García, J.A. Mayoral, F. Figueras

Reaction between haloaromatics over a CuHZSM-5 zeolite—Mechanistic Study Original Research Article
Pages 579-586
S. Vol, L. Vivier, G. Pérot

Selective isomerization of α-pinene oxide with heterogeneous catalysts Original Research Article
Pages 587-594
A.T. Liebens, C. Mahaim, W.F. Hölderich

Reactions of 2,2-dimethyl-1,3-propanediol with zeolites: Correlation of selectivity with acidity Original Research Article
Pages 595-601
H.U. Blaser, B. Casagrande, B. Siebenhaar

Clay-catalyzed reactions of imidazole and benzimidazoles with propiolic esters Original Research Article
Pages 603-607
Mária Balogh, Csaba Gönczi, István Hermecz

Selective synthesis of cyclohexylcyclohexanone on bifunctional zeolite catalysts. Influence of the metal and of the pore structure Original Research Article
Pages 609-616
F. Alvarez, A.I. Silva, F. Ramôa Ribeiro, G. Giannetto, M. Guisnet

Solid acid catalyzed disporportionation and alkylation of alkylsilanes Original Research Article
Pages 617-624
T Yamaguchi, T. Yamada, M. Shibata, T. Tsuneki, M. Ookawa

Intramolecular Ene reactions promoted by mixed cogels Original Research Article
Pages 625-632
Nicoletta Ravasio, Marisa Antenori, Francesco Babudri, Michele Gargano

Rh3+ ions and Rh3+ — diamine complexes intercalated in α — and γ — zirconium hydrogen phosphate as stable and effective catalysts for the conversion of aniline or nitrobenzene to carbamates and/or N,N′ — diphenylurea. Part 3. Original Research Article
Pages 633-640
P. Giannoccaro, S. Doronzo, C. Ferragina

1,4-Butanediol conversion routes over bifunctional supported Co-Zn catalyst Original Research Article
Pages 641-648
L. Leite, S. Kruc, Zh. Yuskovets, V. Stonkus, M. Fleisher, E. Lukevics, J. Stoch, M. Mikolayczyk

Preparation of solid superbase catalyst and its application to the synthesis of fine chemicals Original Research Article
Pages 649-656
Gohfu Suzukamo, Masami Fukao, Takuo Hibi, Kozo Tanaka, Masao Minobe

Synthesis of delicious peptide fragments catalyzed by immobilized proteases Original Research Article
Pages 657-664
M.D. Romero, J. Aguado, M.J. Guerra, G. Alvaro, R. Navarro, E. Rubio

Author index
Pages 665-668