Design of Electronic Devices Using Redox-Active Organic Molecules and Their Porous Coordination Networks (Springer Theses)

Supervisor’s Foreword
Abstract
Parts of this paper have been published in the following journal articles.
Acknowledgements
Contents
1 General Introduction
	1.1 Redox-Active Organic Molecule
		1.1.1 Redox (Oxidation–Reduction) Reaction
		1.1.2 Redox-Active Organic Molecules
		1.1.3 Phenalenyl Chemistry
	1.2 Resistive Random Access Memory (ReRAM)
		1.2.1 Conventional Memory Devices
		1.2.2 Resistive RAM (ReRAM or RRAM)
		1.2.3 Structure and General Characteristic of ReRAMs
		1.2.4 Materials and Switching Mechanisms in ReRAMs
	1.3 Redox-Active Porous Coordination Networks (PCNs)
		1.3.1 Role of Redox-Activity in Metal–Ligand Cooperated System
		1.3.2 Redox-Active Ligands
		1.3.3 Porous Coordination Networks
		1.3.4 Ligand-Based Redox-Active PCNs
		1.3.5 Conductive PCNs
		1.3.6 Chemiresistive Sensor Based on PCNs
	1.4 Post-synthetic Modification (PSM) of PCNs
	References
2 Resistive Switching Memory Devices Based on a Redox-Active Organic Molecule
	Abstract
	2.1 Introduction
	2.2 Results and Discussion
		2.2.1 Selective Formation of Redox-Active TPDAP Films
		2.2.2 Current–Voltage (I–V) Characteristics of TPDAPs
		2.2.3 Ex Situ Study of Resistive Switching Memory Devices
		2.2.4 Selective Formation of Redox-Inert TPHAP Films
		2.2.5 Current–Voltage (I–V) Characteristics of TPHAPs
		2.2.6 Switching Mechanism
	2.3 Conclusion
	2.4 Experimental Section
		2.4.1 General Experimental Information
		2.4.2 Syntheses
		2.4.3 Device Fabrication
		2.4.4 X-ray Structure Analysis
	References
3 Chemiresistive Sensor Based on Redox-Active Porous Coordination Networks
	Abstract
	3.1 Introduction
	3.2 Results and Discussion
		3.2.1 Selective Formation of Redox-Active PCNs
		3.2.2 Film Fabrication of Redox-Active PCNs
		3.2.3 Electrical Properties of Redox-Active PCNs
		3.2.4 Chemiresistive Humidity Sensing Ability of Redox-Active PCN
		3.2.5 Mechanism Investigation
	3.3 Conclusion
	3.4 Experimental Section
		3.4.1 General Experimental Information
		3.4.2 Syntheses
		3.4.3 X-Ray Structure Analysis
		3.4.4 Electrical Measurement
	References
4 Tunable Electrical Properties of Redox-Active Porous Coordination Networks via Post-synthetic Modification
	Abstract
	4.1 Introduction
	4.2 Results and Discussion
		4.2.1 Pore Opening of a Redox-Active PCN by PSMs
		4.2.2 Efficient Oxidation of Open Structure After PSMs
		4.2.3 Tunable Electrical Properties via PSMs
	4.3 Conclusion
	4.4 Experimental Section
		4.4.1 General Experimental Information
		4.4.2 Syntheses
		4.4.3 X-Ray Structure Analysis
		4.4.4 Electrical Measurement
	References
5 Summary and Outlook
	5.1 Summary
	5.2 Limitations and Future Work
	References