Catalytic Olefin Polymerization, Proceedings of the International Symposium on Recent Developments in Olefin Polymerization Catalysts

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Page iii

Copyright page
Page iv

List of Contributors
Pages v-xii

Preface
Page xvii

1. A Theory of Time-Invariant Molecular Weight Distributions in Heterogeneous Ziegler-Natta Polymerizations Original Research Article
Pages 1-10
Tominaga Keii

2. Studies on the Polymerization of Propylene Using Highly Active Magnesium Chloride Supported Ziegler-Natta Catalysts: Effects of Alkyl Concentration on the Polymerization Rate and on the Active Centre Concentration Original Research Article
Pages 11-27
P.J.T. Tait, I.A. Jaber, A.J. Loontjens

3. Gas Phase Polymerization of Propene with MgCl2 Supported Catalyst Original Research Article
Pages 29-37
A. Guyot, R. Spitz, C. Bobichon, J.L. Lacombe

4. Ethylene Polymerization in Gas-Phase and Slurry Reactors Original Research Article
Pages 39-53
M.O. Jejelowo, N. Bu, D.T. Lynch, S.E. Wanke

5. Differences in Kinetic Parameters of Various Kinds of MgC12-Supported High Yield Catalysts Original Research Article
Pages 55-61
Minoru Terano, Takuo Kataoka, Tominaga Keii

6. Kinetic Profile of Polymerization with Cr-Oxide/SiO2 Catalyst Original Research Article
Pages 63-85
Arild Follestad, Stein Helleborg, Vidar Almquist

7. Effects of the Structure of External Alkoxy Silane Donor in High Activity Ziegler-Natta Catalyst on the Microstructure of Polypropylene Original Research Article
Pages 87-105
Mika HäRkönen, Jukka V. Seppälä, Taito Väänänen

8. Active Center Selection and Propene Polymerization Control with the New Supported Ziegler-Natta Catalysts Original Research Article
Pages 107-116
R. Spitz, C. Bobichon, L. Duranel, A. Guyot

9. Control of the Catalyst and Polymer Properties of Linear Polyethylenes Original Research Article
Pages 117-130
R. Spitz, C. Brun, J.F. Joly

10. Easy Conversion of Aspecific into Isospecific Sites Original Research Article
Pages 131-138
Kazuo Soga, Joon Ryeo Park

11. A 13C CP - MAS NMR and Elemental Analysis Study of Adsorption of Silyl Ethers on the MgCl2-Supported Ziegler-Natta Catalysts Original Research Article
Pages 139-146
Pekka Sormunen, Tuula T. Pakkanen, Eila Vähäsarja, Tapani A. Pakkanen, Eero Iiskola

12. Infrared Characterization of Supported Propylene Polymerization Catalysts-A Link to Catalyst Performance Original Research Article
Pages 147-154
Gregory G. Arzoumanidis, Nicholas M. Karayannis

13. Microtacticity Distribution of Polypropylenes Prepared with MgCl2 Supported Ti Catalyst Systems Original Research Article
Pages 155-163
Tatsuya Miyatake, Kooji Mizunuma, Masahiro Kakugo

14. Development of SiO2-Supported Type Catalyst for Propylene Polymerization Original Research Article
Pages 165-176
H. Murata, A. Nakano, H. Furuhashi, M. Imai, Tonen Sekiyukagaku K.K.

15. Effect of Silane Compounds on Catalyst Isospecificity-A Plausible Model Based on MO Calculation Original Research Article
Pages 177-183
T. Okano, K. Chida, H. Furuhashi, A. Nakano, S. Ueki

16. 13C NMR Investigation on Lewis Base Activation Effect in High Yield Supported Ziegler-Natta Catalysts Original Research Article
Pages 185-200
Maria Carmela Sacchi, Incoronata Tritto, Chengji Shan, Luciano Noristi

17. A New Electron Donor for the Stereospecific Polymerization of Propene Original Research Article
Pages 201-209
T. Sugano, Y. Yamamoto, T. Fujita

18. Formation of Cationic Species and Additive Effect of Ethyl Benzoate on Polymerization of Isobutene and Styrene with TiCl3-Alkylaluminum Catalyst Original Research Article
Pages 211-222
K. Endo, T. Otsu

19. Co- and Terpolymerization of Ethene and Higher α-Olefins with MgH2 Supported Ziegler Catalysts: New Mechanistic Insight via the True Reactivity Ratios Original Research Article
Pages 223-243
G. Fink, W. Fenzl, N. Herfert, T. Müller, I. Jaber

20. Co- and Terpolymerization of Ethylene, Propylene and Butadiene with Supported Titanium Catalyst Original Research Article
Pages 245-261
Shangan Lin, Qing Wu, Lixin Sun

21. Kinetics of Ethylene-Propylene Copolymerization over MgCl2–Supported Catalysts Original Research Article
Pages 263-275
S.K. Ihm, K.S. Kang, K.J. Chu, H.S. Chang

22. A Study on the Active Sites of a Primary Type of MgCl2–Supported Catalyst by Ethylene-Propylene Copolymerization Original Research Article
Pages 277-283
Minoru Terano, Kazuhiro Ishii

23. Syntheses of Terminally Hydroxylated Polyolefins Using Zn(C2 H5)2 and Oxygen as Chain Transfer and Quenching Reagents Original Research Article
Pages 285-299
T. Shiono, K. Yoshida, K. Soga

24. Conversion of Titanacyclobutane Complexes for Ring Opening Metathesis Polymerization into Ziegler-Natta Catalysts Original Research Article
Pages 301-312
Incoronata Tritto, Robert H. Grubbs

25. Modification of High cis-1, 4 Polybutadiene by Neodymiun Catalyst Original Research Article
Pages 313-321
Iwakazu Hattori, Fumio Tsutsumi, Mitsuhiko Sakakibara, Kenya Makino

26. Homo- and Co-Polymerization of Ethylene with the Highly Active TiCl4/THF/MgCl2 Catalyst Original Research Article
Pages 323-343
I. Kim, M.C. Chung, H.K. Choi, J.H. Kim, S.I. Woo

27. Morphology of Nascent Polypropylene Produced by MgCl2 Supported Ti Catalyst Original Research Article
Pages 345-354
Masahiro Kakugo, Hajime Sadatoshi, Jiro Sakai

28. Hafnium Based Catalysts for the Polymerization of Olefins Original Research Article
Pages 355-376
F. Masi, S. Malquori, L. Barazzoni, F. Menconi, C. Ferrero, A. Moalli, R. Invernizzi

29. High Active Ziegler-Natta Catalysts for Homo- and Copolymerization of Ethylene by Supporting a Grignard Compound and TiCl4 on SiO2 Original Research Article
Pages 377-404
A. Muñoz-Esealona, A. Fuentes, J. Liscano, A. Albornoz

30. New Solvay SB 12 TiCl3 Polypropylene Catalyst Original Research Article
Pages 405-423
A. Bernard, P. Fiasse

31. Polymerization of Cyclic Olefins with Homogeneous Catalysts Original Research Article
Pages 425-438
W. Kaminsky, A. Bark, I. Däke

32. Syndiospecific Propylene Polymerizations with iPr [CpFlu] ZrCl2 Original Research Article
Pages 439-482
John A. Ewen, M.J. Elder, R.L. Jones, S. Curtis, H.N. Cheng

33. Stereospecific Polymerization of α–Olefin with an Ethylene Bis(1–Indenyl) Hafnium Dichloride and Methyl–Aluminoxane Catalyst System Original Research Article
Pages 483-492
M. Kioka, T. Tsutsui, T. Ueda, N. Kashiwa

34. Isotactic Polypropylene with a Soluble Metallocene Based Catalyst System–Characterization of Blown Film– Original Research Article
Pages 493-499
T. Tsutsui, M. Kioka, A. Toyota, N. Kashiwa

35. Propylene Polymerization by Stereorigid Metallocene Catalysts: Some New Aspects of the Metallocene Structure/Polypropylene Microstructure Correlation Original Research Article
Pages 501-515
M. Antberg, V. Dolle, R. Klein, J. Rohrmann, W. Spaleck, A. Winter

36. Polymerization of Styrene and Copolymerization of Styrene with Olefin in the Presence of Soluble Ziegler-Natta Catalysts Original Research Article
Pages 517-529
Masahiro Kakugo, Tatsuya Miyatake, Kooji Mizunuma

37. Propylene Polymerizations with Silylene-Bridged Metallocene Catalysts Original Research Article
Pages 531-534
Shinya Miya, Takaya Mise, Hiroshi Yamazaki

38. Homogeneous Ziegler–Natta Catalysts and Synthesis of Anisotactic and Thermoplastic Elastomeric Poly (propylenes) Dedicated to Professor T. Keii on the Occasion of his seventieth birthday. Original Research Article
Pages 535-574
James C.W. Chien, Bernhard Rieger, Ryuichi Sugimoto, Daniel T. Mallin, Marvin D. Rausch