Thermodynamics of Biochemical Reactions

Cover Page......Page 1
Copyright 2003 by John Wiley & Sons, In......Page 3
Title Page......Page 2
Contents......Page 4
Preface......Page 5
1 Introduction to Apparent Equilibrium Constants......Page 8
2 Structure of Thermodynamics......Page 25
3 Chemical Equilibrium in Aqueous Solutions......Page 41
4 Thermodynamics of Biochemical Reactions at Specified pH......Page 62
5 Matrices in Chemical and Biochemical Thermodynamics......Page 94
6 Systems of Biochemical Reactions......Page 109
7 Thermodynamics of Binding of the Ligands by Proteins......Page 124
8 Phase Equilibrium in Aqueous Systems......Page 143
9 Oxidation-Reduction Reactions......Page 156
10 Calorimetry of Biochemical Reactions......Page 172
11 Use of Semigrand Partition Functions......Page 179
Glossary......Page 186
References......Page 190
Part Two: Mathematica Solutions to Problems......Page 194
BasicBiochemData2.nb......Page 195
1.0 Introduction......Page 196
2.0 Basic data on the species that make up a reactant.......Page 201
3.0 Calculation of the functions of pH and ionic strength for the standard......Page 203
4.0 Calculation of a table of standard transformed Gibbs energies of formation of reactants at pH 7 and ionic strengths of 0, 0.10, and 0.25 M......Page 206
5.0 Calculation of a table of standard transformed Gibbs energies of reactants at pH 5, 6, 7, 8, and 9 and ionic strength 0.25 M......Page 209
6.0 Calculation of the functions of pH and ionic strength for the standard transformed enthalpies of formation of reactants......Page 213
7.0 Calculation of a table of standard transformed enthalpies of formation of reactants at pH 7 and ionic strengths of 0, 0.10, and 0.25 M......Page 215
8.0 Calculation of the standard transformed enthalpies of formation of reactants at pH 5, 6, 7, 8, and 9 and ionic strength 0.25 M......Page 217
9.0 Examples of calculations using the database on species......Page 219
1 Apparent Equilibrium Constants......Page 231
3 Chemical Equilibrium in One Phase Systems......Page 259
4 Thermodynamics of Biochemical Reactions at Specified pH......Page 277
5 Matrices in Chemical and Biochemical Thermodynamics......Page 317
6 Systems of Biochemical Reactions......Page 325
7 Thermodynamics of Binding of Ligands by Proteins......Page 337
8 Phase Equilibrium in Aqueous Solutions......Page 347
9 Redox Reactions......Page 353
11 Use of Semigrand Partition Functions......Page 379
Index of Mathematica Programs......Page 387
A,B......Page 389
C......Page 390
D,E......Page 391
F,G,H......Page 392
I,L......Page 393
M,N,O......Page 394
P,R......Page 395
S,T......Page 396
W......Page 397