The Chemistry of Clay-Organic Reactions

Cover
Half Title
Title
Copyright
Dedication
Contents
Preface to the First Edition
Preface to the Second Edition
Chapter 1 Clays and Clay Minerals: Structures and Surface Properties
	1.1 Introduction
	1.2 Structural and Surface-Chemical Aspects
	1.3 1:1 Type Phyllosilicates with Planar Layer Structures
		1.3.1 Kaolinite
		1.3.2 Halloysite
		1.3.3 Chrysotile
	1.4 2:1 Type Phyllosilicates with Planar Layer Structures
		1.4.1 Smectite
		1.4.2 Vermiculite
		1.4.3 Chlorite
	1.5 Mica, Illite, Synthetic Swelling Mica, Fluorotetrasilicic Mica, Taenolite
		1.5.1 Muscovite, Biotite, Phlogopite
		1.5.2 Illite
		1.5.3 Synthetic Swelling Micas
		1.5.4 Fluorotetrasilicic Mica
		1.5.5 Taenolite
	1.6 2:1 Type Layer Silicates with Layer-Ribbon Structures
		1.6.1 Palygorskite and Sepiolite
	1.7 Silicates with Short-Range Order Structures
		1.7.1 Allophane and Imogolite
	References
Chapter 2 Interactions of Clay Minerals with Uncharged Organic Compounds
	2.1 Introduction
	2.2 Role of Layer/Surface Charge Density
	2.3 Role of Interlayer Water
	2.4 Adsorption from Aqueous Solutions
	2.5 Molecular Orientation
	2.6 Complex Formation with Various Classes of Uncharged Organic Compounds
		2.6.1 Complexes with Primary n-Alcohols
		2.6.2 Complexes with Polyhydric Alcohols
		2.6.3 Complexes with Amines
		2.6.4 Complexes with Amides
		2.6.5 Complexes with Other Classes of Uncharged Organic Compounds: Ketones, Aldehydes, Ethers, Nitriles, Hydrocarbons
	References
Chapter 3 Interactions of Clay Minerals with Organic Compounds of Biological and Environmental Importance
	3.1 Interactions with Organic Pesticides
		3.1.1 Introduction
		3.1.2 Uncharged (Non-Ionic) Pesticides
		3.1.3 Negatively Charged (Anionic) Pesticides
		3.1.4 Positively Charged (Cationic) Pesticides
	3.2 Interactions with Antibiotics, Pharmaceuticals, and Toxins
	3.3 Interactions with Amino Acids and Peptides
	3.4 Interactions with Purines, Pyrimidines, Nucleosides, and Nucleotides
	3.5 Interactions with Fatty Acids and Fats
	3.6 Interactions with Saccharides
	3.7 Interactions with Dyes
	References
Chapter 4 Interactions of Clay Minerals with Positively Charged Organic Compounds
	4.1 Introduction
	4.2 Mechanisms of Complex Formation
	4.3 Interlayer Organization of Organic Cations
	4.4 Formation, Properties, and Some Applications of Cationic Complexes
	4.5 Organically Modified and Covalently Grafted Clay Minerals
	References
Chapter 5 Interactions of Clay Minerals with Negatively Charged Organic Compounds
	5.1 Introduction
	5.2 Formation and Properties of Complexes
	References
Chapter 6 Organic Complexes of Clay Minerals with a 1:1 Type Layer Structure
	6.1 Introduction
	6.2 Intercalation of Organic Molecules
		6.2.1 General Aspects
		6.2.2 Formation and Properties of Interlayer Complexes
	6.3 Kaolinite
		6.3.1 Interlayer Complex Formation
		6.3.2 Surface Complex Formation
	6.4 Halloysite
		6.4.1 Interlayer Complex Formation
	6.5 Chrysotile
	References
Chapter 7 Organic Complexes of Clay Minerals with Layer-Ribbon and Short-Range Order Structures
	7.1 Introduction
	7.2 Palygorskite and Sepiolite
	7.3 Allophane and Imogolite
	References
Index