Supramolecular Chemistry

Title Page
Copyright Page
About the Authors
Preface to the Third Edition
Acknowledgements
About the Front Cover
About the Companion Website
CHAPTER 1: Concepts
	1.1 DEFINITION AND DEVELOPMENT OF SUPRAMOLECULAR CHEMISTRY
	1.2 CLASSIFICATION OF SUPERMOLECULE FORMATION
	1.3 RECEPTORS, COORDINATION, AND THE LOCK AND KEY ANALOGY
	1.4 BINDING CONSTANTS
	1.5 COOPERATIVITY, MULTIVALENCY, AND THE CHELATE EFFECT
	1.6 PREORGANISATION AND COMPLEMENTARITY
	1.7 THERMODYNAMIC AND KINETIC SELECTIVITY, AND DISCRIMINATION
	1.8 NATURE OF SUPRAMOLECULAR INTERACTIONS
	1.9 SOLVATION EFFECTS
	1.10 SUPRAMOLECULAR CONCEPTS AND DESIGN
	1.11 PRACTICAL APPLICATIONS OF SUPRAMOLECULAR CHEMISTRY
	SUMMARY
	STUDY PROBLEMS
	REFERENCES
CHAPTER 2: The Supramolecular Chemistry of Life
	2.1 BIOLOGICAL INSPIRATION FOR SUPRAMOLECULAR CHEMISTRY
	2.2 ALKALI METAL CATIONS IN BIOCHEMISTRY
	2.3 PORPHYRINS AND TETRAPYRROLE MACROCYCLES
	2.4 SUPRAMOLECULAR FEATURES OF PLANT PHOTOSYNTHESIS
	2.5 UPTAKE AND TRANSPORT OF OXYGEN BY HAEMOGLOBIN
	2.6 ENZYMES AND COENZYMES
	2.7 SIGNALLING: NEUROTRANSMITTERS, HORMONES, AND PHEROMONES
	2.8 DNA AND THE GENETIC CODE
	2.9 BIOCHEMICAL SELF‐ASSEMBLY
	2.10 BIOMINERALISATION
	2.11 EMERGENCE OF LIFE
	SUMMARY
	REFERENCES
CHAPTER 3: Cation‐Binding Hosts
	3.1 INTRODUCTION TO COORDINATION CHEMISTRY
	3.2 PODANDS
	3.3 THE CROWN AND LARIAT ETHERS
	3.4 THE CRYPTANDS
	3.5 THE SPHERANDS
	3.6 NOMENCLATURE OF CATION‐BINDING MACROCYCLES
	3.7 SELECTIVITY OF CATION COMPLEXATION
	3.8 SOLUTION BEHAVIOUR AND APPLICATIONS OF CROWNS AND CRYPTANDS
	3.9 MACROCYCLE SYNTHESIS: THE TEMPLATE EFFECT AND HIGH DILUTION
	3.10 SOFT LIGANDS FOR SOFT METAL IONS
	3.11 PROTON BINDING: THE SIMPLEST CATION
	3.12 COMPLEXATION OF ORGANIC CATIONS
	3.13 ALKALIDES AND ELECTRIDES
	3.14 THE CALIXARENES
	3.15 CARBON DONOR AND π‐ACID LIGANDS
	3.16 THE SIDEROPHORES
	SUMMARY
	REFERENCES
CHAPTER 4: Anion Binding
	4.1 INTRODUCTION
	4.2 BIOLOGICAL ANION RECEPTORS
	4.3 CONCEPTS IN ANION HOST DESIGN
	4.4 CATIONIC RECEPTORS
	4.5 NEUTRAL RECEPTORS
	4.6 BORON BASED RECEPTORS AND LEWIS ACID CHELATES
	4.7 METAL‐CONTAINING RECEPTORS
	4.8 ANION‐BINDING HELICES
	4.9 ANION TRANSPORT
	SUMMARY
	THOUGHT EXPERIMENTS
	REFERENCES
CHAPTER 5: Ion‐Pair Receptors
	5.1 SIMULTANEOUS ANION AND CATION BINDING
	5.2 LABILE COORDINATION COMPLEXES AND CAGES AS ANION HOSTS
	5.3 RECEPTORS FOR ZWITTERIONS
	SUMMARY
	STUDY PROBLEMS
	REFERENCES
CHAPTER 6: Molecular Guests in Solution
	6.1 MOLECULAR HOSTS AND MOLECULAR GUESTS
	6.2 INTRINSIC CURVATURE: GUEST BINDING BY CAVITANDS
	6.3 CYCLODEXTRINS
	6.4 MOLECULAR TWEEZERS, CLIPS AND CLEFTS
	6.5 CYCLOPHANE HOSTS
	6.6 CONSTRUCTING A SOLUTION HOST FROM CLATHRATE‐FORMING BUILDING BLOCKS: THE CRYPTOPHANES
	6.7 COVALENT CAGES: CARCERANDS AND HEMICARCERANDS
	6.8 COORDINATION CAGES
	6.9 HALOGEN‐BONDED COMPLEXES
	SUMMARY
	STUDY PROBLEMS
	THOUGHT EXPERIMENT
	REFERENCES
CHAPTER 7: Solid‐State Inclusion Compounds
	7.1 NOMENCLATURE AND THERMOCHEMICAL ASPECTS
	7.2 POROSITY AND GAS SORPTION
	7.3 CLATHRATE HYDRATES
	7.4 UREA AND THIOUREA CLATHRATES
	7.5 CHANNEL CLATHRATES
	7.6 POLARITY FORMATION
	7.7 HYDROQUINONE, PHENOL, DIANIN’S COMPOUND, AND THE HEXAHOST STRATEGY
	7.8 MACROCYCLIC CLATHRATES
	7.9 COVALENT CAGES
	7.10 GAS SORPTION BY COORDINATION COMPLEX HOSTS
	SUMMARY
	STUDY PROBLEMS
	REFERENCES
CHAPTER 8: Crystal Engineering
	8.1 CONCEPTS
	8.2 CRYSTAL NUCLEATION AND GROWTH
	8.3 UNDERSTANDING CRYSTAL STRUCTURES
	8.4 THE CAMBRIDGE STRUCTURAL DATABASE
	8.5 POLYMORPHISM
	8.6 CO‐CRYSTALS
	8.7 SOLID STATE TRANSFORMATIONS
	8.8 CRYSTAL STRUCTURE PREDICTION
	8.9 COMMON AND EXOTIC SUPRAMOLECULAR SYNTHONS
	8.10 HALOGEN BONDING
	8.11 BENDING AND JUMPING CRYSTALS
	SUMMARY
	STUDY PROBLEMS
	THOUGHT EXPERIMENT
	REFERENCES
CHAPTER 9: Network Solids
	9.1 WHAT ARE NETWORK SOLIDS?
	9.2 ZEOLITES
	9.3 LAYERED SOLIDS AND INTERCALATES
	9.4 IN THE BEGINNING: HOFFMAN INCLUSION COMPOUNDS AND WERNER CLATHRATES
	9.5 COORDINATION POLYMERS
	9.6 POROUS METAL–ORGANIC FRAMEWORKS
	9.7 COVALENT ORGANIC FRAMEWORKS
	SUMMARY
	STUDY PROBLEM
	REFERENCES
CHAPTER 10: Self‐Assembly
	10.1 INTRODUCTION
	10.2 PROTEINS AND FOLDAMERS: SINGLE‐MOLECULE SELF‐ASSEMBLY
	10.3 BIOCHEMICAL SELF‐ASSEMBLY
	10.4 SELF‐ASSEMBLY IN SYNTHETIC SYSTEMS: KINETIC AND THERMODYNAMIC CONSIDERATIONS
	10.5 HELICATES AND HELICAL ASSEMBLIES
	10.6 SELF‐ASSEMBLING COORDINATION COMPOUNDS
	10.7 SELF‐ASSEMBLY OF CLOSED COMPLEXES BY HYDROGEN BONDING
	10.8 TEMPLATED ASSEMBLY OF PORPHYRIN ARRAYS
	10.9 PROGRAMMED ASSEMBLY WITH BIOMOLECULES
	SUMMARY
	STUDY PROBLEMS
	THOUGHT EXPERIMENT
	REFERENCES
CHAPTER 11: The Mechanical Bond
	11.1 SCOPE AND IMPORTANCE OF MECHANICAL BONDING AND MECHANOSTEREOCHEMISTRY
	11.2 CATENANES AND ROTAXANES
	11.3 MOLECULAR KNOTS
	11.4 BORROMEAN RINGS AND MULTIPLY INTERLOCKED CATENANES
	11.5 INTERPENETRATED CAGES
	11.6 AN UNUSUAL THRING
	SUMMARY
	STUDY PROBLEM
	REFERENCES
CHAPTER 12: Molecular Devices and Machines
	12.1 INTRODUCTION
	12.2 SUPRAMOLECULAR PHOTOCHEMICAL DEVICES
	12.3 INFORMATION AND SIGNALS: SEMIOCHEMISTRY AND SENSING
	12.4 MOLECULE‐BASED ELECTRONICS
	12.5 MOLECULAR ANALOGUES OF MECHANICAL MACHINES
	SUMMARY
	STUDY PROBLEMS
	REFERENCES
CHAPTER 13: Biological Mimics and Supramolecular Catalysis
	13.1 INTRODUCTION
	13.2 CYCLODEXTRINS AS ENZYME MIMICS
	13.3 CORANDS AS ATPASE MIMICS
	13.4 CATION‐BINDING HOSTS AS TRANSACYLASE MIMICS
	13.5 METALLOBIOSITES
	13.6 ENZYME MIMETIC MATERIALS
	13.7 ION CHANNEL MIMICS
	13.8 SUPRAMOLECULAR CATALYSIS
	SUMMARY
	THOUGHT EXPERIMENT
	REFERENCES
CHAPTER 14: Interfaces and Liquid Assemblies
	14.1 ORDER IN LIQUIDS
	14.2 SURFACTANTS AND INTERFACIAL ORDERING
	14.3 LIQUID CRYSTALS
	14.4 POLYAMORPHOUS LIQUIDS
	14.5 IONIC LIQUIDS AND DEEP EUTECTIC SOLVENTS
	14.6 LIQUID CLATHRATES
	14.7 POROUS LIQUIDS
	SUMMARY
	STUDY PROBLEMS
	REFERENCES
CHAPTER 15: Supramolecular Materials
	15.1 INTRODUCTION
	15.2 DENDRIMERS
	15.3 FRACTAL ASSEMBLIES
	15.4 COVALENT POLYMERS WITH SUPRAMOLECULAR PROPERTIES
	15.5 SELF‐ASSEMBLED SUPRAMOLECULAR POLYMERS
	15.6 MECHANICALLY INTERLOCKED MATERIALS
	15.7 SUPRAMOLECULAR GELS
	15.8 POLYMERIC LIQUID CRYSTALS
	15.9 BIOLOGICAL SELF‐ASSEMBLED MATERIALS
	SUMMARY
	STUDY PROBLEMS
	REFERENCES
CHAPTER 16: Dynamic Covalent Bonding and Complex Systems
	16.1 CHEMISTRY OUT OF EQUILIBRIUM
	16.2 DYNAMIC COMBINATORIAL LIBRARIES
	16.3 SELF‐REPLICATION
	16.4 SHAPESHIFTING MOLECULES
	16.5 DISSIPATIVE SELF‐ASSEMBLY
	SUMMARY
	REFERENCES
CHAPTER17 Nanochemistry
	17.1 WHEN IS NANO REALLY NANO?
	17.2 NANOTECHNOLOGY: THE ‘TOP‐DOWN’ AND ‘BOTTOM‐UP’ APPROACHES
	17.3 TEMPLATED AND BIOMIMETIC MORPHOSYNTHESIS
	17.4 NANOSCALE PHOTONICS
	17.5 MICROFABRICATION, NANOFABRICATION AND SOFT LITHOGRAPHY
	17.6 ASSEMBLY AND MANIPULATION ON THE NANOSCALE
	17.7 NANOPARTICLES
	17.8 ENDOHEDRAL FULLERENES, NANOTUBES AND GRAPHENE
	SUMMARY
	THOUGHT EXPERIMENT
	REFERENCES
Index
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