Structure, Dynamics, and Properties of Silicate Melts

Page 1
	Titles
		REVIEWS in MINERALOGY Volume 32
		EDITORS:
		Mineralogical Society of America
Page 1
	Titles
		MINERALOGICAL SOCIETY OF AMERICA
		REVIEWS IN MINERALOGY
		Volume 32
		Structure, Dynamics and Properties
Page 1
	Titles
		STRUCTURE, DYNAMICS AND PROPERTIES OF SILICATE MELTS
		FOREWORD
		EDITORS\' PREFACE
		iii
Page 2
	Titles
		iv
Page 3
	Titles
		v
Page 4
	Tables
		Table 1
Page 1
	Titles
		STRUCTURE, DYNAMICS AND PROPERTIES
		vii
Page 2
	Titles
		viii
Page 3
	Titles
		ix
Page 4
	Titles
		x
Page 5
	Titles
		xi
Page 6
	Titles
		xii
Page 7
	Titles
		xiii
Page 8
	Titles
		xiv
Page 9
	Titles
		xv
Page 10
Page 1
	Titles
		Chapter 1
		STRUCTURAL RELAXATION AND THE GLASS TRANSITION
		Cornelius T. Moynihan
Page 2
	Titles
		2
Page 3
	Titles
		3
Page 4
	Titles
		4
		time
		- - -
		o
		_____,..
		T
		Structural Relaxation in Liquids
		(2)
		_ H - He _ Tf - T2 _ t
		Ho - He T, - T2 T
		(4)
Page 5
	Titles
		5
		,
		6TL __
		a
		b
Page 6
	Titles
		6
Page 7
	Titles
		7
		a
		P
	Tables
		Table 1
Page 8
	Titles
		8
		t
		(5)
Page 9
	Titles
		9
		0.5
		720
Page 10
	Titles
		10
Page 11
	Titles
		11
		x6H* (1 - x)6H*
		\'I = Toexp[ RT + RTf 1 (8;
		B
		\'I = TO exp[\",,.., /\", ,l
		(9)
		¢(t) = \'L:9iexP[-l dt\'hl (11)
		,
		x6H* (1 - x)6H*
Page 12
	Titles
		12
		¢(t) = exp[-([ dt\'/T)f3) (14)
		¢(t) = p(t) - Pe = Tf(t) - T2 (l5)
		Po - Pe Tl - T2
		Tf(t) = To + L 6Tj[1 - ¢(t, tj))
		¢(t, tj) = exp[-(!ot-tj d(t\' - tj)/T),B]
Page 13
	Titles
		13
	Tables
		Table 1
Page 14
	Titles
		14
	Tables
		Table 1
Page 15
	Titles
		15
	Tables
		Table 1
Page 16
	Titles
		16
		TglT
		(22)
		B7] 1 [B7] 1
		\'i) = \'i)oexp[TSc(T) = \'i)oexp T!:::.Cpln(TjTK)
	Tables
		Table 1
Page 17
	Titles
		17
		60
		1; 50
		~
		\"Q. 40
		10
		20 30
		Na201 mol%
		40
		1~
		~
		0-;\'
		Jf
		50
Page 18
	Titles
		18
		Moynihan: Structural Relaxation and the Glass Transition
		REFERENCES
Page 19
	Titles
		Moynihan: Structural Relaxation and the Glass Transition
		19
Page 20
Page 1
	Titles
		Chapter 2
		SOME APPLICATIONS
		D. B. Dingwell
Page 2
	Titles
		22
		P
		dP
Page 3
	Titles
		23
		\"\\
Page 4
	Titles
		24
Page 5
	Titles
		25
		T = n/G
Page 6
	Titles
		26
		Dingwell: Relaxation in Silicate Melts: Applications
		f ~ s-c
		~~ IJ ~
		g.
		o
	Tables
		Table 1
Page 7
	Titles
		27
		;;
Page 8
	Titles
		28
		M = K + (4/3)0
Page 9
	Titles
		29
		o
		c
		-_
	Tables
		Table 1
Page 10
	Titles
		30
		o
		o
		....
		•
		•
	Tables
		Table 1
Page 11
	Titles
		31
Page 12
	Titles
		32
		Dingwell: Relaxation in Silicate Melts: Applications
		::: 1 MAl r;6,~~.. __ _
		i,
		\"\" -f- - - - - - --- - - - - - - KEO
		AGPAITIC INDEX
	Tables
		Table 1
Page 13
	Titles
		33
Page 14
	Titles
		34
	Tables
		Table 1
		Table 2
		Table 3
Page 15
	Titles
		35
		\'.
		..
		.
		\"
		-:
		..... ..... .. ~ )
Page 16
	Titles
		36
Page 17
	Titles
		37
		(6)
Page 18
	Titles
		TEMPERA TURE
	Tables
		Table 1
Page 19
	Titles
		39
		H
Page 20
	Titles
		40
		Dingwell: Relaxation in Silicate Melts: Applications
		a
		m m ill ~ ill m ~ ~
		\"
		b
		c
		(\\f \\
		TEMPERATURE
		caC)
Page 21
	Titles
		41
		] 6
		15
		14
		12
		-6
		,
		u
		bD
	Tables
		Table 1
Page 22
	Titles
		42
Page 23
	Titles
		Dingwell: Relaxation in Silicate Melts: Applications
		•
		43
		-S
		o
		>
		o
		::2\'
		TEMPERATURE (C)
	Tables
		Table 1
Page 24
	Titles
		44
	Tables
		Table 1
Page 25
	Titles
		45
	Tables
		Table 1
Page 26
	Titles
		MOLAR VOLUME OF THE MELTS
		Dingwell: Relaxation in Silicate Melts: Applications
		mol%
	Tables
		Table 1
Page 27
	Titles
		47
Page 28
	Titles
		48
		\'\"
		..
		.•.. -. ....
		\'\"
	Tables
		Table 1
Page 29
	Titles
		49
		•
		•
		~
		.. ..
Page 30
	Titles
		50
Page 31
	Titles
		51
Page 32
	Titles
		52
		1
Page 33
	Titles
		53
		~
Page 34
	Titles
		54
Page 35
	Titles
		55
		a
	Tables
		Table 1
Page 36
	Tables
		Table 1
		Table 2
Page 37
	Titles
		57
		o
		::z::
		,
		::z::
		__ of
		T----~----~----~
Page 38
	Titles
		58
		Dingwell: Relaxation in Silicate Melts: Applications
		10
	Tables
		Table 1
		Table 2
		Table 3
Page 39
	Titles
		59
Page 40
	Titles
		60
Page 41
	Titles
		61
		o
		calcalkaline
		t
		10,OOO/T(K)
	Tables
		Table 1
Page 42
	Titles
		62
Page 43
	Titles
		Dingwell: Relaxation in Silicate Melts: Applications
		63
		REFERENCES
Page 44
	Titles
		64
		Dingwell: Relaxation in Silicate Melts: Applications
Page 45
	Titles
		Dingwell: Relaxation in Silicate Melts: Applications
		65
Page 46
	Titles
		66
		Dingwell: Relaxation in Silicate Melts: Applications
Page 1
	Titles
		Chapter 3
		RHEOLOGY AND CONFIGURATIONAL ENTROPY
		P. Richet and Y. Bottinga
		o
		eo
		-
		~
		.....
		o
		~
		....
		...
		9
Page 2
	Titles
		68
Page 3
	Titles
		69
Page 4
	Titles
		do/dr = G~ ds/dr .
		daldt = G~ ds/dr - air, (8)
Page 5
	Titles
		71
		...
		~ ...
		~ ..
		TJ = G~ \'t\'.
		K = K~ - K; (12)
		TJv = Kr\'t\'v
		\'t\'p = 1:vK.JK. (14)
Page 6
	Titles
		72
		(J\' = TJel deelfdt , (15)
		(J\' = E eel,
		TJel = 3 TJ . (19)
Page 7
	Titles
		73
		1500
		3Rfg atom
		1200
		900
		~~ I\' id
		y _... IqUI
		a
		600
		\'.
		...
		~~
		,
		t glass
		50~~~~~~~~~~~~~
		300
		90
		60
		c.. 70
		g-
		o 80
		~
		T (K)
Page 8
	Titles
		74
	Tables
		Table 1
Page 9
	Titles
		75
		T (K)
		sconr
	Tables
		Table 1
Page 10
	Titles
		76
		sconf(T) = sconf(Tg) + J C~Onf I TdT.
		weT) = A exp (-BeiTsconf) , (25)
	Tables
		Table 1
Page 11
	Titles
		Temperature dependence of the viscosity
	Tables
		Table 1
Page 12
	Titles
		78
		Richet & Bottinga: Rheology and Configurational Entropy
		so
		~
		~ 40
Page 13
	Titles
		79
	Tables
		Table 1
Page 14
	Titles
		80
		~
Page 15
	Titles
		81
	Tables
		Table 1
Page 16
	Titles
		82
Page 17
	Titles
		83
		\"
		..
Page 18
	Titles
		84
Page 19
	Titles
		85
		< f:J.S f:J. V > = kB T (aVlaT)p (38)
		< ss=« f:J. V > = kB T [(av/aT)p - (av/aT)p] . (39)
	Tables
		Table 1
Page 20
	Titles
		86
Page 21
	Titles
		87
Page 22
	Titles
		88
		\'\"
		.::
Page 23
	Titles
		ACKNOWLEDGMENTS
		REFERENCES
Page 24
	Titles
		90
		Richet & Bottinga: Rheology and Configurational Entropy
Page 25
	Titles
		Richet & Bottinga: Rheology and Configurational Entropy
		91
Page 26
	Titles
		92
		Richet & Bottinga: Rheology and Configurational Entropy
Page 27
	Titles
		Richet & Bottinga: Rheology and Configurational Entropy
		9~
Page 28
Page 1
	Titles
		Chapter 4
		Sharon L. Webb and Donald B. Dingwell
Page 2
	Titles
		96
		-
		-
		~!
		~
		- r- - - - -
		TIME
		(2)
Page 3
	Titles
		97
		>-­
		:;
		log, TIME
Page 4
	Titles
		98
		Webb & Dingwell: Viscoelasticity
		(5)
		,
		,
		>­
		1+ \'ts 1+ \'ts
Page 5
	Titles
		99
		K * (00) = K= - Ko + Ko 2 2 + lKo ----:::;- 2
		(9)
		I . 00 \'is
		I (oo\'tv K= - KO)
Page 6
	Titles
		100
		~
		a
		>
		,
		o
		:J
		~
		,/\\
		3:
Page 7
	Titles
		101
	Tables
		Table 1
Page 8
	Titles
		102
Page 9
	Titles
		103
Page 10
	Titles
		104
Page 11
	Titles
		105
		-
	Tables
		Table 1
		Table 2
Page 12
	Tables
		Table 1
Page 13
	Titles
		107
		-.-
		- .. -
		loglo 7:1\\
	Tables
		Table 1
Page 14
	Titles
		108
Page 15
	Titles
		109
		M(oo) = p v~ (00).
	Tables
		Table 1
Page 16
	Titles
		110
		Webb & Dingwell: Viscoelasticity
		2
		G\'((1)
	Tables
		Table 1
		Table 2
Page 17
	Titles
		111
Page 18
	Titles
		112
Page 19
	Titles
		113
		10
		>-­
		:;
		o
		iovz-c
	Tables
		Table 1
Page 20
	Titles
		114
		V = IX v: + I X X v:
		K = ~=- v· ap .
		1 [ n .... -V· n av 1
		(20)
Page 21
	Titles
		115
	Tables
		Table 1
		Table 2
Page 22
	Titles
		116
Page 23
	Titles
		Webb & Dingwell: Viscoelasticity
		117
		melts is an essential component of progress in understanding viscous deformation in
		REFERENCES
Page 24
	Titles
		118
		Webb & Dingwell: Viscoelasticity
Page 25
	Titles
		119
		APPENDIX
		Mechanical relaxation time
		Electrical relaxation time
		\'t =~~------------~~--~~--------------
		(AI)
		(A2)
		Thermal relaxation time
		\'tt =-=
		(A3)
Page 26
Page 1
	Titles
		Chapter 5
		ENERGETICS OF SILICATE MELTS
		Alexandra Navrotsky
Page 2
	Titles
		122
Page 3
	Titles
		123
Page 4
	Titles
		124
		Navrotsky: Energetics of Silicate Melts
		FACTORS AFFECTING MELT ENERGETICS
		Major acid-base interactions and polymerization equilibria
		(1)
		(2)
		b
		o
		a
	Tables
		Table 1
		Table 2
Page 5
	Titles
		125
	Tables
		Table 1
Page 6
	Titles
		126
	Tables
		Table 1
Page 7
	Titles
		127
Page 8
	Titles
		[
		e
		:t
	Tables
		Table 1
Page 9
	Titles
		129
Page 10
	Titles
		130
		Navrotsky: Energetics of Silicate Melts
		-48b
		-og
	Tables
		Table 1
		Table 2
Page 11
	Titles
		131
	Tables
		Table 1
Page 12
	Titles
		Navrotsky: Energetics of Silicate Melts
		Temperature (K)
	Tables
		Table 1
Page 13
	Titles
		133
	Tables
		Table 1
Page 14
	Titles
		134
Page 15
	Titles
		\'\"
		135
Page 16
	Tables
		Table 1
		Table 2
Page 17
	Titles
		137
	Tables
		Table 1
Page 18
Page 19
	Titles
		139
		•
		•
		•
		•
		••
		11\\
	Tables
		Table 1
Page 20
	Titles
		140
		Navrotsky: Energetics of Silicate Melts
		REFERENCES
Page 21
	Titles
		Navrotsky: Energetics of Silicate Melts
		141
Page 22
	Titles
		142
		Navrotsky: Energetics of Silicate Melts
Page 23
	Titles
		Navrotsky: Energetics of Silicate Melts
		143
Page 24
Page 1
	Titles
		Paul C. Hess
Page 2
Page 3
Page 4
	Tables
		Table 1
Page 5
	Titles
		149
Page 6
	Titles
		150
		... ·::::z
		..» 0<····· RnO
		-175 +--.--.--.--.-.--.--.--.---.--1
Page 7
	Titles
		151
Page 8
	Titles
		(6)
		8:::::::::::::::·.
Page 9
	Tables
		Table 1
Page 10
	Titles
		154
Page 11
	Titles
		155
Page 12
	Titles
		ENTHALPY OF SIMPLE \"MINERAL\" MELTS
	Tables
		Table 1
Page 13
Page 14
	Titles
		158
		:r:
Page 15
	Titles
		Hess: Thermodynamic Mixing Properties and Structure
		159
	Tables
		Table 1
Page 16
	Tables
		Table 1
Page 17
	Titles
		(21)
Page 18
	Titles
		162
	Tables
		Table 1
Page 19
Page 20
	Titles
		so ,
Page 21
	Titles
		165
Page 22
	Titles
		166
Page 23
	Titles
		167
	Tables
		Table 1
Page 24
Page 25
	Titles
		169
		o
		Peraluminous
		K* (
		Peralkaline
Page 26
Page 27
	Titles
		171
Page 28
	Titles
		172
Page 29
	Titles
		173
		----
	Tables
		Table 1
Page 30
	Titles
		174
		[Z+Z-I]e02
	Tables
		Table 1
Page 31
	Titles
		Hess: Thermodynamic Mixing Properties and Structure
		175
		5oo,_------~r-------~------~r_------~
Page 32
	Titles
		K
Page 33
Page 34
Page 35
Page 36
	Titles
		180
Page 37
	Titles
		181
Page 38
	Titles
		182
	Tables
		Table 1
		Table 2
Page 39
	Titles
		(A20)
		(A21)
		(A23)
Page 40
	Titles
		184
		X s.o,
Page 41
	Titles
		Hess: Thermodynamic Mixing Properties and Structure
		185
		(A30)
		Entropy of mixing
		(A31)
Page 42
	Titles
		186
		(0°)(0-2)
		K .:.__-\'--\'-___:__
		(0-)2
		O,_----------.----------,-----------r----------~
Page 43
	Titles
		Hess: Thermodynamic Mixing Properties and Structure 187
		REFERENCES
Page 44
	Titles
		188
		Hess: Thermodynamic Mixing Properties and Structure
Page 45
	Titles
		Hess: Thermodynamic Mixing Properties and Structure
		189
Page 46
Page 1
	Titles
		Chapter 7
		DYNAMICS AND STRUCTURE OF SILICATE AND OXIDE
		Jonathan F. Stebbins
		INTRODUCTION
Page 2
	Titles
		192
Page 3
	Titles
		193
Page 4
	Titles
		194
		(2)
Page 5
	Titles
		195
Page 6
	Titles
		196
		o
		A e
		-
		-~ ,
		v - C
Page 7
	Titles
		197
Page 8
	Titles
		198
		o
		-A--
	Tables
		Table 1
Page 9
	Titles
		199
Page 10
	Titles
		200
		on A- __
	Tables
		Table 1
Page 11
	Titles
		201
Page 12
	Titles
		202
		Structural effects on chemical shifts
Page 13
	Titles
		203
Page 14
	Titles
		204
		Stebbins: Dynamics and Structure of Melts: NMR Studies
		1 bar
		o
		o
		o
		o
Page 15
	Titles
		205
Page 16
	Titles
		206
	Tables
		Table 1
Page 17
	Titles
		207
Page 18
	Titles
		208
Page 19
	Titles
		209
Page 20
	Titles
		210
Page 21
	Titles
		Stebbins: Dynamics and Structure of Melts: NMR Studies
		211
Page 22
	Titles
		212
Page 23
	Titles
		213
Page 24
	Titles
		214
Page 25
	Titles
		215
Page 26
	Titles
		216
Page 27
	Titles
		217
Page 28
	Titles
		218
REV032C007_p219-246.pdf
	Page 1
		Titles
			219
	Page 2
	Page 3
		Titles
			221
	Page 4
		Titles
			222
	Page 5
		Titles
			223
			(j)
	Page 6
		Titles
			224
			•
			2~~~~~~~~~~~~~~~+
			..
			(14)
		Tables
			Table 1
	Page 7
		Titles
			225
		Tables
			Table 1
	Page 8
		Titles
			226
			Stebbins: Dynamics and Structure of Melts: NMR Studies
		Tables
			Table 1
			Table 2
	Page 9
		Titles
			227
	Page 10
		Titles
			228
	Page 11
		Titles
			229
			J /
	Page 12
		Titles
			230
			•
			•
			••
			• •
			•
			-
			• •
			•
			•
			\"
	Page 13
		Titles
			231
			•
		Tables
			Table 1
	Page 14
		Titles
			232
	Page 15
		Titles
			233
		Tables
			Table 1
	Page 16
		Titles
			234
		Tables
			Table 1
	Page 17
		Titles
			235
			~o
		Tables
			Table 1
	Page 18
		Titles
			236
	Page 19
		Titles
			237
			8
			8
			o
			8
			o
			o
		Tables
			Table 1
	Page 20
		Titles
			238
			o
		Tables
			Table 1
	Page 21
		Titles
			239
	Page 22
		Titles
			240
			Stebbins: Dynamics and Structure of Melts: NMR Studies
	Page 23
		Titles
			Stebbins: Dynamics and Structure of Melts: NMR Studies
			241
	Page 24
		Titles
			242
			Stebbins: Dynamics and Structure of Melts: NMR Studies
	Page 25
		Titles
			Stebbins: Dynamics and Structure of Melts: NMR Studies
			243
	Page 26
		Titles
			244
			Stebbins: Dynamics and Structure of Melts: NMR Studies
	Page 27
		Titles
			245
	Page 28
		Titles
			246
			Stebbins: Dynamics and Structure of Melts: NMR Studies
Page 1
	Titles
		Chapter 8
		VIBRA TIONAL SPECTROSCOPY OF SILICATE LIQUIDS
		Paul F. McMillan and George H. Wolf
Page 2
	Titles
		248
Page 3
	Titles
		249
		\'\"
		=
		:e
		\'\"
		~
		\'\"
		\'\"
		::
		\'\"
		- - - - - - - - - - -
Page 4
	Titles
		250
		..
		s fa
		•
		.s
		\'8
		.......
		E 2
	Tables
		Table 1
Page 5
	Titles
		251
Page 6
	Titles
		252
Page 7
	Titles
		253
Page 8
Page 9
	Titles
		255
Page 10
	Titles
		256
Page 11
	Titles
		257
Page 12
	Titles
		258
Page 13
	Titles
		259
		aln V v sv
		y: = ---\' = ---\'
		a=.!.(av) =(alnV) ,
		vs.sr ), st p
		YiT=_.!.(alnVi) = __ 1 (aVi) .
		, a st p aviaTp
Page 14
	Titles
		260
		~= ~;(:~J: .
		--\' =--=
		coc Vi e
Page 15
	Titles
		261
		_ 1
		s
		c
		\'\"
		~
		:c
		...
		\"
		~
		\"
		\'\"
		..,
		s
		\'\"
		...
		...
		~
		b
	Tables
		Table 1
Page 16
	Titles
		262
Page 17
	Titles
		McMillan & Wolf: Spectroscopy of Silicate Liquids
		263
		Vi dq,
		Linewidths and Iineshapes
		, 3c2 dq,
Page 18
	Titles
		264
Page 19
	Titles
		265
Page 20
	Titles
		266
Page 21
	Titles
		267
Page 22
	Titles
		268
		c e -1
Page 23
	Titles
		269
Page 24
	Titles
		no
		a
		o
		b
	Tables
		Table 1
Page 25
	Titles
		271
Page 26
	Tables
		Table 1
Page 27
	Titles
		273
Page 28
	Titles
		274
		a
		\'(, ...
		. ~ \'.. I
		.. \'. ,I.!+ttl
		-.,,~ .. ,-~ I+.~l I~ h
		b
		.~
Page 29
	Titles
		275
Page 30
	Titles
		276
		McMillan & Wolf: Spectroscopy of Silicate Liquids
		(f) Raman
		(e) Neutron spectrum giro)
		(a) Raman
		(b) Infrared
		tc) Dielectric function
		(g) Infrared absorption
		(d) IR energy loss
		wauenumber cm-I
Page 31
	Titles
		277
Page 32
Page 33
	Titles
		279
		.~
Page 34
	Titles
		280
		-=-~.~
Page 35
	Tables
		Table 1
Page 36
	Titles
		282
REV032C008_p283-316.pdf
	Page 1
		Titles
			283
	Page 2
		Titles
			284
			McMillan & Wolf: Spectroscopy of Silicate Liquids
	Page 3
		Titles
			285
			Rllc::all tetrasilicate glasses
			Cs
			Na
			li
	Page 4
	Page 5
		Titles
			287
	Page 6
		Titles
			288
			McMillan & Wolf: Spectroscopy of Silicate Liquids
			K Si 0
			Raman shift (cm-1)
			•
		Tables
			Table 1
			Table 2
			Table 3
	Page 7
		Titles
			289
	Page 8
		Titles
			\'\"
			\'\"
			\'\"
			\'\"
			\'\"
			\'\"
		Tables
			Table 1
	Page 9
		Titles
			291
	Page 10
		Titles
			292
	Page 11
		Titles
			293
			Raman shift (cm-1)
	Page 12
	Page 13
		Titles
			295
			vv
			JM
			I ~ I~li
			___/ / ~/ .. \'\\
			r-/\".
			..
			. .:
	Page 14
		Titles
			296
			McMillan & Wolf: Spectroscopy of Silicate Liquids
			/ !.:.\\ ->>
			,... I\" /
			,i. \". \\/
			j\' N~\\\\\\ __ 1 .. 7.:\\v
			\\ I\'!\\ /r- \'\\
			~n~zu/ \\
			-\' \\
			7IO,ftoJ \\
			\\_.
	Page 15
		Titles
			297
			McMillan & Wolf: Spectroscopy of Silicate Liquids
			~ ~
	Page 16
		Titles
			298
	Page 17
		Titles
			299
	Page 18
		Titles
			300
	Page 19
		Titles
			McMillan & Wolf: Spectroscopy of Silicate Liquids
			I
			a
			b
			o
	Page 20
		Titles
			302
	Page 21
		Titles
			303
			18
			28
			48
			18
			~
	Page 22
		Titles
			304
	Page 23
		Titles
			305
	Page 24
		Titles
			306
			McMillan & Wolf: Spectroscopy of Silicate Liquids
	Page 25
		Titles
			McMillan & Wolf: Spectroscopy of Silicate Liquids
			307
	Page 26
		Titles
			308
			McMillan & Wolf: Spectroscopy of Silicate Liquids
	Page 27
		Titles
			McMillan & Wolf: Spectroscopy of Silicate Liquids
			309
	Page 28
		Titles
			310
	Page 29
		Titles
			311
	Page 30
		Titles
			312
			McMillan & Wolf: Spectroscopy of Silicate Liquids
	Page 31
		Titles
			McMillan & Wolf: Spectroscopy of Silicate Liquids
			313
	Page 32
		Titles
			314
			McMillan & Wolf: Spectroscopy of Silicate Liquids
	Page 33
		Titles
			McMillan & Wolf: Spectroscopy of Silicate Liquids
			315
	Page 34
Page 1
	Titles
		Chapter 9
		X-RA Y SCATTERING AND X-RAY SPECTROSCOPY
		Gordon E. Brown, Jr.
		Francois Farges
		Georges Calas
Page 2
Page 3
Page 4
Page 5
Page 6
	Tables
		Table 1
Page 7
	Titles
		Brown, Farges & Calas: X-ray Scattering and Spectroscopy Studies 323
	Tables
		Table 1
Page 8
	Titles
		(1)
Page 9
	Tables
		Table 1
Page 10
	Titles
		I\' 2
Page 11
	Tables
		Table 1
Page 12
Page 13
	Titles
		,,:
Page 14
	Titles
		330 Brown, Farges & Calas: X-ray Scattering and Spectroscopy Studies
		Radial distribution function of silica glass
		4000--------------------------------------------------------------------------l
Page 15
	Titles
		~
Page 16
	Titles
		16
		o
		OJ--=:::tl\\ {Ix l \\} \\ I\' V \\ I >\" (\'\\ \"\"\"\'d
		...
Page 17
Page 18
	Titles
		334 Brown, Farges & Calas: X-ray Scattering and Spectroscopy Studies
	Tables
		Table 1
		Table 2
Page 19
	Titles
		0~9.,\"\'/\\,
		/\\
Page 20
Page 21
	Titles
		.:
		...
		~
Page 22
Page 23
Page 24
	Titles
		r,A
Page 25
	Tables
		Table 1
Page 26
Page 27
	Titles
		:\\.-.--\'\'\'--,--~
Page 28
Page 29
	Titles
		Brown, Farges & Calas: X-ray Scattering and Spectroscopy Studies 345
	Tables
		Table 1
Page 30
	Titles
		q_ .... _ e ~ 0::.::;0
		s= k:~ <1\"\'-
		~ R: ... _
Page 31
Page 32
REV032C009_p349-380.pdf
	Page 1
		Titles
			c
			\'\"
			E
			\"
	Page 2
	Page 3
	Page 4
	Page 5
		Titles
			1 - 2/ 2
	Page 6
		Titles
			I o.J~
			] \'nW\', U
	Page 7
		Titles
			(17)
			_ kBT
			J~R
			o kBT
			g
			o
			ol------L\'~ ____,-/~
	Page 8
		Titles
			356 Brown, Farges & Calas: X-ray Scattering and Spectroscopy Studies
			(20)
			&» = \"\" -1 n (2k)20 + I C 4 k 2 (1 + RIA.)
			4 3 2( 1 I)
			hn.=--C k -4kcr -+-
			\'-\"I\' 3 3 R A.
		Tables
			Table 1
			Table 2
	Page 9
	Page 10
		Titles
			a=--\"\"----
			a = __ 3
		Tables
			Table 1
	Page 11
		Tables
			Table 1
	Page 12
		Titles
			kBT
			- o . ....L-?-~~A--;.-......r--r\"\"\"r....,.
	Page 13
	Page 14
	Page 15
	Page 16
	Page 17
		Titles
			Brown, Farges & Calas: X-ray Scattering and Spectroscopy Studies 365
			5100
			5050
			5000
			ENERGY (eV)
		Tables
			Table 1
			Table 2
	Page 18
	Page 19
	Page 20
	Page 21
		Titles
			Be
	Page 22
		Titles
			c
	Page 23
	Page 24
		Titles
			.~ ~ ~g~
	Page 25
	Page 26
		Tables
			Table 1
	Page 27
		Tables
			Table 1
	Page 28
		Titles
			8300 8350 8400 8450 8300 8350 8400 8450
	Page 29
		Tables
			Table 1
	Page 30
	Page 31
	Page 32
REV032C009_p381-410.pdf
	Page 1
	Page 2
		Titles
			[(RO - R)]
	Page 3
		Titles
			~
			\'\"
			\"
	Page 4
		Titles
			384 Brown, Farges & Calas: X-ray Scattering and Spectroscopy Studies
			_O.44~
			~i\'
	Page 5
	Page 6
	Page 7
	Page 8
		Titles
			388 Brown, Farges & Calas: X-ray Scattering and Spectroscopy Studies
			0\\\'
			.....
			8 !:I
			~ ~
			~~
			~08
			\'N
			~
			~ ~ v: ~ ~ ~ ~ ~ v: ~ ~ r-: r-: r-: r-: r-: r-: r-: r-: r-: r-: ~ ~I~ ~I~ ~ r-: 0;
			................................ --------------------~----
			\"\'.
			0000
			~~~~
			o
			~
			o
			~
			\'\"
			o
			~
			~ ~I N
			=: 6~
			~ , .....
			e C
			=
			rIl U1_
			- \'\"
			!\"i~u
			\'\"
			~·~I\"OIO
			~ = § . .!.
			\';illCZl
			=
			\'\"
			.! \"8 tl
			= ;5 ;...
			... ::E ~
			ei
			~
			·:lgl~
			\'\"
			~
			.~
			e
			~ 8, \'\"
		Tables
			Table 1
	Page 9
		Titles
			B~ ~ ~ B
	Page 10
		Titles
			- -
			-
			\':?
			:0-
			o
			~
			t.!.~
			o
			\'\" I\'\" I\'\" IS\'::: I::: 100
			~ ~ ~
			.........
			~ ~
			o
			\'\"
			~
			o
			i
			z
	Page 11
		Titles
			\\0 \"\'~i aX
Page 25
	Titles
		435
Page 26
	Titles
		436
		·· ...... · .... · .... ··· ..... \'-rlfll.
		.
	Tables
		Table 1
Page 27
	Titles
		437
Page 28
	Titles
		•
	Tables
		Table 1
Page 29
	Titles
		y
		1 E1
		439
Page 30
	Titles
		440
Page 31
	Titles
		441
Page 32
	Titles
		442
		r
		I LIQUID I
		t :(:v)--
		~ ~
		1fT (K)
		I GLASS I
REV032C010_p443-474.pdf
	Page 1
		Titles
			443
	Page 2
		Titles
			444
			D = A exp ( - R (#-T2) ReT)-
	Page 3
		Titles
			445
			1500
			1200
			900
		Tables
			Table 1
	Page 4
		Titles
			446
			1 rr (K)
			b
			1 rr (K)
	Page 5
		Titles
			447
	Page 6
		Titles
			448
	Page 7
		Titles
			Chakraborty: Diffusion in Silicate Melts
			449
			GLASS
			LIQUID
	Page 8
		Titles
			450
			Chakraborty: Diffusion in Silicate Melts
	Page 9
		Titles
			451
	Page 10
		Titles
			452
	Page 11
		Titles
			453
	Page 12
		Titles
			454
	Page 13
		Titles
			455
	Page 14
		Titles
			456
	Page 15
		Titles
			457
			Use of exact relationships.
	Page 16
		Titles
			458
			a
			qj = ax [JLj - JLn]
			~ aJLj ~ aJLk
			c: aC~k =,l,...J aC~j·
	Page 17
		Titles
			459
	Page 18
		Titles
			460
	Page 19
		Titles
			461
	Page 20
		Titles
			462
	Page 21
		Titles
			463
	Page 22
		Titles
			464
	Page 23
		Titles
			465
	Page 24
		Titles
			466
	Page 25
		Titles
			467
	Page 26
		Titles
			468
			C(t ,x)
			= C1 +Cz + 2( e1 -Cz) ;... ..!.exp [ -Dl2Tf2t 1 cos [wrrx ]Sin [wrrx i 1
	Page 27
		Titles
			469
			D( N;) = (N; - N2) V J Hz*) i( 1 - YO) f ~ dx + Y*] \\; Y dx I
			N; - N;
	Page 28
		Titles
			470
	Page 29
		Titles
			471
	Page 30
		Titles
			472
	Page 31
		Titles
			473
			( A) = (Llui) J ( w)
			(Llui)
	Page 32
		Titles
			474
REV032C010_p475-504.pdf
	Page 1
		Titles
			475
			Uncertainties in diffusion data
	Page 2
		Titles
			476
	Page 3
		Titles
			477
			W(X, n)
			_1 exp(-£).
			2nJ...2
			2D = (rlJ...i+r2J...~+ ... +rnJ...~).
	Page 4
		Titles
			478
	Page 5
		Titles
			479
	Page 6
		Titles
			480
			_1_ [L ((6r/m))2) + L (6r/rriJ.6r/n))]
			6 VkT m t 111 n; mm t
	Page 7
		Titles
			481
	Page 8
		Titles
			482
	Page 9
		Titles
			483
			VIII. DIFFUSION DATA IN SILICATE MELTS
	Page 10
		Titles
			484
	Page 11
		Titles
			485
	Page 12
		Titles
			486
	Page 13
		Titles
			487
			le4/T(K)
			\'U\'
			E~
			•
			•
	Page 14
		Titles
			488
	Page 15
		Titles
			489
			a
			c
			o~
			o
	Page 16
		Titles
			490
	Page 17
		Titles
			491
			°
			.I
			-1\\
			~/
			ii
			iii
			~i:
			\\/.,/
			/
			/ \\ \\\\
			/\\ \\\\
			-:
	Page 18
		Titles
			492
			..
			~
			•
			J 300r An - Ab
			•
			.. ..
			o
			I
			•
			•
			•
			•
			•
			I
	Page 19
		Titles
			493
	Page 20
		Titles
			494
	Page 21
		Titles
			Chakraborty: Diffusion in Silicate Melts
			495
			REFERENCES
	Page 22
		Titles
			496
			Chakraborty: Diffusion in Silicate Melts
	Page 23
		Titles
			Chakraborty: Diffusion in Silicate Melts
			497
	Page 24
		Titles
			498
			Chakraborty: Diffusion in Silicate Melts
	Page 25
		Titles
			Chakraborty: Diffusion in Silicate Melts
			499
	Page 26
		Titles
			500
			Chakraborty: Diffusion in Silicate Melts
	Page 27
		Titles
			Chakraborty: Diffusion in Silicate Melts
			501
	Page 28
		Titles
			502
			Chakraborty: Diffusion in Silicate Melts
	Page 29
		Titles
			Chakraborty: Diffusion in Silicate Melts
			503
	Page 30
Page 1
	Titles
		Chapter 11
		PRESSURE EFFECTS ON SILICATE MELT
		George H. Wolf and Paul F. McMillan
Page 2
Page 3
	Titles
		\".
		o
		o
	Tables
		Table 1
Page 4
	Titles
		s
		....
Page 5
Page 6
Page 7
Page 8
	Titles
		512
	Tables
		Table 1
Page 9
	Titles
		Wolf & McMillan: Pressure Effects on Structure and Properties 513
Page 10
Page 11
Page 12
	Titles
		516 Wolf & McMillan: Pressure Effects on Structure and Properties
		GPa is qualitatively similar to that of stishovite at the same pressure (Williams et aI.,
		;:a
	Tables
		Table 1
Page 13
Page 14
	Titles
		-
		a
		U5
		o
		Pressure (GPa)
Page 15
	Titles
		Wolf & McMillan: Pressure Effects on Structure and Properties
		519
		1 5.0t
		Longitudinal
		Shear
		> 6
		a
		•
		•
		•
		•
		•
		•
		•
		v
		•
		v
		••• • •
		•
		•
		C o
		eO
		C§
		B
		•
		••
		•
		,
		b
		•
		~§ 4
		!:9
		\"
		VB =~K/p
Page 16
Page 17
Page 18
Page 19
	Titles
		Wolf & McMillan: Pressure Effects on Structure and Properties
		523
		•
		• •
		•
	Tables
		Table 1
		Table 2
Page 20
	Titles
		524 Wolf & McMillan: Pressure Effects on Structure and Properties
		b
		~::::
		a
		..
		..
		..
		,
		..
		.. :
		o
		.
		. .
		• ••
		. 1-\'-- • -:-- i
	Tables
		Table 1
Page 21
Page 22
Page 23
	Titles
		•
		•
		•
		•
		\\
		. (\\ ~t; .. \"
		~/\\ .\'
		~
		•
Page 24
Page 25
	Titles
		\"
		..
		1
Page 26
Page 27
Page 28
	Titles
		b
Page 29
	Titles
		Wolf & McMillan: Pressure Effects on Structure and Properties 533
		10 r---.---,-.,..-~--,---.---,
		o
		-
		-
Page 30
Page 31
	Titles
		C jl;de~omDressed
		A\' ~ :::~P\'
		~n \'A~
Page 32
	Titles
		.\"~~
		:::;:~
		~sio,\'
		~ \\ I
		I ~:.J •
		~:
Page 33
Page 34
Page 35
Page 36
Page 37
Page 38
REV032C011_p543-580.pdf
	Page 1
	Page 2
		Titles
			544 Wolf & McMillan: Pressure Effects on Structure and Properties
			~, /\" \\ I
			~~b ,~~
		Tables
			Table 1
	Page 3
	Page 4
		Titles
			r
	Page 5
		Titles
			Wolf & McMillan: Pressure Effects on Structure and Properties
			547
		Tables
			Table 1
			Table 2
	Page 6
	Page 7
		Titles
			Frequency (em -1)
			Frequency (em -1)
		Tables
			Table 1
	Page 8
	Page 9
	Page 10
	Page 11
		Titles
			Wolf & McMillan: Pressure Effects on Structure and Properties 553
			REFERENCES
	Page 12
		Titles
			554 Wolf & McMillan: Pressure Effects on Structure and Properties
	Page 13
		Titles
			Wolf & McMillan: Pressure Effects on Structure and Properties 555
	Page 14
		Titles
			556 Wolf & McMillan: Pressure Effects on Structure and Properties
	Page 15
		Titles
			Wolf & McMillan: Pressure Effects on Structure and Properties 557
	Page 16
		Titles
			558 Wolf & McMillan: Pressure Effects on Structure and Properties
	Page 17
		Titles
			Wolf & McMillan: Pressure Effects on Structure and Properties 559
	Page 18
		Titles
			560 Wolf & McMillan: Pressure Effects on Structure and Properties
	Page 19
		Titles
			Wolf & McMillan: Pressure Effects on Structure and Properties 561
	Page 20
Page 21
	Titles
		Chapter 12
		COMPUTER SIMULATIONS OF SILICATE MELTS
		Peter H. Poole
		Paul F. McMillan and George H. Wolf
Page 22
	Titles
		564
Page 23
	Titles
		565
Page 24
	Titles
		566
		N 3 p~
		(2)
		 = - LL¢>;/r;,rj) == LL¢>;/r;,rj) , (3)
Page 25
	Titles
		567
		(6)
		(A),ime = (A(r(t)))time = lim ~ r\' A(r(t\'))dt\' (4)
		LA(k)P(k)
		f A(k)P(k)dk
		(A) - s: -.--_
		.s.
		P(k)=e kBT
Page 26
	Titles
		568
		(A)k = _!_ tACk) (9)
		The molecular dynamics method
Page 27
	Titles
		569
		f·=m·--l (12)
		1
		1
Page 28
	Titles
		570
		{A} = {A}k = {Atne
Page 29
	Titles
		571
Page 30
	Titles
		572
		o
		o 0
		o
		I.e ~ \" 0
		.;\'\'\';\'\' .... 0
		/ 0 0
		o
		o 10
		o 0 0
		o
		o 10
		o
		o
		o
Page 31
	Titles
		573
Page 32
	Titles
		574
	Tables
		Table 1
Page 33
	Titles
		575
Page 34
	Titles
		576
		,
		-. \\,-\",\' ------------
Page 35
	Titles
		577
Page 36
	Titles
		578
Page 37
	Titles
		579
Page 38
	Titles
		580
		2 ( (In]
REV032C011_p581-616.pdf
	Page 1
		Titles
			581
			z.z .e\' -rij