Stereochemistry and Stereoselective Synthesis: an Introduction

Content: Cover
 Title Page
 Copyright
 Contents
 About the Companion Website
 Introduction
 Part I Basic Concepts at the Molecular Level
 Part II Properties at the Level of Material Assemblies
 Part III General Characteristics of Stereoselective Reactions
 Part IV Applications of Enantioselective Methods
 Index
 EULA
 Chapter 1 Structure and Properties
 Chapter 2 Concepts of Stereochemistry
 Problems to Chapters 1 and 2
 Chapter 3 Timescale, Conformational Changes
 Chapter 4 Absolute Configuration
 Chapter 5 Methods for the Determination of Enantiomeric Composition
 Chapter 6 Tautomerism. Problems to Part IIChapter 7 Types and Classification of Selectivities
 Chapter 8 Stereoselective and Stereospecific Reactions
 Problems to Part III
 Chapter 9 Stoichiometric Methods of Enantioselective Synthesis
 Chapter 10 Catalytic Methods of Enantioselective Synthesis
 1.1 The Covalent Bond and the Octet Rule
 1.2 Representation of Chemical Structures
 1.3 Description of Chemical Structure
 1.4 Problems of Correlating Chemical Structure with Properties
 References
 2.1 Elements and Groups of Symmetry
 2.2 Classification of the Basic Concepts of Stereochemistry
 2.3 Stereodescriptors. 2.4 Prostereogenic Elements, ProchiralityReferences
 3.1 Conformational Motion of Ethane and Its Optical Inactivity
 3.2 Conformations and Optical Inactivity of n-Butane and 1,2-Dichloroethane
 3.3 Biphenyl and Substituted Biphenyls, Atropisomerism
 References
 4.1 Methods to Determine Absolute Configuration
 4.2 Strategies to Determine Absolute Configuration by Chemical Correlation
 References
 5.1 Chiroptical Methods
 5.2 NMR Methods Based on Diastereotopicity
 5.3 Chromatographic and Related Methods Based on Diastereomeric Interactions
 5.4 Kinetic Methods Based on Enantiomer Selectivity. 5.5 Fusion Methods5.6 Methods Based on Isotope Dilution
 5.7 Potentiometric Methods
 References
 6.1 Types of Tautomerism
 6.2 Prototropy
 6.3 Methods for Studying Tautomerism
 6.4 Nitrogen Inversion
 References
 7.1 Main Types of Selectivity
 7.2 Classification of Selectivities
 References
 8.1 Stereospecificity
 8.2 Stereoselectivity
 8.3 Selective Syntheses of Enantiomers
 8.4 Diastereomer Selectivity
 8.5 Diastereotope Selectivity
 8.6 Enantiomer Selectivity
 8.7 Enantiotope Selectivity
 8.8 Combination of More Than One Type of Selectivity
 References
 9.1 Diastereotope Selective Methods. 9.2 Enantiotope Selective Methods10.1 Chemical Catalysis
 10.2 Biocatalysis
 2.2.1 Concepts Related to a Single Object (Molecule) or Parts of Thereof
 2.2.2 Concepts Referring to the Relationship of Two Objects (Molecules) (Isomerism, Isomeric Relationship)
 2.2.3 Concepts Referring to the Relationship of Parts of an Object (Molecule) or Modes of Approach to an Object (Topicity)
 2.3.1 The d/l System, Fischer's Projection
 2.3.2 The R/S System
 2.3.3 Hindered Rotation around a Double Bond, E/Z Isomerism
 2.3.4 Axial Chirality, Helicity, M/P Descriptors.