Semiconducting Black Phosphorus: From 2D Nanomaterial to Emerging 3D Architecture (Emerging Materials and Technologies)

Cover
Half Title
Series Information
Title Page
Copyright Page
Table of Contents
Preface
Authors’ Biographies
1 General Overview of 2D Black Phosphorus
	1.1 Introduction
	1.2 Overview of Chapters
	1.3 Summary
	1.4 Acknowledgments
	References
2 Chemistry of Phosphorus
	2.1 Introduction
	2.2 Allotropes of Phosphorus
		2.2.1 White Phosphorus
			2.2.1.1 Toxicity
		2.2.2 Red Phosphorus
		2.2.3 Black Phosphorus
	2.3 Stability Study of Various Allotropes of Phosphorus
	2.4 Summary
	2.5 Acknowledgments
	References
3 2D Form of Black Phosphorus
	3.1 Introduction
	3.2 Synthetic Strategies/Morphological Engineering and Characterizations of Black Phosphorus
		3.2.1 Non-Epitaxial Growth
			3.2.1.1 Mechanical Cleavage Approach
			3.2.1.2 Liquid Phase Exfoliation
			3.2.1.3 Electrochemical Exfoliation
			3.2.1.4 Laser Irradiation
			3.2.1.5 Thermal Annealing
			3.2.1.6 Scalable Synthesis of 2D Black Phosphorus
		3.2.2 Epitaxial Growth
			3.2.2.1 Chemical Vapor Deposition
			3.2.2.2 Pulsed Laser Deposition
			3.2.2.3 Molecular Beam Epitaxy
	3.3 Stability Property and Defect Engineering of Black Phosphorus
	3.4 Properties and Application of 2D BP
		3.4.1 Bandgap
		3.4.2 On–Off Ratio/Mobility
		3.4.3 In-Plane Anisotropy
		3.4.4 Thermal Properties of Back Phosphorus
		3.4.5 Mechanical Properties of Black Phosphorus
		3.4.6 The Optical Property of Black Phosphorus
			3.4.6.1 Linear Optical Properties
			3.4.6.2 Nonlinear Optical Properties
		3.4.7 Electrical Properties of Black Phosphorus
		3.4.8 Biodegradable Property of Black Phosphorus
	3.5 Summary
	3.6 Acknowledgments
	References
4 Composites and Heterostructures of Black Phosphorus
	4.1 Introduction
	4.2 Composites of Black Phosphorus With Polymers
	4.3 Heterostructures of Black Phosphorus With Graphene
	4.4 Heterostructures of Black Phosphorus With Transition Metal Dichalcogenides
		4.4.1 Heterostructures of Black Phosphorus With MOS2
		4.4.2 Heterostructures of Black Phosphorus With WS2
		4.4.3 Heterostructures of Black Phosphorus With WSe2
	4.5 Summary
	4.6 Acknowledgments
	References
5 3D Structures Based On 2D BP
	5.1 Why 3D Structures of BP Are Important
	5.2 Morphological Engineering of 3D Architecture of BP
		5.2.1 Honeycomb-Lantern-Inspired 3D Structures of 2D Black Phosphorus
		5.2.2 3D-Printed Scaffolds From 2D Black Phosphorus
		5.2.3 Black Phosphorus Sponges By the Modified Electrochemical Approach
		5.2.4 Graphene Oxide/Black Phosphorus 3D Nanoflakes Aerogel
		5.2.5 Cellulose/BP Nanosheets (BPNSs)-Based Hydrogel Possesses 3D Networks
		5.2.6 Palladium Nanoparticles and Black Phosphorus Hybrids 3D Structure
	5.3 Comparison of 3D Structures of BP With Other 3D Structures of 2D Layered Materials
		5.3.1 3D Structures of Graphene
			5.3.1.1 3D Graphene Network From GO-Derived Structures
		5.3.2 3D Structures of Transition Metal Dichalcogenides
			5.3.2.1 MoS2
			5.3.2.2 WS2
		5.3.3 3D Structures of Boron Nitride
		5.3.4 Comparison of 3D Structures of BP With Other 3D Structures of 2D Layered Materials
	5.4 Summary
	5.5 Acknowledgments
	References
6 Emerging Applications of 3D Structures of BP
	6.1 Introduction
	6.2 3D Architecture of BP in Optoelectronics
		6.2.1 Photo-Detectors
		6.2.2 Biomedical-Based Applications
			6.2.2.1 Photothermal Performance
			6.2.2.2 Tissue Engineering
		6.2.3 Energy Storage Devices
			6.2.3.1 Li-Ion Batteries
		6.2.4 Supercapacitors
		6.2.5 Catalysis
			6.2.5.1 Electrocatalysis
			6.2.5.2 Photocatalysis
	6.3 Conclusion
	6.4 Acknowledgments
	References
7 Brief Summary and Future Directions
	7.1 Brief Summary
	7.2 Future Directions
	7.3 Conclusions
	7.4 Acknowledgments
	References
Index