Phase Equilibria With Supercritical Carbon Dioxide: Application to the Components of a Biocatalytic Process

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Phase Equilibria With Supercritical Carbon Dioxide: Application to the Components of a Biocatalytic Process
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Table of Contents
1. Supercritical Fluids: Properties and Applications
	Abstract
	1. Introduction
	2. Properties of supercritical fluids
	3. Supercritical carbon dioxide (scCO2)
	4. Applications of supercritical fluids
		4.1 Extraction with supercritical fluids
		4.2 Formation of particles by supercritical technology
			4.2.1 Rapid expansion of supercritical solutions (RESS)
			4.2.2 GAS antisolvent process (GAS)
			4.2.3 Supercritical antisolvent process (SAS)
			4.2.4 Solution-enhanced dispersion by supercritical fluids (SEDS)
			4.2.5 Particles from gas-saturated solutions (PGSS)
			4.2.6 Particles from gas-saturated solutions drying (PGSS drying)
			4.2.7 Supercritical fluid-assisted atomization (SAA)
		4.3 Reactions in supercritical fluids
			4.3.1 Homogeneous catalytic reactions in supercritical carbon dioxide
			4.3.2 Heterogeneous catalytic reactions in supercritical carbon dioxide
			4.3.3 Supercritical biocatalysis
				4.3.3.1 Enzymatic reactions in supercritical carbon dioxide (scCO2)
				4.3.3.2 scCO2/H2O biphasic systems
				4.3.3.3 scCO2/ionic liquid biphasic systems
		4.4 Other applications
	5. Conclusions
	References
2. High-Pressure Fluid Phase Equilibria
	Abstract
	1. Introduction
	2. Experimental acquisition of high-pressure fluid phase equilibrium data
		2.1 Analytical methods
		2.2 Synthetic methods
	3. Classification of the phase diagrams for binary mixtures
	4. Thermodynamic modeling of high-pressure fluid phase equilibria
		4.2 Mixing rules
		4.1 Equations of state
	5. Conclusion
	References
3. Application of Supercritical Phase Equilibria to the Components of the Transesterification Reaction of rac-2-Pentanol with a Vinyl Ester
	Abstract
	1. Introduction
	2. Apparatus and experimental procedure
	3. Results and discussion
		3.1 Experimental phase equilibrium data
		3.2 Density-based models
		3.3 Thermodynamic modeling
	4. Conclusions
	References