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ویرایش: سری: ISBN (شابک) : 9783527271504, 9783527600397 ناشر: Wiley-VCH Verlag GmbH سال نشر: 2000 تعداد صفحات: 685 زبان: English فرمت فایل : PDF (درصورت درخواست کاربر به PDF، EPUB یا AZW3 تبدیل می شود) حجم فایل: 8 مگابایت
در صورت تبدیل فایل کتاب Peroxide Chemistry: Mechanistic and Preparative Aspects of Oxygen Transfer به فرمت های PDF، EPUB، AZW3، MOBI و یا DJVU می توانید به پشتیبان اطلاع دهید تا فایل مورد نظر را تبدیل نمایند.
توجه داشته باشید کتاب شیمی پراکسید: جنبه های مکانیکی و آماده سازی انتقال اکسیژن نسخه زبان اصلی می باشد و کتاب ترجمه شده به فارسی نمی باشد. وبسایت اینترنشنال لایبرری ارائه دهنده کتاب های زبان اصلی می باشد و هیچ گونه کتاب ترجمه شده یا نوشته شده به فارسی را ارائه نمی دهد.
This collection of thirty articles on research projects in all
areas of peroxide chemistry, i. e. analytical, biochemical,
inorganic, organic, organometallic, physical, spectroscopic,
and theoretical facets, are the result of a multidisciplinary
research program funded by the Deutsche Forschungsgemeinschaft
(DFG). The emphasis was to lie on the development of
environmentally acceptable, selective (chemo-, regio-,
diastereo- and enantioselectivity) oxidations. One chapter
focuses on industrial applications which have to meet both
economical and ecological demands to remain competitive in the
future. Latest results on the consequences of lipid
peroxidation in age-dependent diseases, which range from
Alzheimer and Parkinson disorders to diabetes, rheumatic
arthritis, atherosclerosis and cardiovascular diseases are also
presented. Content:
Chapter 1 Landmarks in the Development of Organic Peroxide
Chemistry (pages 1–38): Manfred Schulz
Chapter 1 Recent Advances in Homogeneous Catalyzed Epoxidations
Using Hydrogen Peroxide or tert.?Butyl Hydroperoxide (pages
39–59): Thomas Kratz and Werner Zei?
Chapter 2 Photoinduced Electron?Transfer Reactions of Alkenes
and Azide Anions in the Presence of Molecular Oxygen: Formation
of 1,2?Azidohydroperoxides and Use As Oxygen?Transfer Reagents
(pages 60–77): Axel G. Griesbeck, Jorg Steinwascher and Thomas
Hundertmark
Chapter 3 Preparative Use of Peroxidic Oxidants for
Oxygen?Transfer Reactions (pages 78–112): Waldemar Adam,
Hans?Georg Degen, Aurelia Pastor, Chantu R. Saha?Moller, Simon
B. Schambony and Cong?Gui Zhao
Chapter 4 Organosulfonic and Sulfonimidic Peracids – New
Oxidants for Diastereoselective and Enantioselective Oxidations
of Organic Substrates (pages 113–127): Manfred Schulz and Ralph
Kluge
Chapter 5 Reactive Peroxo Compounds Generated in Situ from
Hydrogen Peroxide: Kinetics and Catalytic Application in
Oxidation Processes (pages 128–138): Horst Elias and Stephane
Vayssie
Chapter 6 Carbonyl O?Oxides and Dioxiranes – From Laboratory
Curiosities to Useful Reagents (pages 139–156): K. Block, W.
Kappert, A. Kirschfeld, S. Muthusamy, K. Schroeder, W. Sander,
E. Kraka, C. Sosa and D. Cremer
Chapter 7 Formation of Dioxiranes and Singlet Molecular Oxygen
by the Ketone?Catalyzed Decomposition of Peroxycarboxylic Acids
(pages 157–176): Andreas Lange and Hans?Dieter Brauer
Chapter 1 Age and Age?Dependent Diseases, a Consequence of
Lipid Peroxidation (pages 177–208): Gerhard Spiteller, Dieter
Spiteller, Wolfgang Jira, Uwe Kie?ling, Angela Dudda, Michael
Weisser, Stefan Hecht and Caroline Schwarz
Chapter 2 New Peroxycarboxylic Acids by Lipase Catalysis:
Preparation and Oxidation Properties (pages 209–231): Siegfried
Warwel and Mark Rusch gen. Klaas
Chapter 3 Transition?Metal?Catalyzed Oxyfunctionalization of
Catechol and Flavonol Derivatives (pages 232–248): Florian
Schweppe, Holger Sirges, Matthias Pascaly, Mark Duda, Cetin
Nazikkol, Werner Steinforth and Bernt Krebs
Chapter 4 Binding and Activation of Dioxygen by Biomimetic
Metal Complexes (pages 249–280): Ernst?G. Jager, Jutta Knaudt,
Kerstin Schuhmann and Anka Guba
Chapter 5 Transition Metal?Catalyzed Stereoselective Synthesis
of Functionalized Tetrahydrofurans (pages 281–300): Simone
Drees, Marco Greb, Jens Hartung and Philipp Schmidt
Chapter 1 Metallosalen?Catalyzed Asymmetric Oxygen?Transfer
Reaction: Dynamics of Salen Ligand Conformation (pages
301–319): Tsutomu Katsuki
Chapter 2 Transition?Metal Catalyzed Epoxidation of
Unfunctionalized Alkenes (pages 320–340): Andreas Scheurer,
Paul Mosset, Martina Spiegel and Rolf W. Saalfrank
Chapter 3 Peroxo Complexes of Molybdenum, Tungsten and Rhenium
with Phase Transfer Active Ligands: Catalysts for the Oxidation
of Olefins and Aromatics by Hydrogen Peroxide and
Bistrimethylsilyl Peroxide (pages 341–364): Carsten Jost,
Gunter Wahl, Dirk Kleinhenz and Jorg Sundermeyer
Chapter 4 Kinetic Resolution by Jacobsen Epoxidation as an Easy
Route to Podophyllotoxin Analoga (pages 365–380): Torsten
Linker, Ulrike Engelhardt and Arunkanti Sarkar
Chapter 5 Preparation of Optically Active Hydroperoxides and
Their Use for Stereoselective Oxygen Transfer (pages 381–405):
Hans?Jurgen Hamann, Eugen Hoft and Jurgen Liebscher
Chapter 6 New Early Transition?Metal Complexes as Homogeneous
Catalysts for Olefin Oxidation (pages 406–432): Wolfgang A.
Herrmann, Jorg Fridgen and Joachim J. Haider
Chapter 7 Olefin Epoxidation Catalyzed by Molybdenum Peroxo
Complexes: A Mechanistic Study (pages 433–453): Werner R.
Thiel, Michael Barz, Holger Glas and Anna?Katharina
Pleier
Chapter 8 Oxidation Reactions in Perfluorinated Solvents (pages
454–468): Bodo Betzemeier and Paul Knochel
Chapter 9 Transition?Metal Alkoxide?Catalyzed Oxidation of
Phenols, Alcohols, and Amines with tert.?Butyl hydroperoxide
(pages 469–493): Horst Adam, Karameli Khanbabaee, Karsten
Krohn, Jochen Kupke, Hagen Rieger, Klaus Steingrover and
Ingeborg Vinke
Chapter 10 Enantioselective Baeyer–Villiger Reactions and
Sulfide Oxidations (pages 494–510): Carsten Bolm
Chapter 11 Chiral Pentacoordinated Manganese Complexes As
Biomimetic Catalysts for Asymmetric Epoxidations with Hydrogen
Peroxide (pages 511–525): Albrecht Berkessel, Thomas
Schwenkreis, Matthias Frauen?Kron, Adrian Steinmetz, Norbert
Schatz and Jochen Prox
Chapter 12 Photocatalytic Activation of Oxygen by
Iron(III)porphyrins (pages 526–541): Horst Hennig and Doritt
Luppa
Chapter 13 Oxidation and Oxygenation of Substituted Arenes with
Alkyl Hydroperoxides or Dioxygen/Mediation by Schiff?Base
Complexes (pages 542–566): Anton Rieker, Stefan Forster and
Emerich Eichhorn
Chapter 1 The Nature of the Transition Structures for Oxygen
Atom Transfer from Peroxy Acids, Dioxiranes and Chiral
Bis(silyl) Peroxides (pages 567–600): Robert D. Bach
Chapter 2 Mechanistic Aspects of Transition?Metal?Catalyzed
Olefin Epoxidation from Density Functional Studies (pages
601–619): Notker Rosch, Philip Gisdakis, Ilya V. Yudanov and
Cristiana Di Valentin
Chapter 3 Near?UV Photolysis of Singlet Oxygen Generated by
Energy Transfer from Aromatic Molecules in Rare?Gas Matrices
(pages 620–639): Murthy S. Gudipati, Robert Wagner, Martin Kalb
and Andreas Klein
Chapter 4 Transition?Metal Ion Chemistry of Peroxides in the
Gas Phase (pages 640–664): Detlef Schroder, Christoph A.
Schalley and Helmut Schwarz