Oxyl-, Peroxyl- and Related Radicals

General introduction....Pages 1-4
8.1.0 Introduction....Pages 5-6
8.1.1 Radical-radical reactions....Pages 6-8
8.1.2 Unimolecular reactions....Pages 8-11
8.1.3.1 Absolute rate constants....Pages 12-26
8.1.3.2.1 Methoxyl radicals....Pages 26-30
8.1.3.2.3 Alkoxyl radicals with three carbon atoms....Pages 31-32
Part 1....Pages 32-43
Part 2....Pages 44-55
Part 3....Pages 56-67
Part 4....Pages 68-78
8.1.3.2.6 Cumyloxyl radicals....Pages 78-79
Part 1....Pages 79-91
Part 2....Pages 92-104
Part 3....Pages 105-116
8.1.4.3 - 8.1.4.9 Other alkoxyl radicals with four to ten carbon atoms....Pages 116-123
8.1.5 Miscellaneous....Pages 123-127
8.2 Acyloxyl radicals....Pages 127-138
References for 8.1 and 8.2....Pages 138-141
8.3.0 Introduction....Pages 142-142
8.3.1.1 Self-reactions....Pages 143-159
8.3.1.2 Self-reactions exhibiting first-order kinetics....Pages 160-161
8.3.1.3 Radical-dimer equilibria....Pages 161-166
8.3.1.4 Reactions involving a different radical....Pages 166-168
8.3.2 Unimolecular reactions....Pages 168-170
8.3.3.1 Reactions of phenoxyl radicals with hydrocarbons....Pages 171-172
8.3.3.2 Reactions of phenoxyl radicals with alcohols....Pages 172-173
8.3.3.4 Reactions of phenoxyl radicals with hydroperoxides....Pages 173-175
8.3.3.5 Reactions of phenoxyl radicals with peroxides....Pages 176-178
8.3.3.6 Reactions of phenoxyl radicals with phenols....Pages 178-186
8.3.3.7 Reactions of phenoxyl radicals with aromatic amines....Pages 187-188
8.3.3.9 Electron transfer reactions of phenoxyl radicals....Pages 188-192
8.3.3.10 Reactions of phenoxyl radicals with miscellaneous compounds....Pages 192-193
8.4 Hydroperoxyl radical....Pages 193-205
8.5.0 Introduction....Pages 205-206
8.5.1.1.1 Alkylperoxyls....Pages 206-214
8.5.1.1.2 Alkenylperoxyls....Pages 214-218
8.5.1.1.3 Alkynylperoxyl....Pages 218-218
8.5.1.1.4 Aralkylperoxyls....Pages 219-226
8.5.1.1.5 alpha-Hydroxyalkylperoxyls....Pages 226-228
8.5.1.1.6 alpha-Ketoalkylperoxyls....Pages 228-231
8.5.1.1.7 alpha-Alkoxyalkylperoxyls....Pages 231-235
8.5.1.1.9 Acylperoxyls....Pages 235-236
8.5.1.1.11 alpha-Alkoxycarbonylalkylperoxyls....Pages 236-237
8.5.1.1.14 alpha- and beta-Aminoalkylperoxyls....Pages 237-239
8.5.1.1.15 alpha-Pyridylperoxyls....Pages 240-240
8.5.1.1.17 Polymeric peroxyls....Pages 241-244
8.5.1.1.18 Group IVB centered peroxyls....Pages 244-245
8.5.1.2 Radical-dimer equilibria of peroxyls....Pages 245-247
8.5.1.3 Reactions involving a different radical....Pages 247-253
8.5.2 Unimolecular reactions....Pages 254-257
8.5.3.1 Reactions of alkylperoxyl radicals with alkanes....Pages 257-263
8.5.3.2 Reactions of alkylperoxyl radicals with alkenes....Pages 263-273
Part 1....Pages 274-282
Part 2....Pages 283-292
8.5.3.5 Reactions of alkylperoxyl radicals with aralkenes....Pages 292-298
8.5.3.6 Reactions of alkylperoxyl radicals with alcohols....Pages 298-302
8.5.3.7 Reactions of alkylperoxyl radicals with ketones and quinones....Pages 302-309
8.5.3.8 Reactions of alkylperoxyl radicals with ethers....Pages 309-317
8.5.3.9 Reactions of alkylperoxyl radicals with aldehydes....Pages 317-318
8.5.3.10 Reactions of alkylperoxyl radicals with carboxylic acids....Pages 319-320
8.5.3.11 Reactions of alkylperoxyl radicals with esters....Pages 320-325
Part 1....Pages 325-336
Part 2....Pages 337-348
Part 3....Pages 349-360
Part 4....Pages 361-371
8.5.3.13 Reactions of alkylperoxyl radicals with hydroperoxides....Pages 371-373
8.5.3.14 Reactions of alkylperoxyl radicals with alkyl halides....Pages 373-375
8.5.3.15 Reactions of alkylperoxyl radicals with aliphatic amines....Pages 375-377
8.5.3.16 Reactions of alkylperoxyl radicals with aromatic amines....Pages 377-391
8.5.3.17 Reactions of alkylperoxyl radicals with pyridines....Pages 391-392
8.5.3.18 Reactions of alkylperoxyl radicals with imines....Pages 392-396
8.5.3.19 Reactions of alkylperoxyl radicals with amides....Pages 396-396
8.5.3.21 Reactions of alkylperoxyl radicals with hydroxylamines....Pages 397-398
8.5.3.22 Reactions of alkylperoxyl radicals with N-alkyl hydroxylamines....Pages 398-398
8.5.3.23 Reactions of alkylperoxyl radicals with sulfides....Pages 399-399
8.5.3.26 Electron transfer reactions of alkylperoxyl radicals with organic compounds....Pages 400-403
8.5.3.27 Reactions of alkylperoxyl radicals with trivalent phosphorus compounds....Pages 403-407
8.5.3.28 Reactions of alkylperoxyl radicals with transition metals and metal complexes....Pages 407-418
8.5.3.29 S{H}2-reactions of alkylperoxyl radicals at a metal center....Pages 419-421
8.5.3.30 Reactions of alkylperoxyl radicals with inorganic compounds....Pages 421-421
8.5.3.31 Reactions of alkylperoxyl radicals with miscellaneous compounds....Pages 422-422
References for 8.3 - 8.5....Pages 423-430
Appendix: Data added in proof....Pages 430-431