Oxygen Complexes and Oxygen Activation by Transition Metals

Front Matter....Pages i-ix
Opening Remarks....Pages 1-2
Bonding of Dioxygen to Transition Metals....Pages 3-16
Oxygen Binding by the Metalloproteins Hemerythrin, Hemocyanin, and Hemoglobin....Pages 17-32
Metal Oxo Complexes and Oxygen Activation....Pages 33-47
Kinetics of Formation of Biological Oxygen Carriers....Pages 49-60
Synthetic Dioxygen Carriers for Dioxygen Transport....Pages 61-85
Formation and Degradation of Cobalt Dioxygen Complexes....Pages 87-106
Reversible Complexes for the Recovery of Dioxygen....Pages 107-125
Summary — Dioxygen Complexes with Transition Metal....Pages 127-128
Summary — Oxygen Activation by Transition Metals....Pages 129-130
The Chemistry and Activation of Dioxygen Species (O 2 , O 2 -. , and HOOH) in Biology....Pages 131-148
Oxygen Activation by Neutrophils....Pages 149-174
Mechanisms of Dioxygen Activation in Metal-Containing Monooxygenases: Enzymes and Model Systems....Pages 175-187
Radical Cation Pathways for Selective Catalytic Oxidation by Molecular Oxygen....Pages 189-201
Vanadium Catalyzed Autoxidation of Hydrogen Sulfide....Pages 203-213
Copper Catalyzed Oxidative Carbonylation of Methanol to Dimethyl Carbonate....Pages 215-232
Dependence of Reaction Pathways and Product Distribution on the Oxidation State of Palladium Catalysts for the Reactions of Olefinic and Aromatic Substrates with Molecular Oxygen....Pages 233-251
Oxygen Activation and Oxidation Reactions on Metal Surfaces....Pages 253-264
Methane Oxidation at Metal Oxide Surfaces....Pages 265-272
The Activation of Oxygen by Metal Phosphorus Oxides — The Vanadium Phosphorus Oxide Catalyst....Pages 273-292
The Oxidation of Organic Compounds by Metal Complexes in Zeolites....Pages 293-303
Front Matter....Pages 305-305
Kinetics and Mechanisms of Degradation of Binuclear Cobalt Dioxygen Complexes....Pages 307-307
Methane Activation Over Lanthanide Oxides....Pages 308-308
Dioxygen Affinities of Some Synthetic Cobalt Schiff Base Complexes....Pages 309-309
Temporal Analysis of Products (TAP): A Unique Catalyst Evaluation System with Sub-Millisecond Time Resolution....Pages 310-310
Dioxygen Insertion into Metal-Carbon Bonds of Metalloporphyrins: Formation and Characterization of Alkylperoxy Metalloporphyrins....Pages 311-311
Iron Porphyrin Catalyzed Air Oxidation of Aldehydes and Alkenes....Pages 312-312
Oxidative Dimerization of Methane Over Sodium-Promoted Calcium Oxides....Pages 313-313
Synthesis and Metal Ion Affinities of a Binucleating Polyamine: Reversible Formation of a Cobalt Dioyxgen Complex....Pages 314-314
Potentiometric Determination of Stabilities of Cobalt(II) Complexes of Polyamine Schiff Bases and Their Dioxygen Adducts....Pages 315-315
Catalysis of Cobalt Schiff Base Complexes for the Oxygenation of Olefins. Mechanisms for the Ketonization Reaction....Pages 316-318
Selective Oxidation of Saturated Hydrocarbons by the Gif and Gif-Orsay Systems....Pages 319-319
The Formation, Characterization, and Reactivity of the Oxene Adduct of Tetra-Kis(2,6-Dichlorophenyl)Porphinato-Iron(III) Perchlorate in Acetonitrile....Pages 320-320
Preparation and Characterization of A Binuclear Iron(III)-Hydroxo-µ-Hydroxyperoxy Complex[(PH 3 PO) 4 (HO)Fe III (HOOH)Fe III (OH)(OPPh 3 ) 4 ](C10 4 ) 4 ....Pages 321-321
Autoxidation of Fe II (Dihydroxyphenanthroline) 3 ....Pages 322-322
Phosphine-Ruthenium(II)-Aquo Redox Chemistry: The Aerobic Catalytic Oxidation of Cyclohexene....Pages 323-323
The Oxidation of Organic Substrates By Molecular Oxygen; Catalysis By Ru(III) And Ru(III)-Edta....Pages 324-325
Oxygenation of Tryptophane Catalyzed by Polyamine Cobalt Dioyxgen Complexes....Pages 326-326
Resonance Raman Spectroscopy of the Fe(IV)=O Group in Peroxidase Intermediates....Pages 327-327
Reaction of Dioxygen with Synthetic Copper(I) Compounds of Biological Relevance....Pages 328-328
Front Matter....Pages 305-305
Thorough Elucidation of Oxygenation- and Oxidation-Mechanisms of Iron(II) Porphyrin on the Basis of a New Hypothesis for an Electron-Transfer Pathway....Pages 329-330
Back Matter....Pages 331-341