Oxygen Atom Transfer Reactions

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Contents
Foreword
Series Preface
	PREFACE
Preface
List of Contributors
Introductory Notes on Mechanisms in Oxygen Atom Transfer Reactions of Transition Metal Complexes
	Robert Bakhtchadjian1,*
	INTRODUCTION
		Transition Metal-oxo Complexes and their Formation
		Application of the Redox Concept in Oxidation Reactions
		Types of Reaction Mechanisms in Oxidation Processes and the Place of the Oxo-atom Transfer Reactions within their Classification
		The Role of Oxo-atom Transfer Reaction in Catalytic Oxidation Processes
		Electronic Structure and Nature of the Metal-oxygen Chemical Bonds in Metal-oxo Complexes
		General Types of Reactions of Metal-oxo Complexes
		Mechanisms of Oxygen Transfer Reactions of Metal-oxo Complexes
		Functionalization of the C-H Bond via Abstraction of a Hydrogen Atom Oxygen Rebound Mechanism
		Mechanisms of Catalytic Water Oxidation by the Participation of Transition Metal-oxo Moieties
		Spin State and Reactivity of Metal-oxo Complexes. Two Spin State and Multiple Spin State Reactivities in the Mechanisms of Oxo-atom Transfer Reactions
	SOME CONCLUDING REMARKS ON MECHANISMS OF OXYGEN ATOM TRANSFER REACTIONS
	CONSENT FOR PUBLICATION
	CONFLICT OF INTEREST
	ACKNOWLEDGEMENT
	REFERENCES
Bio-Inspired Dioxygen Activation and Catalysis By Redox Metal Complexes
	Guangjian Liao1 and Guochuan Yin1,*
	INTRODUCTION
		Dioxygen Activation and Catalytic Oxygenation by Cytochrome P450, Methane Monooxygenases With Their Synthetic Models
			1) P450 Mechanism
			2) sMMO and pMMO Mechanism
			3) Coreductant Involved Catalytic Oxidation
			4) The Reactivity of sMMO Like Diamond Core and its Lewis Acid Promoted Oxygenation
		Dioxygen Activation by Dioxygenases
			1) Dioxygenase Mechanism
			2) Dioxygenase-type Dioxygen Activation and Catalysis by Redox Metal Complexes
		New Strategies in Dioxygen Activation and Catalysis
			1) The Role of Hydrogen Bond in Enzymatic Dioxygen Activation
			2) Lewis Acid Promoted Dioxygen Activation and Catalysis
	CONCLUSIVE MARKS AND PERSPECTIVE
	CONSENT FOR PUBLICATION
	CONFLICT OF INTEREST
	ACKNOWLEDGEMENTS
	REFERENCES
Highlights of Oxygen Atom Transfer Reactions Catalysed by Nickel Complexes
	Anjana Rajeev1 and Muniyandi Sankaralingam1,*
	INTRODUCTION
		Oxygen Atom Transfer Reactions
		Oxidation Involving Hydrogen Atom Abstraction Reaction
		Complexes Exhibiting Both Oxygen Atom Transfer and Hydrogen Atom Abstraction Reactivity
	CONCLUSION
	CONSENT FOR PUBLICATION
	CONFLICT OF INTEREST
	ACKNOWLEDGEMENTS
	REFERENCES
Mechanisms of Some Heterogeneous Photocatalytic Reactions of Oxidation Occurring via Oxygen Atom Transfer
	Robert Bakhtchadjian1,*
	INTRODUCTION
		Photocatalytic Oxidation Reactions Occurring via Oxygen Atom Transfer
		About Two Classes of Heterogeneous Photocatalytic Reactions: Photogenerated Catalysis and Catalyzed Photolysis
		Oxygen Atom Transfer from Transition Metal Oxo-complexes in Heterogeneous Photocatalytic Redox Systems
	CONCLUSION
	CONSENT FOR PUBLICATION
	CONFLICT OF INTEREST
	ACKNOWLEDGEMENT
	REFERENCES
Subject Index
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