Nuclear Magnetic Resonance Spectroscopy of Cement-Based Materials

Front Matter....Pages I-XV
Front Matter....Pages 1-1
Characterization of the Calcium Silicate and Aluminate Phases in Anhydrous and Hydrated Portland Cements by 27 Al and 29 Si MAS NMR Spectroscopy....Pages 3-45
In Situ High Temperature Multinuclear NMR Study of Clinker Formation....Pages 47-55
 29 Si NMR Study of Chemical Shift Tensor Anisotropy of Tricalcium Silicate....Pages 57-68
Relationship between NMR 29 Si Chemical Shifts and FT-IR Wave Numbers in Calcium Silicates....Pages 69-78
Multiquantum (3Q and 5Q) MAS NMR Spectroscopy of Aluminium-27 in Solids....Pages 79-88
New Progress in High Resolution 27 Al and 17 O Solid State NMR (MAS and MQ-MAS) of Aluminium Bearing Phases....Pages 89-105
Time Resolved Very High Temperature NMR Study of the Cooling Process of CaO-Al 2 O 3 Liquids....Pages 107-116
Front Matter....Pages 117-117
C-S-H Structure Evolution with Calcium Content by Multinuclear NMR....Pages 119-141
The Structure of Calcium Silicate Hydrate: NMR and Raman Spectroscopic Results....Pages 143-158
 29 Si MAS NMR Spectroscopy of Poorly-Crystalline Calcium Silicate Hydrates (C-S-H)....Pages 159-168
Characterization of Protons in C-S-H Phases by Means of High-Speed 1 H MAS NMR Investigations....Pages 169-180
Structural Investigation of Calcium Silicate Hydrates by X-Ray Absorption Spectroscopy....Pages 181-188
NMR and Infrared Spectroscopies of C-S-H and Al-Substituted C-S-H Synthesised in Alkaline Solutions....Pages 189-196
The Structure, Stoichiometry and Properties of C-S-H Prepared by C 3 S Hydration Under Controlled Condition....Pages 197-207
Tricalcium Silicate Hydration at High Temperature. A 29 Si and 1 H NMR Investigation....Pages 209-215
Influence of Heat Treatment Kinetics on Calcium Silicate Hydrates Phase Evolution....Pages 217-225
Thermochemical and Macromolecular Approach of the C-S-H Structure....Pages 227-234
Front Matter....Pages 235-235
Hydration of Tricalcium Silicate by D 2 O: 29 Si and 2 H Solid State NMR Spectra....Pages 237-244
Kinetics of Reaction in Cementitious Pastes Containing Silica Fume as Studied by 29 Si MAS NMR....Pages 245-268
 29 Si Enrichment and Selective Enrichment for Study of the Hydration of Model Cements and Blended Cements....Pages 269-275
Front Matter....Pages 235-235
Alkali Activation of Reactive Silicas in Cements: In Situ 29 Si MAS NMR Studies of the Kinetics of Silicate Polymerization....Pages 277-286
Effect of Post Set Heat Treatment on Hydrate Formation in Reactive Powder Concrete Studied by 29 Si NMR....Pages 287-293
Tricalcium Aluminate and Silicate Hydration. Effect of Limestone and Calcium Sulfate....Pages 295-308
The Interaction of Polyvinylalcohol/Acetate with CA, C 3 A and C 3 S in MDF Materials, as Described by Spin-Propagation Across Heterogeneous Interfaces....Pages 309-320
Changes in Structure of CaAl 2 O 14 H 20 during Heat Treatments: X-ray Absorption Spectroscopy and 27 Al NMR Studies....Pages 321-329
Front Matter....Pages 331-331
Nuclear Relaxation of Water Confined in Reactive Powder Concrete....Pages 333-343
NMR Studies of Growth Dynamics in Hardening Cement Gels....Pages 345-354
NMR-Approach in the Study of the Influence a Nonionic Sufractant on Water State during Cement Hardening....Pages 355-361
A Study of Na-montmorillonite Additions Influence on Portland Cement Hydration by 1 H T 1 Relaxation....Pages 363-367
NMR Microscopy of Glass-Ionomer Cements....Pages 369-378
Influence of Fillers on Textural and Mechanical Properties of C 3 S Pastes....Pages 379-385
Water Extraction out of Mortar during Brick Laying: A NMR Study....Pages 387-395
Moisture Transport over the Brick/Mortar Interface....Pages 397-401
 27 Al MAS NMR Study on Cement Paste Degradation by Water....Pages 403-409
The Hardening of Portland Cement Studied by 1 H Stray-Field Imaging: Influence of Concentration and Evaporation Rate of Water....Pages 411-416
Bringing Applied Research into the Student’s Lab: Pulse NMR of Cement Based Materials....Pages 417-424
Back Matter....Pages 425-430