Molten salts handbook

Front Cover......Page 1
Title Page\r......Page 4
Copyright Page......Page 5
Table of Contents......Page 8
PREFACE......Page 6
ACKNOWLEDGMENT......Page 7
CHAPTER I. PHYSICAL PROPERTIES\r......Page 14
I.A. ATOMIC AND IONIC RADII, MELTING POINTS, AND BOILING POINTS OF SINGLE SALTS AND EUTECTICS\r......Page 16
I.Β. DENSITY\r......Page 54
I.C. VISCOSITY......Page 67
I.D. VAPOR PRESSURE......Page 78
I.E. SURFACE TENSION......Page 95
I.F. REFRACTIVE INDEX......Page 104
I.G. CRITICAL DATA......Page 108
CHAPTER II. THERMODYNAMIC  PROPERTIES\r......Page 112
II.A. LIQUID-LIQUID IMMISCIBILITY\r......Page 114
II.Β. METAL-MOLTEN SALT SYSTEMS\r......Page 119
II.C. METAL OXIDE-MOLTEN SALT SYSTEMS\r......Page 133
II.D. SILVER SALTS-MOLTEN SALT SYSTEMS\r......Page 135
II.Ε. PHASE-RULE STUDIES\r......Page 146
II.F. SOLUBILITY\r......Page 193
II.G. THERMAL DATA\r......Page 201
II.\rΗ. CRYOSCOPY AND RELATED THERMODYNAMIC STUDIES......Page 229
II.I.  EXPANSIVITY, COMPRESSIBILITY, ULTRASONIC, AND HIGH PRESSURE STUDIES\r......Page 265
CHAPTER III. ELECTROCHEMICAL PROPERTIES\r......Page 282
IIΙ.A. REFERENCE ELECTRODES AND EMF SERIES\r......Page 284
III.Β. ELECTRICAL CONDUCTANCE......Page 306
III.C. POLAROGRAPHY, CHRONOPOTENTIOMETRY, \nAND DOUBLE LAYER CAPACITY STUDIES......Page 337
IIΙ.D. ELECTROMIGRATION: TRANSPORT NUMBERS AND DIFFUSION......Page 361
III.Ε. DIELECTRIC AND THERMOELECTRIC PROPERTIES......Page 375
CHAPTER IV. SPECTROSCOPY AND STRUCTURE\r......Page 378
IV.A. VIBRATIONAL SPECTROSCOPY......Page 380
IV.Β. VISIBLE AND U. V. SPECTROSCOPY......Page 387
IV.C. NUCLEAR MAGNETIC AND ELECTRON PARAMAGNETIC RESONANCE SPECTROSCOPY\r......Page 394
IV.D. X-RAY AND NEUTRON DIFFRACTION\r......Page 397
IV.Ε. FUSED SALT ELECTROLYTES\r......Page 401
CHAPTER V. PRACTICAL FEATURES\r......Page 404
V.A. MELT PREPARATION AND PURIFICATION\r......Page 406
V.Β. CONTAINMENT AND CORROSION\r......Page 411
V.C. CHROMATOGRAPHIC ANALYSIS\r......Page 429
V.D. ELECTROLYSIS\r......Page 434
V.Ε. CHEMICAL PROCESSES\r......Page 480
V.F. FUEL CELLS, BATTERIES, NUCLEAR TECHNOLOGY\r......Page 487
CHAPTER VI. EXPERIMENTAL TECHNIQUES\r......Page 522
VI.A. ILLUSTRATIONS OF EXPERIMENTAL ASSEMBLIES\r......Page 524
VI.B. Additional References and Data Sources......Page 538
CHEMICAL FORMULA INDEX......Page 560