Methane Conversion, Proceedings of a Symposium on the Production of Fuels and Chemicals from Natural Gas

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Page iii

Copyright page
Page iv

Chairmen of Organizing Committee and Subcommitees
Page v

Sponsors
Page vi

List of Contributors
Pages vii-xi

Preface
Pages xiii-xiv
M. Koizumi, Y. Murakami, A. Iijima, J.W. Ward

Advisory Board
Pages xxv-xxvii

Porous Crystals: A Perspective Original Research Article
Pages 3-11
R.M. Barrer

Zeolites and Zeolite-like Materials Original Research Article
Pages 13-22
W.M. Meier

Exploration of the Void Size and Structure of Zeolites and Molecular Sieves Using Chemical Reactions Original Research Article
Pages 23-32
Peter A. Jacobs, Johan A. Martens

Geologic Occurrence of Zeolites and Some Associated Minerals Original Research Article
Pages 35-40
R.L. Hay

The Crystal Chemistry of Natural Zeolites Original Research Article
Pages 41-49
G. Gottardi

Geology of the Itaya Zeolite Deposit, Yamagata, Northeast Honshu Original Research Article
Pages 51-58
Y. Watanahe, M. Utada, A. Iijima

Zeolites from Tertiary Tuffaceous Rocks in Yeongil Area, Korea Original Research Article
Pages 59-66
J.H. Noh, S.J. Kim

Analcime-Bearing Pyroclastites from Western Taurus Mountains, Turkey Original Research Article
Pages 67-70
N. Tuzcu

Identification and Characterization of Natural Zeolites by Magnetic Resonance Original Research Article
Pages 71-78
S. Nakata, S. Asaoka, T. Kondoh, H. Takahashi

Clinoptilolite Deposit in the Pine Ridge Indian Reservation, South Dakota, U.S.A. Original Research Article
Pages 79-85
William H. Raymond

Hydrothermal Zeolite Occurrence from the Smrekovec Mt. Area, Slovenia, Yugoslavia Original Research Article
Pages 87-92
P. Kovič, N. Krošl-Kuščer

Zeolites of Yakutia Original Research Article
Pages 93-100
K.Ye. Kolodeznikov, V.V. Stepanov

Aluminophosphate Molecular Sieves and the Periodic Table Original Research Article
Pages 103-112
Edith M. Flanigen, Brent M. Lok, R. Lyle Patton, Stephen T. Wilson

Parameters Affecting the Growth of Large Silicalite Crystals Original Research Article
Pages 113-120
D.T. Hayhurst, J.C. Lee

New Route to Pentasil-Type Zeolites Using a Non Alkaline Medium in the Presence of Fluoride Ions Original Research Article
Pages 121-128
J.L. Guth, H. Kessler, R. Wey

Titanium-Silicalite: a Novel Derivative in the Pentasil Family Original Research Article
Pages 129-136
G. Peregot, G. Bellussi, C. Corno, M. Taramasso, F. Buonomot, A. Esposito

The Synthesis and Characterisation of Iron Silicate Molecular Sieves Sieves Original Research Article
Pages 137-144
W.J. Ball, J. Dwyer, A.A. Garforth, W.J. Smith

Preparation and Characterization of Iron Bidimensional Zeolitic Montmorillonite Original Research Article
Pages 145-152
G. Murali Dhar, M. Vittal, T.G. Narendra Babu

Comparative Study of Zeolite A Synthesis in Batch and Semibatch Reactors Original Research Article
Pages 153-160
Menelaos Tassopoulos, Robert W. Thompson

Preparation and Properties of a New Synthetic Analogue of Natural Zeolite Mazzite Original Research Article
Pages 161-167
G.V. Tsitsishvili, M.K. Charkviani

The Role of Interfacial Energy in Zeolite Synthesis Original Research Article
Pages 169-175
R.A. van Santen, J. Keijsper, G. Ooms, A.G.T.G. Kortbeek

The Synthesis of Zeolite NaA from Homogeneous Solutions and Studies of its Properties Original Research Article
Pages 177-184
Pang Wenqin, Satoru Ueda, Mitsue Koizumi

Clear Aqueous Nuclei Solution for Faujasite Synthesis Original Research Article
Pages 185-192
S. Kasahara, K. Itabashi, K. Igawa

Crystallization of High-Silica Zeolite in the Mixture of Water and Organic Solvent Original Research Article
Pages 193-200
M. Sugimoto, K. Takatsu, N. Kawata, T. Konishi

The Templating Effect during the Formation of ZSM-5 Type Zeolite Original Research Article
Pages 201-206
Song Tianyou, Xu Ruren, Li Liyun, Ye Zhaohui

The Influence of Template Size and Geometry on Faujasite Crystallization Original Research Article
Pages 207-213
D.E.W. Vaughan, K.G. Strohmaier

Bis-Quaternary Ammonium Compounds as Templates in the Crystallisation of Zeolites and Silica Molecular Sieves Original Research Article
Pages 215-222
J L Casci

Mechanism of Zeolite Crystallization without Using Template Reagents of Organic Bases Original Research Article
Pages 223-230
F.-Y. Dai, M. Suzuki, (late) H. Takahashi, I. Saito

Role of Alkali and Tetrapropylammonium Cations in (M)ZSM-5 Hydrogel Precursors Original Research Article
Pages 231-238
J.B. Nagy, P. Bodart, E.G. Derouane, Z. Gabelica, A. Nastro

Nucleation and Growth of NH4-ZSM-5 Zeolites Original Research Article
Pages 239-246
Liang-Yuan Hou, Leonard B. Sand, Robert W. Thompson

Application of 29Si and 27Al NMR to Determine the Distribution of Anions in Sodium Silicate and Sodium Alumino-Silicate Solutions Original Research Article
Pages 247-254
A.V. McCormick, A.T. Bell, C.J. Radke

Influence of Sodium Salts on Zeolite Nu-10 Crystallization Original Research Article
Pages 255-262
R. Aiello, A. Nastro, C. Pellegrino

Crystallization of Zeolitic Aluminosilicates in Bicationic Systems Including Lithium Original Research Article
Pages 263-270
C. Colella, M. de Gennaro, V. Iorio

Ion Exchange in Zeolites: Some Recent Developments in Theory and Practice Original Research Article
Pages 273-282
R.P. Townsend

Modelling and Calculating Ion-Exchange Processes of Metal Sorption by Natural Clinoptilolite Original Research Article
Pages 283-288
V.A. Nikashina, M.M. Senyavin, L.I. Mironova, V.A. Tyurina

Ternary Exchange Equilibria Involving H3O+, NH4+and Na+ Ions in Synthetic Zeolites of the Faujasite Structure Original Research Article
Pages 289-296
K.R. Franklin, R.P. Townsend, S.J. Whelan, C J Adams

Germanium Methoxide: New Reagent for Controlling the Pore-Opening Size of Zeolite by CVD Original Research Article
Pages 297-304
Miki Niwa, Carmela V. Hidalgo, Tadashi Hattori, Yuichi Murakami

The Influence of Structural Modification by Silanation on the Ion-Exchange Properties of Mordenite L.P. Original Research Article
Pages 305-310
P. de Hulsters, J. Verbiest, J. Philippaerts, G. Peeters, E.F. Vansant

Interaction of Tricoordinated Phosphorus Compounds with Zeolites Original Research Article
Pages 311-318
Th. Beln, D.B. Chase, R.D. Farlee, G.D. Stucky

The Implantation of Boron-Nitrogen Compounds in Mordenite LP and their Influence on the Adsorption Properties Original Research Article
Pages 319-327
J. Philippaerts, G. Peeters, E.F. Vansant, P. de Hulsters, J. Verbiest

Modification of Y Type Zeolite by Ferric Nitrate Solution Original Research Article
Pages 329-336
S. Hidaka, A. Iino, K. Nita, Y. Maeda, K. Morinaga, N. Yamazoe

Effect of Rare Earth Loading in Y-Zeolite on its Dealumination during Thermal Treatment Original Research Article
Pages 337-344
J.W. Roelofsen, H. Mathies, R.L. de Groot, P.C.M. van Woerkom, H. Angad Gaur

The Effect of Dealumination on the Structure and Acidic Properties of Offretite Original Research Article
Pages 345-350
C. Fernandez, A. Auroux, J.C. Vedrine, J. Grosmangin, G. Szabo

Faujasites Enriched in Silicon. A Comparison of Processes and Products Original Research Article
Pages 351-357
D. Akporiaye, D.M. Clark, J. Dwyer, I.S. Elliott, D.J. Rawlence, A.P. Chapple

Zeolite Structural Investigations by High Resolution Solid State MAS NMR Original Research Article
Pages 361-368
G.T. Kokotailo, C.A. Fyfe, G.J. Kennedy, G.C. Gobbi, H. Strobl, C.T. Pasztor, G.E. Barlow, S. Bradley

Distribution of Aluminum in the Synthetic Mordenites Original Research Article
Pages 369-376
K. Itabashi, T. Okada, K. Igawa

Generation of New Paramagnetic Rhodium Species in NaX Zeolite and Coordination with Adsorbates Original Research Article
Pages 377-384
D. Goldfarb, L. Kevan

Combined EPR-DRS Spectroscopies on Zeolites: Coordination of Cu(II) to an Oxygen Six-Ring Original Research Article
Pages 385-392
D. Packet, R.A. Schoonheydt

Adsorption of Xenon : A New Method for Studying Zeolites Original Research Article
Pages 393-400
J. Fraissard, M. Springuel-Huet, T. Ito, J. Demarquay

In Situ Synthesis of Iridium Carbonyl Clusters Encaged in Y-Zeolite Original Research Article
Pages 401-408
G. Bergeret, P. Gallezot, F. Lefebvre

Surface States of Aluminophosphate and Zeolite Molecular Sieves Original Research Article
Pages 409-414
S.L. Suib, A.M. Winiecki, A. Kostapapas

Distribution of the Bivalent Nickel Ion in ZSM-5 Molecular Sieves Original Research Article
Pages 415-422
Liu Zhenyi, Zhang Wangjin, Yu Qin, Lü Guanglie, Li Wangrong, Wang Shuju, Zhang Youshi, Lin Bingxiong

The Application of Electronegativity Equalization Concepts to Zeolites Original Research Article
Pages 423-428
Wllfrled J. Mortler

Quaternary Ammonium Cation Effects on the Crystallization of Zeolites of the Offretite-Erionite Family Part II. Electron Diffraction Studies Original Research Article
Pages 429-436
J.V. Sanders, M.L. Occelli, R.A. Innes, S.S. Pollack

The Absence of T-O-T Angles of 180° in Zeolites Original Research Article
Pages 437-441
Alberto Alberti

The Structure of Zeolite Li-A(BW) by Single Crystal Data Original Research Article
Pages 443-447
E. Krogh Andersen, G. Ploug-Sørensen

Distribution of Cations and Water Molecules in the Heulandite-Type Framework Original Research Article
Pages 449-456
K. Sugiyama, Y. Takeuchi

Structural Studies of Gallosilicate Zeolites Original Research Article
Pages 457-464
J.M. Newsam, D.E.W. Vaughan

Intracrystalline Diffusion of C8 Aromatic Isomers in NaX Zeolite and Natural Faujasite Original Research Article
Pages 467-473
M. Goddard, D.M. Ruthven

The Use of Computer Graphics to Study Adsorption, Diffusion and Catalysis in Zeolites Original Research Article
Pages 475-479
A.K. Nowak, A.K. Cheetham

The Effects of Steam Treatment, Impregnation with P, Mg and Ion Exchange on Diffusion in HZSM-5 Zeolite Original Research Article
Pages 481-486
Chuanchang Wu, Guanlin Qin, Yuming Xie

Studies on the Surface Acidity of HY Zeolite by Combined IR and TPD Original Research Article
Pages 487-494
Li Quanzhi, Zhang Ruiming, Xue Zhiyuan

Bronsted Site Population on External and on Internal Surface of Shape-Selective Catalysts Original Research Article
Pages 495-502
J. Take, T. Yamaguchi, K. Miyamoto, H. Ohyama, M. Misono

A Method for Calculating Activation Energy Distribution of Desorption from Temperature-Programmed Desorption Spectrum of Ammonia Original Research Article
Pages 503-510
K. Hashimoto, T. Masuda, T. Mori

One Dimensional Gas Adsorbed in the Zeolitic Pore Original Research Article
Pages 511-520
T. Takaishi

Smectite Molecular Sieves. Part I. Hydrogen, Deuterium, and Neon in Expanded Fluorhectorites Original Research Article
Pages 521-529
R.M. Barrer, R.J.B. Craven

Adsorption of Hydrocarbons in (Na, K)-ZSM5, -ZSM11 and “Al-Free” NaZSM5 and NaZSM11 Original Research Article
Pages 531-538
Y.H. Ma, T.D. Tang, L.B. Sand, L.Y. Hou

Adsorption Properties of Microporous Aluminophosphate AIPO4-5 Original Research Article
Pages 539-546
H. Stach, H. Thamm, K. Fiedler, B. Grauert, W. Wieker, E. Jahn, G. Ohlmann

Hydrocarbon Adsorption Characterization of Some High Silica Zeolites Original Research Article
Pages 547-554
E.L. Wu, G.R. Landolt, A.W. Chester

Adsorption Equilibrium of Ethylene-Carbon Dioxide Mixture on Zeolite ZSM5 Original Research Article
Pages 555-562
Jin-Gu Wang, Yang-chun Chang, Yi Hua Ma, Hai-qing Li, T.D. Tang

Simulation of Pressure Swing Adsorption for Air Separation Original Research Article
Pages 563-570
K. Chihara, I. Yoneda, S. Morishita, M. Suzuki

Effect of the Interaction between Admolecules on the Sorption Equili Equilibrium at the Liquid-Solid Interface for the Y Zeolite Original Research Article
Pages 571-578
Son-Ki Ihm, Han-Soo Lee

Molecular Mobility of Hydrocarbon ZSM5/Silicalite Systems Studied by Sorption Uptake and Frequency Response Methods Original Research Article
Pages 579-586
M. Bülow, H. Schlodder, L.V.C. Rees, R.E. Richards

Zeolitic Diffusivities of Binary Gas Mixtures by the Frequency Response Method Original Research Article
Pages 587-594
Y. Yasuda, Y. Yamada, I. Matsuura

Nuclear Relaxation Studies of Aromats in Faujasite Type Zeolites Original Research Article
Pages 595-600
H. Lechert, W.D. Basler, K.P. Wittern

Study of the Mobility of Ca2+ in Ca, Na-A by n-Pentane Sorption Original Research Article
Pages 601-608
P. Fraenkel

Four Different States of Benzene Adsorbed in Faujasites Original Research Article
Pages 609-615
A. de Mallmann, D. Barthomeuf

Combined UV and IR Spectroscopic Studies on the Adsorption of SO2 onto Faujasite-Type Zeolites Original Research Article
Pages 617-624
Hellmut G. Karqe, Marek Łaniecki, Maria Ziołek

Heat Capacities and Adsorption Energies of Helium Adsorbed on Y Zeolites with Various Cations Original Research Article
Pages 625-632
N. Wada, Y. Yaraamoto, H. Kato, T. Watanabe, T. Ito

NMR Investigations of Self-Diffusion in Pentasils Original Research Article
Pages 633-639
J. Kärger, H. Pfeifer, D. Freude, J. Caro, M. Bülow, G. Ohimann

Catalytic and Acidic Properties of Boron Pentasil Zeolites Original Research Article
Pages 643-652
G. Coudurier, J.C. Védrine

Disproportionation of Paraffins I. Pentanes Original Research Article
Pages 653-660
N.Y. Chen

Shape Selective Cracking of Octane in the Presence of Another Hydrocarbon on HZSM-5 Original Research Article
Pages 661-668
S. Namba, K. Sato, K. Fujita, J.H. Kim, T. Yashima

Pore Size and Shape Effects in Zeolite Catalysis Original Research Article
Pages 669-675
J.G. Bendoraitis, A.W. Chester, F.G. Dwyer, W.E. Garwood

The Nature of the Catalytic Sites in HZSM-5- Activity Enhancement Original Research Article
Pages 677-684
R.M. Lago, W.O. Haag, R.J. Mikovsky, D.H. Olson, S.D. Hellring, K.D. Schmitt, G.T. Kerr

Influence of the Activation Conditions on the Catalytic Behaviour of Offretite Original Research Article
Pages 685-691
F. Hernandez, C. Oliver, F. Fajula, F. Figueras

Investigation of Carbonaceous Deposits on a LaY Zeolite Catalyst by CP/MAS-13C-NMR Spectroscopy Original Research Article
Pages 693-700
S. Maixner, C.Y. Chen, P.J. Grobet, P.A. Jacobs, J. Weitkamp

Formation and Nature of Coke Deposits on Zeolites HY and HZSM-5 Original Research Article
Pages 701-707
M. Guisnet, P. Magnoux, C. Canaff

Preparation of Bifunctional Pt/H-ZSM5 Catalysts and their Application for Propane Conversion Original Research Article
Pages 709-716
C.W.R. Engelen, J.P. Wolthuizen, J.H.C. van Hooff, H.W. Zandbergen

Transformation of Propene into Aromatic Hydrocarbons over ZSM-5 Zeolites Original Research Article
Pages 717-724
M. Shibata, H. Kitagawa, Y. Sendoda, Y. Ono

Aromatization of Hydrocarbons over Platinum Alkaline Earth Zeolites Original Research Article
Pages 725-732
T.R. Hughes, W.C. Buss, P.W. Tamm, R.L. Jacobson

Alkylation of Chlorobenzene over H-Mordenite and H-ZSM-5: Effect of Si/AI Ratio Original Research Article
Pages 733-738
Chen Fang Ren, G. Coudurier, C. Naccache

The Selective Alkylation of Aniline with Methanol over ZSM-5 Zeolite Original Research Article
Pages 739-746
P.Y. Chen, H.C. Chen, H.Y. Chu, N.S. Chang, T.K. Chuang