Mechanically Interlocked Materials: Polymers, Nanomaterials, MOFs, and more

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Mechanically Interlocked Materials: Polymers, Nanomaterials, MOFs, and more
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Contents
Preface
	Refrences
1. Force-Promoted Transformations in Mechanically Linked Molecules
	1.1 Introduction
	1.2 SMFS in the Study of Non‐covalent Interactions
		1.2.1 Rotaxanes
		1.2.2 Poly‐(pseudo)rotaxanes
		1.2.3 Catenanes
	1.3 Strength of Mechanical Bonds
		1.3.1 Polymers Containing a Rotaxane
		1.3.2 Polymers Containing a Catenane
	1.4 Changes in Optical Properties – Reversible and Irreversible Changes of Optical Properties by Movement of Macrocycle in a Rotaxane
	1.5 Conclusions
	References
2. Colloidal Nanomaterials with Mechanically Interlocked Parts
	2.1 Introduction
	2.2 Installing and Actuating Mechanically Interlocked Molecular Architectures at Colloidal Nanoparticle Surfaces
	2.3 Modulating Nanoparticle Physicochemical Properties Using Switchable Mechanically Interlocked Architectures
	2.4 Interlocked Gates for Nanoparticle Pores: From Cargo Release to Nanoscale Communication
		2.4.1 Optimizing Mechanisms for Cargo Release
		2.4.2 Autonomous Drug Delivery Triggered By Endogenous Conditions
		2.4.3 Cargo Release Using Tissue‐Penetrating External Triggers
		2.4.4 Nanoscale Communication Between Responsive Nanoparticles
	2.5 Mechanically Interlocked Molecular Links for Nanoparticle Assemblies
		2.5.1 Pseudorotaxane‐linked Nanoparticle Assembly–Disassembly
		2.5.2 Fully Interlocked Molecular Links for Nanoparticle Assemblies
	2.6 From Switches to Motors and Beyond: The Future of Colloidal Nanomaterials with Mechanically Interlocked Parts
	References
3. Mechanically Interlocked Nanotubes
	3.1 Introduction
	3.2 Carbon Nanotubes
	3.3 MINTs: Clipping Strategy
	3.4 Other Strategies for the Preparation of MINTs
	3.5 Application of MINTs
	3.6 Conclusions
	References
4. Concepts of Molecular Motors in Solution and on Surfaces
	4.1 Light-driven Overcrowded Alkenes
		4.1.1 General Concept and Development
		4.1.2 Applications
			4.1.2.1 Molecular Motors in Liquid Crystals
			4.1.2.2 Self‐assembly of Molecular Motors
			4.1.2.3 Macroscopic Contraction of Gels
			4.1.2.4 Cancer Treatment
	4.2 Molecular Motors Based on Catenanes
	4.3 Other Concepts of Molecular Motors
	4.4 Computationally Designed Light‐driven Molecular Motors
	4.5 Molecular Motors on Surfaces
		4.5.1 Tethering of Molecular Motors
			4.5.1.1 Tunable Wettability of Surfaces
		4.5.2 Molecular Motors on Surfaces Without Tethers
		4.5.3 Unidirectional Motion on Surfaces
	4.6 Conclusions and Outlook
	Acknowledgments
	References
5. MIMs in MOFs: Designing Mechanically Interlocked Molecules to Function Inside Metal–Organic Frameworks
	5.1 Introduction
	5.2 Coordination Polymers Using [2]Pseudorotaxanes as Linkers
	5.3 Robust Dynamics
	5.4 Techniques for Elucidating Dynamic Behavior in the Solid State
	5.5 Rotational Motion of a MIM Wheel: UWDM‐1, a Case Study
	5.6 Translational Motion of a MIM Wheel: UWDM‐4, a Case Study
	5.7 MIM Linker Design Strategies
	5.8 Controlling Dynamics and Switching of MIMs in MOFs
	5.9 MIMs to Construct Poly‐Threaded MOF Lattices
	5.10 Applications and Future Perspectives
	References
6. Mechanically Interlocked Proteins
	6.1 Introduction
	6.2 Classification of Mechanically Interlocked Proteins
	6.3 Making Mechanically Interlocked Proteins
	6.4 Biological Significance of Natural MIPs
	6.5 Cultivating Mechanically Interlocked Proteins
	6.6 Conclusion and Future Perspective
	Acknowledgments
	References
7. Recent Advances on Catenanes and Rotaxanes Made of DNA
	7.1 Introduction
	7.2 DNA Catenanes
	7.3 DNA Rotaxanes
	7.4 Conclusions and Outlook
	References
8. Oligo- and Poly-catenanes from Molecular and Supramolecular Building Blocks
	8.1 Introduction
	8.2 [n]Molecular Necklaces by Cyclization of Polypseudorotaxanes
	8.3 Main Chain Polycatenanes Composed of Covalent Macocyclic Building Block
	8.4 Main Chain Nano‐polycatenanes Composed of Non‐covalent Building Block
	8.5 Polycatenanes Composed of Metal–Organic Coordination Cages
	8.6 Poly[2]catenane
	8.7 Summary and Outlook
	References
9. Synthesis, Properties, and Applications of Mechanically Interlocked Polymers
	9.1 Introduction
	9.2 Synthesis and Physical Properties of Polyrotaxanes
		9.2.1 Synthetic Strategies Towards Main‐Chain Polyrotaxanes
		9.2.2 Structural Diversity of Polyrotaxanes
		9.2.3 Cyclodextrin‐Poly(ethylene glycol) Main‐Chain Polyrotaxanes
		9.2.4 Polyrotaxane Networks
		9.2.5 Insulated Molecular Wires
	9.3 Applications
		9.3.1 Composite Materials
		9.3.2 Biomedical Applications
		9.3.3 Molecular Electronics
		9.3.4 Molecular Machines
		9.3.5 Batteries
	9.4 Conclusion and Outlook
	References
index