Macromolecules Containing Metal and Metal-Like Elements: Photophysics and Photochemistry of Metal-Containing Polymers, Volume 10

Macromolecules Containing Metal and Metal-Like Elements Volume 10......Page 5
Contributors......Page 7
Contents......Page 9
Preface......Page 15
Series Preface......Page 17
1. Introduction to Photophysics and Photochemistry......Page 19
I. General......Page 20
II. Photophysics and Photochemistry......Page 21
III. Light Absorption......Page 22
IV. Luminescence......Page 28
V. Emission Lifetime......Page 33
A. Energy and Electron Transfer (Excited State Interactions and Reactions)......Page 36
B. Energy Transfer......Page 37
i. Förster Mechanism......Page 38
ii. Dexter Mechanism......Page 39
C. Electron Transfer......Page 40
VII. Nonlinear Optical Behavior......Page 43
VIII. Photoconductive and Photonic Polymers......Page 44
IX. Photosynthesis......Page 46
A. Purple Photosynthetic Bacteria......Page 47
B. Green Sulfur Bacteria......Page 50
X. Organometallic Polymers and Synthetic Photosynthesis Systems......Page 51
XI. Summary......Page 57
XIII. References......Page 58
2. Luminescent Organometallic Coordination Polymers Built on Isocyanide Bridging Ligands......Page 63
I. Introduction......Page 64
II. Luminescent Organometallic Polynuclear Systems and Coordination Polymers Containing a Terminal Isocyanide Ligand......Page 66
III. Luminescent Polymeric Systems Containing an Isocyanide Ligand Assembled via M?M Interactions......Page 82
IV. Luminescent Organometallic Polymetallic Systems and Coordination Polymers Containing Bridging Isocyanides......Page 89
VI. Acknowledgments......Page 101
VII. References......Page 102
3. Luminescent Oligomeric and Polymeric Copper Coordination Compounds Assembled by Thioether Ligands......Page 107
I. Introduction......Page 108
II. Background Informations......Page 109
A. Copper Polymers Assembled by Monothioether Ligands RSR......Page 111
B. Copper Polymers Assembled by Aromatic Dithioether Ligands......Page 123
C. Copper Polymers Assembled by Aliphatic Dithioether and Polythioether Ligands......Page 152
D. Copper Polymers Assembled by Dithioether and Polythioether Ligands Bearing Heteroelements in the Spacer Unit......Page 156
IV. Conclusion......Page 170
VI. References......Page 171
4. Applications of Metal Containing Polymers in Organic Solar Cells......Page 177
II. Types of Organic Solar Cells......Page 178
A. Dye-Sensitized Solar Cells......Page 179
B. Organic Thin Film Solar cells......Page 181
III. Solar Cell Characterizations......Page 182
IV. Metal Containing Polymers in Solar Cells......Page 183
A. Dye-Sensitized Solar Cells......Page 184
ii. Polymeric Metal Complexes......Page 188
iii. Ruthenium/Rhenium Complexes Containing Conjugated Polymers......Page 189
v. Conjugated Polymers with Pendant Metal Complexes......Page 193
vi. Platinum Acetylide Containing Conjugated Polymers......Page 196
vii. Other Metal Containing Polymers with Potential Photovoltaic Applications......Page 200
VII. References......Page 203
5. Functional Silole-Containing Polymers......Page 209
I. Introduction......Page 210
II. Electronic Transition and Band Gap......Page 211
A. Photoluminescence......Page 212
B. Electroluminescence......Page 214
V. Field Effect Transistors......Page 217
VI. Aggregation-Induced Emission......Page 218
IX. Optical Limiting......Page 219
XI. Acknowledgments......Page 220
XII. References......Page 221
6. Photophysics and Photochemistry of Polysilanes for Electronic Applications......Page 223
II. Synthesis of Electronic-Grade Polysilanes......Page 224
III. Band Structure......Page 232
A. Influence of the Backbone Structure......Page 236
B. Side Groups......Page 238
D. PL Quenching by Doping......Page 243
E. Energy Transfer......Page 244
F. Electroluminescence......Page 246
G. Cathodoluminescence......Page 251
H. Interaction with Photoelectrons......Page 252
V. Photochemistry......Page 255
A. Photo-Oxidation......Page 257
A. LED......Page 258
B. Photoconductors......Page 259
C. Photovoltaics......Page 260
D. Lithography......Page 261
E. Electron Beam......Page 262
VII. Polysilane Films for Optical Devices......Page 265
VIII. Summary......Page 267
IX. References......Page 268
7. Polymers with Metal-Metal Bonds as Models in Mechanistic Studies of Polymer Photodegradation......Page 273
I. Introduction......Page 274
II. Experimental Strategies......Page 277
A. Step-Growth Polymers......Page 278
B. ADMET Polymerization......Page 283
IV. Photochemical Reactions of the Polymers in Solution......Page 284
V. Photochemistry in the Solid State......Page 289
A. Temperature Effects......Page 291
B. Interpreting the Kinetics of Polymer Degradation in the Solid State......Page 295
i. The Effect of Radical-Radical Recombination......Page 297
ii. More Details on Stress-Induced Changes in k(recombination)......Page 298
VII. Kinetics of Polymer Formation......Page 300
VIII. Concluding Remarks on the Importance of Radical-Radical Recombination on the Efficiency of Polymer Photochemical Degradation......Page 302
X. References......Page 303
8. Optical Properties and Photophysics of Platinum-Containing Poly(aryleneethynylene)s......Page 307
I. Introduction......Page 308
II. Synthetic Methods and Materials Characterization......Page 309
A. Energy Gap Law for Triplet States......Page 316
i. Effect of π-Conjugation and Interruption......Page 318
iii. Effect of Ring Substitution......Page 327
iv. Effect of Donor-Acceptor Interaction......Page 328
B. Phosphorescence Color Tuning of Metallopolyynes......Page 330
i. Light-Emitting Devices......Page 332
ii. Photovoltaic Cells......Page 333
iii. Optical Power Limiters......Page 335
V. Acknowledgments......Page 338
VI. References......Page 339
9. Luminescence in Polymetallic Gold-Heteronuclear Derivatives......Page 343
I. Introduction and Background......Page 344
II. Luminescent Gold-Silver Derivatives......Page 347
A. Supramolecular Gold-Silver Complexes with Bidentate Ligands......Page 348
B. Supramolecular Gold-Silver Complexes with Tridentate Ligands......Page 350
C. Supramolecular Gold-Silver Complexes Built with Metallic Cationic and Anionic Counterparts......Page 351
III. Luminescent Gold-Copper Derivatives......Page 359
IV. Luminescent Gold-Thallium Derivatives......Page 361
A. Supramolecular Gold-Thallium Complexes with Bidentate Ligands......Page 362
B. Supramolecular Gold-Thallium Complexes through Acid-Base Reactions......Page 363
V. Luminescent Gold-Lead Derivatives......Page 376
VI. Luminescent Gold-Platinum Derivatives......Page 377
VIII. Conclusion......Page 378
IX. References......Page 379
I. Introduction......Page 383
II. Zinc(II) Terpyridine Polymers......Page 385
III. Zinc(II) Schiff Base Polymer......Page 393
VI. References......Page 402
11. Redox and Photo Functions of Metal Complex Oligomer and Polymer Wires on the Electrode......Page 405
I. Introduction......Page 406
II. Bottom-Up Fabrication of Redox-Conducting Metal Complex Oligomers on an Electrode Surface and Their Redox Conduction Behavior......Page 407
A. Bottom-Up Fabrication of Metal Complex Oligomer and Polymer Wires......Page 408
B. Electron Transport Behavior of the Molecular Wires on the Electrode......Page 413
III. Photoelectric Conversion System Using Porphyrin and Redox-Conducting Metal Complex Wires......Page 419
A. Bottom-Up Fabrication of the Porphyrin-Terminated Redox-Conducting Metal Complex Film on ITO......Page 420
B. Photoelectrochemical Properties of the Porphyrin-Terminated Redox-Conducting Metal Complex Film on ITO......Page 421
IV. Biophotosensor and Biophotoelectrode Composed of Cyanobacterial Photosystem I and Molecular Wires......Page 422
A. Biophotosensor Composed of Cyanobacterial Photosystem I, Molecular Wire, Gold Nanoparticle, and Transistor......Page 423
B. Biophotoelectrode Composed of Cyanobacterial Photosystem I and Molecular Wires......Page 427
VI. References......Page 430
Index......Page 433