Kinetically Controlled Stepwise Syntheses of a Heterometallic Complex and a Tetrahedral Chiral-at-Metal Complex (Springer Theses)

Supervisor’s Foreword
Acknowledgments
Contents
Abbreviations
1 General Introduction
	1.1 Selective Synthesis of Metal Complexes
	1.2 Target Scope of Kinetically Controlled Stepwise Synthesis
	1.3 Overview of This Study
	References
2 Heterometallic CoIINi3II Complex
	2.1 Introduction
	2.2 Step 1: Complexation with a Redox-Active Metal
	2.3 Step 2: Site-Selective Oxidation
	2.4 Step 3: Site-Selective Transmetalation
	2.5 Step 4: Reduction
	2.6 Comparison with Other Strategies
	2.7 Conclusions
	2.8 Experimental Section
		2.8.1 Materials and Methods
		2.8.2 Synthesis of Compounds
		2.8.3 Miscellaneous Experiments
		2.8.4 Single-Crystal XRD Analyses
	References
3 Tetrahedral Chiral-at-Metal ZnII Complex
	3.1 Introduction
	3.2 Molecular Design
	3.3 Strategy for Enantioselective Synthesis
	3.4 Step 1: Racemic Complexation
	3.5 Step 2: Asymmetric Induction with a Chiral Ligand
	3.6 Step 3: Replacement of the Chiral Ligand
	3.7 Configurational Stability
	3.8 Enantioselective Catalysis
	3.9 Conclusions
	3.10 Experimental Section
		3.10.1 Materials and Methods
		3.10.2 Synthesis of the Ligand
		3.10.3 Syntheses of the Metal Complexes
		3.10.4 Single-Crystal X-Ray Diffraction Analyses
		3.10.5 Miscellaneous Experiments
	References
4 Conclusions
	4.1 Conclusions
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