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ویرایش: سری: Inorganic Reactions and Methods ISBN (شابک) : 9780471186656, 9780470145302 ناشر: سال نشر: 1986 تعداد صفحات: 534 زبان: English فرمت فایل : PDF (درصورت درخواست کاربر به PDF، EPUB یا AZW3 تبدیل می شود) حجم فایل: 113 مگابایت
در صورت تبدیل فایل کتاب Inorganic Reactions and Methods: Electron-Transfer and Electrochemical Reactions; Photochemical and Other Energized Reactions, Volume 15 به فرمت های PDF، EPUB، AZW3، MOBI و یا DJVU می توانید به پشتیبان اطلاع دهید تا فایل مورد نظر را تبدیل نمایند.
توجه داشته باشید کتاب واکنشهای معدنی و روشها: انتقال الکترون و واکنشهای الکتروشیمیایی. فتوشیمیایی و سایر واکنش های پرانرژی، جلد 15 نسخه زبان اصلی می باشد و کتاب ترجمه شده به فارسی نمی باشد. وبسایت اینترنشنال لایبرری ارائه دهنده کتاب های زبان اصلی می باشد و هیچ گونه کتاب ترجمه شده یا نوشته شده به فارسی را ارائه نمی دهد.
How to Use this Book
Preface to the Series
Editorial Consultants to the Series
Contributors to Volume 15
12. Electron-Transfer and Electrochemical Reactions
12.1. Introduction
12.2. Electron Transfer
12.3. Electrochemical Reactions
13. Photochemical and Other Energized Reactions
13.1. Introduction
13.2. Photosubstitution and Photoisomerization
13.3. Photoinduced Cleavage of Metal-Metal Bonds
13.4. Photoinduced Electron-Transfer Reactions
13.5. Pulse Radiolysis
List of Abbreviations
Author Index
Compound Index
Subject IndexContent:
Chapter 12.2.1 Introduction (pages 1–5): J. J. Zuckerman, N.
Sutin and R.G. Linck
Chapter 12.2.2.1 Outer?Sphere Reactions (pages 5–7): R.G.
Linck
Chapter 12.2.2.1.2 Outer?Sphere Transition States (pages 7–9):
R.G. Linck
Chapter 12.2.2.2 Inner?Sphere Reactions (pages 9–11): R.G.
Linck
Chapter 12.2.2.2.2 Inner?Sphere Reactions: Scheme II (pages
11–12): R.G. Linck
Chapter 12.2.2.2.3 Inner?Sphere Reactions: Scheme III (pages
12–14): R.G. Linck
Chapter 12.2.2.2.4 Double?Ligand Bridging (page 14): R.G.
Linck
Chapter 12.2.2.3 Other Reaction Classes (page 14): R.G.
Linck
Chapter 12.2.2.3.2 Intramolecular Electron Transfer (pages
14–15): R.G. Linck
Chapter 12.2.2.3.3 Two?Electron Transfers (page 16): R.G.
Linck
Chapter 12.2.3 Theory of Electron?Transfer Reactions (pages
16–17): N. Sutin
Chapter 12.2.3.1 The Stability of the Precursor Complex (pages
17–19): N. Sutin
Chapter 12.2.3.2 Potential?Energy Surfaces (page 20): N.
Sutin
Chapter 12.2.3.2.1 Of Zero Order (pages 20–22): N. Sutin
Chapter 12.2.3.2.2 Of First Order (pages 22–23): N. Sutin
Chapter 12.2.3.2.3 The Electronic Factor (pages 23–24): N.
Sutin
Chapter 12.2.3.3 Electron?Exchange Reactions (pages 24–26): N.
Sutin
Chapter 12.2.3.3.1 The Reorganization Energy (pages 26–29): N.
Sutin
Chapter 12.2.3.3.2 Nuclear Tunneling in Electron Exchange
(pages 29–30): N. Sutin
Chapter 12.2.3.3.3 Quantum?Mechanical Treatment (pages 30–31):
N. Sutin
Chapter 12.2.3.3.4 Comparison of Observed and Calculated
Parameters for Electron Exchange (pages 32–37): N. Sutin
Chapter 12.2.3.4 Electron Transfer Accompanied by a Net
Chemical Change (pages 37–41): N. Sutin
Chapter 12.2.3.4.2 Cross Reactions and Electron?Exchange Rates
(pages 41–45): N. Sutin
Chapter 12.2.3.4.3 Quantum?Mechanical Treatment (pages 45–46):
N. Sutin
Chapter 12.2.3.5 Conclusions (pages 46–49): C. Creutz and N.
Sutin
Chapter 12.2.4.1 The Inner?Shell Reorganization Energy:
Exchange Rates of Aquo Ions (pages 49–53): C. Creutz and N.
Sutin
Chapter 12.2.4.2 Variations with Ligand: The Outer?Shell
Reorganization Energy (pages 53–57): C. Creutz and N.
Sutin
Chapter 12.2.4.3 Electronic Factors: Nonadiabaticity (pages
58–59): C. Creutz and N. Sutin
Chapter 12.2.4.4 Free?Energy Relations (pages 59–64): C. Creutz
and N. Sutin
Chapter 12.2.4.5 Inner?Sphere Versus Outer?Sphere Electron
Transfer (pages 64–65): N. Sutin
Chapter 12.2.4.6 Rate Saturation in Electron Transfer (pages
65–68): N. Sutin
Chapter 12.2.5 Specific Reactivity Patterns in
Electron?Transfer Reactions (pages 68–78): R.G. Linck
Chapter 12.2.5.1.2 Two?Electron Reductants (page 78): R.G.
Linck
Chapter 12.2.5.2 Variation with the Oxidant (pages 78–81): R.G.
Linck
Chapter 12.2.5.2.2 Multiple?Electron Oxidants (pages 81–82):
R.G. Linck
Chapter 12.2.5.3 Oxidation and Reduction of Coordinated Ligands
(page 82): R.G. Linck
Chapter 12.2.5.4 Catalysis in Electron?Transfer Reactions
(pages 83–84): R.G. Linck
Chapter 12.2.5.4.2 Catalyzed Ligand Substitution (pages 84–85):
R.G. Linck
Chapter 12.2.5.5 Induced Electron?Transfer Reactions (pages
85–86): R.G. Linck
Chapter 12.2.5.6 Photoinduced Electron?Transfer Reactions
(pages 86–87): R.G. Linck
Chapter 12.3.1 Introduction (page 88): W.E. Geiger
Chapter 12.3.1.1 The Electrode Process (pages 88–90): W.E.
Geiger
Chapter 12.3.1.2.2 Chemical Reversibility (pages 90–100): W.E.
Geiger
Chapter 12.3.2.1.2 Pulse?Polarographic Methods (pages 100–106):
W.E. Geiger
Chapter 12.3.2.1.3 Alternating?Current Polarography (pages
107–110): W.E. Geiger
Chapter 12.3.2.1.4 Cyclic Voltammetry (pages 110–116): W.E.
Geiger
Chapter 12.3.3 Evaluation of Formal Potentials (pages 116–117):
W.E. Geiger
Chapter 12.3.3.2 Involving Unstable Electrode Products (pages
118–123): W.E. Geiger
Chapter 12.3.3.3 Involving Reactants Undergoing
Multiple?Electrode Reactions (pages 123–128): W.E. Geiger
Chapter 12.3.4 Chemical Reactions Accompanying Electrode
Reactions (pages 128–129): W.E. Geiger
Chapter 12.3.4.1.2 Fast?Reaction (I ? A) Limit (pages 130–133):
W.E. Geiger
Chapter 12.3.4.2 Reactions Following Electron Transfer (EC)
(pages 133–135): W.E. Geiger
Chapter 12.3.4.2.2 Giving Electroactive Products (ECE) (pages
135–141): W.E. Geiger
Chapter 12.3.4.3 Other Coupled Chemical Reactions (pages
141–142): W.E. Geiger
Chapter 12.3.5 Electrochemical Synthesis (page 142): W.E.
Geiger
Chapter 12.3.5.1 By Controlled?Potential Electrolysis (pages
142–145): W.E. Geiger
Chapter 12.3.5.2 Involving Bulk Preparations (pages 145–146):
W.E. Geiger
Chapter 12.3.6 Thermodynamics of Simple Electrochemical
Reactions (pages 147–150): M.J. Weaver
Chapter 12.3.7 Kinetics of Electrochemical Reactions (pages
150–153): M.J. Weaver
Chapter 12.3.7.2 Theory of Heterogeneous Electron?Transfer
Reactions (pages 153–163): M.J. Weaver
Chapter 12.3.7.3 Double?Layer Effects in Electrochemical
Kinetics (pages 164–165): M.J. Weaver
Chapter 12.3.7.4 Electrode?Reaction Mechanisms (pages 165–167):
M.J. Weaver
Chapter 12.3.7.5 Influence of the Electrode Material (pages
168–171): M.J. Weaver
Chapter 12.3.7.6 Electrochemical Reactivity
Patterns—Comparisons with Homogeneous Reactivities (pages
171–174): M.J. Weaver
Chapter 13.2 Photosubstitution and Photoisomerization (pages
175–179): G.L. Geoffroy and P.C. Ford
Chapter 13.2.1 With Group VIA Complexes (pages 179–183): P.C.
Ford
Chapter 13.2.1.2 Of Molybdenum and Tungsten (pages 183–184):
P.C. Ford
Chapter 13.2.2 With Group VIIA Complexes (page 184): P.C.
Ford
Chapter 13.2.3 With Group VIII Complexes (pages 184–186): P.C.
Ford
Chapter 13.2.3.2 Of Ruthenium (pages 186–190): P.C. Ford
Chapter 13.2.3.3 Of Osmium (page 190): P.C. Ford
Chapter 13.2.3.4 Of Cobalt (pages 190–194): P.C. Ford
Chapter 13.2.3.5 Of Rhodium(III) and Iridium(III) (pages
195–198): P.C. Ford
Chapter 13.2.3.6 Of Nickel(II) and Palladium(II) (pages
198–199): P.C. Ford
Chapter 13.2.3.7 Of Platinum(II) (pages 199–202): P.C.
Ford
Chapter 13.2.3.8 Of Platinum(IV) (pages 202–204): P.C.
Ford
Chapter 13.2.4 With Metal Carbonyls (pages 204–205): H.B.
Abrahamson
Chapter 13.2.4.1.1 Of Titanium, Zirconium and Hafnium (pages
205–206): H.B. Abrahamson
Chapter 13.2.4.1.2 Of Vanadium, Niobium and Tantalum (pages
206–209): H.B. Abrahamson
Chapter 13.2.4.1.3 Of Chromium, Molybdenum and Tungsten (pages
209–217): H.B. Abrahamson
Chapter 13.2.4.1.4 Of Manganese and Rhenium (pages 217–221):
H.B. Abrahamson
Chapter 13.2.4.1.5 Of Iron, Ruthenium and Osmium (pages
221–224): H.B. Abrahamson
Chapter 13.2.4.1.6 Of Cobalt, Rhodium and Iridium (pages
225–226): H.B. Abrahamson
Chapter 13.2.4.1.7 Of Nickel (page 226): H.B. Abrahamson
Chapter 13.2.4.2 Involving Dinuclear Complexes (pages 226–229):
H.B. Abrahamson
Chapter 13.2.4.3 Involving Polynuclear Complexes (pages
229–230): H.B. Abrahamson
Chapter 13.2.5 With Other Organometallic Complexes (pages
230–235): G.L. Geoffroy
Chapter 13.2.5.2 Containing Isocyanides (pages 235–236): G.L.
Geoffroy
Chapter 13.2.5.3 Containing Olefins (pages 236–240): G.L.
Geoffroy
Chapter 13.2.5.4 Containing Arenes and Cyclopentadienyls (pages
240–242): G.L. Geoffroy
Chapter 13.2.5.5 Containing Alkyls (pages 242–245): G.L.
Geoffroy
Chapter 13.3.1 In Dinuclear Complexes (pages 246–248): H.B.
Abrahamson
Chapter 13.3.1.1.2 And Contain Manganese, Technetium and
Rhenium (pages 248–252): H.B. Abrahamson
Chapter 13.3.1.1.3 And Contain Iron and Ruthenium (pages
252–254): H.B. Abrahamson
Chapter 13.3.1.1.4 And Contain Cobalt (pages 254–255): H.B.
Abrahamson
Chapter 13.3.1.1.5 And Contain Nickel, Palladium and Platinum
(pages 255–256): H.B. Abrahamson
Chapter 13.3.1.2 That are Heteronuclear (pages 256–257): H.B.
Abrahamson
Chapter 13.3.2 In Polynuclear Complexes (pages 257–259): H.B.
Abrahamson
Chapter 13.4 Photoinduced Electron?Transfer Reactions (page
260): N. Sutin
Chapter 13.4.1 Excited?State Assignments (pages 260–262): N.
Sutin
Chapter 13.4.2 Excited?State Electron Exchange (pages 262–265):
N. Sutin
Chapter 13.4.3 Quenching and Back Reactions (pages 265–268): N.
Sutin
Chapter 13.4.4 Free?Energy Relations (pages 269–271): N.
Sutin
Chapter 13.5.1 Introduction (pages 272–273): M.Z. Hoffman
Chapter 13.5.3 Techniques (pages 273–274): M.Z. Hoffman
Chapter 13.5.4.1 Of Hydrated Electrons (page 274): M.Z.
Hoffman
Chapter 13.5.4.2 Of Hydroxyl Radicals (pages 274–275): M.Z.
Hoffman
Chapter 13.5.4.3 Of Hydrogen Atoms (page 275): M.Z.
Hoffman
Chapter 13.5.4.4 Of Secondary Radicals (pages 275–276): M.Z.
Hoffman
Chapter 13.5.5 Of Metal Complexes (pages 276–277): M.Z.
Hoffman
Chapter 13.5.5.1 Involving Groups IA and IIA (page 277): M.Z.
Hoffman
Chapter 13.5.5.2 Involving Group IIIA (page 277): M.Z.
Hoffman
Chapter 13.5.5.3 Involving Group IVA (page 277): M.Z.
Hoffman
Chapter 13.5.5.4 Involving Group VA (pages 277–278): M.Z.
Hoffman
Chapter 13.5.5.5 Involving Group VIA (pages 278–279): M.Z.
Hoffman
Chapter 13.5.5.5.2 With Molybdenum and Tungsten (page 279):
M.Z. Hoffman
Chapter 13.5.5.6 Involving Group VIIA (page 280): M.Z.
Hoffman
Chapter 13.5.5.6.2 With Technetium (pages 280–281): M.Z.
Hoffman
Chapter 13.5.5.7 Involving Group VIIIA (pages 281–282): M.Z.
Hoffman
Chapter 13.5.5.7.2 With Ruthenium (pages 282–284): M.Z.
Hoffman
Chapter 13.5.5.7.3 With Osmium (page 284): M.Z. Hoffman
Chapter 13.5.5.7.4 With Cobalt (pages 284–288): M.Z.
Hoffman
Chapter 13.5.5.7.5 With Rhodium (pages 288–289): M.Z.
Hoffman
Chapter 13.5.5.7.6 With Iridium (page 289): M.Z. Hoffman
Chapter 13.5.5.7.7 With Nickel (pages 289–290): M.Z.
Hoffman
Chapter 13.5.5.7.8 With Palladium and Platinum (pages 290–291):
M.Z. Hoffman
Chapter 13.5.5.8 Involving Group IB (pages 291–292): M.Z.
Hoffman
Chapter 13.5.5.8.2 With Silver (pages 292–293): M.Z.
Hoffman
Chapter 13.5.5.8.3 With Gold (page 293): M.Z. Hoffman
Chapter 13.5.5.9 Involving Group IIB (pages 293–294): M.Z.
Hoffman
Chapter 13.5.5.9.2 With Cadmium (page 294): M.Z. Hoffman
Chapter 13.5.5.9.3 With Mercury (pages 294–295): M.Z.
Hoffman
Chapter 13.5.5.10 Involving Group NIB (page 295): M.Z.
Hoffman
Chapter 13.5.5.10.2 With Indium (page 295): M.Z. Hoffman
Chapter 13.5.5.10.3 With Thallium (page 295): M.Z.
Hoffman
Chapter 13.5.5.11 Involving Group IVB (page 296): M.Z.
Hoffman
Chapter 13.5.5.11.2 With Lead (page 296): M.Z. Hoffman
Chapter 13.5.5.12 Involving Lanthanides (page 296): M.Z.
Hoffman
Chapter 13.5.5.13 Involving Actinides (page 297): M.Z. Hoffman