Influence of the Solvents on Some Radical Reactions

Cover Page......Page 1
Title: INFLUENCE OF THE SOLVENTS ON SOME RADICAL REACTIONS......Page 4
ISBN 9781617282430......Page 5
Contents......Page 6
Preface......Page 8
1. Consideration of Factors Influencing on Kinetics of Radical Reactions......Page 10
1. Homolytical Non–initiated (Inhibited) Reactions of Decomposition [6,7,16,17]......Page 13
2. The Case, when the Limitative is Only One Stage among other Stages of the Radical Process......Page 14
4. Reactions with the Participation of Low–activity Radicals, for Example, in a Case of Phenoxyl Radicals Dimerization [22]......Page 16
References......Page 21
2. The Medium Influence on Thermolysis of Diacyl – and Dialkylperoxides......Page 24
References......Page 48
3. Decomposition of Peracids Esters......Page 50
References......Page 62
4. Decomposition of the Hydroperoxides and Reactions of the Phenoxy Radicals......Page 64
References......Page 73
5. Effects of the Solvents in the Oxidation Reactions......Page 76
5.1. Oxidation of Unsaturated Cyclic Hydrocarbons......Page 77
5.2. Oxidation of Saturated Cyclic Hydrocarbons......Page 88
5.3. Oxidation of Aldehydes......Page 92
References......Page 100
6.1. The Medium Influence on Azobisisobutyronitrile (AIBN) Decomposition......Page 104
6.2. The Medium Influence  on Hydrocarbons Halogenation......Page 110
6.3. The Examples of Oxidation by Peracetic Acid......Page 120
References......Page 124
Conclusions......Page 126
Appendix......Page 128
Index......Page 134