High Pressure Organic Synthesis

Cover
Half Title
Also of interest
High Pressure Organic Synthesis
Copyright
Dedication
Preface
Contents
Abbreviations
1. Introduction
	1.1 Historical background
	1.2 Basic physicochemical principles
	1.3 Technical details (equipment)
		1.3.1 Piston-cylinder apparatus
		1.3.2 HP solvents
	1.4 Quantum–chemical calculations
	References
2. Diels–Alder cycloaddition reactions
	Introduction
	2.1 DA cycloaddition reactions
	2.2 Heterocyclic dienes
		2.2.1 Five-membered dienes
			2.2.1.1 Furan
			2.2.1.2 Pyrrole
			2.2.1.3 Thiophene
			2.2.1.4 Siloles
			2.2.1.5 Oxazoles
		2.2.2 Six-membered dienes
			2.2.2.1 Pyrones
			2.2.2.2 Pyridone
			2.2.2.3 Tetrazines
	2.3 HDA reactions
	2.4 Intramolecular DA reactions
	2.5 RDA reactions
	2.6 Homo-Diels–Alder reactions
	2.7 Tandem DA reactions
	2.8 Selectivities of DA reactions
	2.9 Asymmetric reactions
	2.10 Natural product synthesis
	2.11 DA reactions of fullerenes
	References
3. 1,3-Dipolar cycloaddition reactions
	3.1 Azides
	3.2 Diazo compounds
	3.3 Nitrones
	3.4 Nitrile oxides
	References
4. C–C bonds
	4.1 Aldol condensation
	4.2 Knoevenagel reaction
	4.3 Cope rearrangement
	4.4 Michael reaction
	4.5 Conjugate additions
	4.6 Morita–Baylis–Hillman reaction
	4.7 Friedel–Crafts reaction
	4.8 Palladium catalyzed coupling reactions
	4.9 Cycloaddition reactions
		4.9.1 [2+2] Cycloaddition reactions
		4.9.2 [4+4] Cycloadditions
		4.9.3 [6+4] and [8+2] Cycloadditions
	4.10 Wittig reaction
	4.11 Ene reaction
	4.12 Condensation and polymerization reactions
	4.13 Organotin reactions
	References
5. C–N bonds
	5.1 Menshutkin reaction
		5.1.1 N-Alkylation
	5.2 Formation of peptide/amide bonds
		5.2.1 Peptide coupling
		5.2.2 Aminolysis of esters
		5.2.3 Transamidation
		5.2.4 [2 + 2] cycloaddition
	5.3 Aza-Michael reaction
	5.4 Functional transformations of carboxylic acid derivatives
	5.5 Miscellaneous reactions
	References
6. C–O, C–S and other bonds
	Introduction
	6.1 C–O bonds
		6.1.1 Ethers
		6.1.2 Esters
		6.1.3 Alcohols
	6.2 C–S bond
	6.3 C–Sn bond
	6.4 C–Si bond
	6.5 C–Se bond
	6.6 C–B bond
	6.7 C–P bonds
	6.8 C–Halogen bonds
	6.9 C–Metal bond
	6.10 O–O bond
	References
7. Oxidation and reduction reactions
	7.1 Oxidation reactions
	7.2 Reduction reactions
	References
8. Multicomponent reactions
	References
9. Supramolecular chemistry
	References
10. Miscellaneous reactions
	10.1 Conformational changes
	10.2 Sigmatropic shifts
	10.3 Valence isomerization
	10.4 Hydrogen transfer
	References
Author Index
Subject Index