Heterogeneous Catalysis and Fine Chemicals II, Proceedings of the 2nd International Symposium

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Page iii

Copyright page
Page iv

Foreword
Page xiii

Preface
Page xv

Scientific Committee
Page xvii

Organizing Committee
Pages xvii-xviii

Financial Support
Page xviii

Gas - Liquid - Solid Reactors for Hydrogenation in Fine Chemicals Synthesis Original Research Article
Pages 1-19
Jean F. Jenck

Structure-Reactivity in the Hydrogenation of Alkenes. Comparisons with Reductions by Diimide and The Formation of a Ni(0) Complex Original Research Article
Pages 21-32
S. Siegel

Heterogeneous Catalytic Oxidation and Fine Chemicals Original Research Article
Pages 33-54
R.A. Sheldon

Solids For Catalysis and Control in Organic Synthesis Original Research Article
Pages 55-71
Keith Smith

Enantioselective Catalysis by Chiral Solids: Approaches and Results. Original Research Article
Pages 73-92
Hans-Ulrich Blaser, Manfred Müller

Catalysis with Immobilized Enzymes : Hydrolysis and Esterification by Rhizopus Arrhizus Original Research Article
Pages 93-104
C. Gancet

Hydrogenation of Benzaldehyde to Benzyl Alcohol in a Slurry and Fixed-Bed Reactor Original Research Article
Pages 105-112
M. Herskowitz

Structure and Catalytic Properties in Hydrogenation of Valeronitrile of Raney Nickel Prepared from Cr and Mo Doped Ni2Al3 Alloys. Original Research Article
Pages 113-120
M. Besson, D. Djaouadi, J.M. Bonnier, S. Hamar-Thibault, M. Joucla

Selective Preparation of Chloroanilines from Chloronitrobenzenes Over Sulfided Hydrotreating Catalysts Original Research Article
Pages 121-127
C. Moreau, C. Saenz, P. Geneste, M. Breysse, M. Lacroix

The Applicability of Dispersed Metals as Catalysts for Organometallic Reactions Original Research Article
Pages 129-136
R.L. Augustine, S.T. O\'Leary, K.M. Lahanas, Y.-M. Lay

Surface Organometallic Chemistry on Metals: Selective Hydrogenation of Citral into Geraniol and Nerol on Tin Modified Silica Supported Rhodium. Original Research Article
Pages 137-143
B. Didillon, A. El Mansour, J.P. Candy, J.P. Bournonville, J.M. Basset

Selective Hydrogenation of Unsaturated Aldehydes over Zeolite-Supported Metals Original Research Article
Pages 145-152
D.G. Blackmond, A. Waghray, R. Oukaci, B. Blanc, P. Gallezot

The Mechanism of Hydrogenolysis and Isomerization of Oxacycloalkanes on Metals, Part X. Nature of the Active Sites in the Regioselective Hydrogenation of Oxiranes Original Research Article
Pages 153-159
F. Notheisz, Á.G. Zsigmond, M. Bartók, D. Ostgard, G.V. Smith

Chemo-, Regio- and Stereoselectivity in Steroid Hydrogenation with Cu/Al2O3. Intra- and Intermolecular Hydrogen Transfer Reactions. Original Research Article
Pages 161-168
N. Ravasio, M. Gargano, V.P. Quatraro, M. Rossi

Selective Hyorogenation of Aromatic and Aliphatic Nitro Compounds by Hydrogen Transfer Over Mgo Original Research Article
Pages 169-176
J. Kijeńiski, M. Gliński, R. Wiśniewski, S. Murghani

Mass Transfer Considerations for the Enantioselective Hydrogenation of α-KETO Esters Catalyzed by Cinchona Modified Pt/Al2O3 Original Research Article
Pages 177-184
M. Garland, H.P. Jalett, H.U. Blaser

Selective Carvone Hydrogenation on Rh Supported Catalysts Original Research Article
Pages 185-191
R. Gomez, J. Arredondo, N. Rosas, G. Del Angel

Selective Hydrogenation of Citral in the Liquid Phase over Unsupported Nickel-Molybdenum Catalysts Nil-xMox. Original Research Article
Pages 193-200
J. Court, F. Janati-Idrissi, S. Vidal

Sulfur Removal from Terpenes by Hydrodesulfurization on Carbon-Supported Catalysts Original Research Article
Pages 201-208
F. Casbas, D. Duprez, J. Ollivier

Studies on the Catalytic Hydrogenation of Resin Acids Derivatives: Synthesis of a Benzoxazole Original Research Article
Pages 209-213
B. Gigante, A.M. Lobo, S. Prabhakar, M.J. Marcelo-Curto, D.J. Williams

The Isomerisation of Lactose to Lactulose Catalysed by Alkaline ION-Exchangers Original Research Article
Pages 215-221
B.F.M. Kuster, J.A.W.M. Beenackers, H.S. van der Baan

Furanic Derivatives Synthesis from Polyols by Heterogeneous Catalysis Over Metals. Original Research Article
Pages 223-230
C. Montassier, J.C. Menezo, J. Moukolo, J. Naja, J. Barbier, J.P. Boitiaux

Activity and Stability of Promoted Raney-Nickel Catalysts in Glucose Hydrogenation Original Research Article
Pages 231-236
P.J. Cerino, G. Fleche, P. Gallezot, J.P. Salome

Transformation of Sugar into Glycols on a 5% Ru/C Catalyst Original Research Article
Pages 237-244
P. Müller, P. Rimmelin, J.P. Hindermann, R. Kieffer, A. Kiennemann, J. Carré

Selective Hydrogenation of Acetophenone on Unpromoted Raney Nickel : Influence of The Reaction Conditions Original Research Article
Pages 245-252
J. Masson, P. Cividino, J.M. Bonnier, P. Fouilloux

Chemoselective Reduction of Enones to Allylic Alcohols Original Research Article
Pages 253-261
Jan Kaspar, Alessandro Trovarelli, Franco Zamoner, Erica Farnetti, Mauro Graziani

Comparison of Homogeneous and Heterogeneous Palladium Catalysts in the Carbonylation of Allyl Ethers Original Research Article
Pages 263-268
M.M. Barreto-Rosa, M.C. Bonnet, I. Tkatchenko

Liquid-Phase Selective Hydrogenation of 1, 4–Butynediol on Supported Ni and Ni-Cu Catalysts. Original Research Article
Pages 269-276
F.M. Bautista, J.M. Campelo, A. Garcia, R. Guardeño, D. Luna, J.M. Marinas

Catalytic Properties of Transition Metal Sulphides for the Dehydrogenation of Sulphur Containing Molecules Original Research Article
Pages 277-285
M. Lacroix, H. Marrakchi, C. Calais, M. Breysse, C. Forquy

Reactions of Unsaturated Ethers on a Copper-Chromium Catalyst Original Research Article
Pages 287-293
R. Hubaut, J.P. Bonnelle

Hydrogenation of Methyl-3, Butenal on Polycrystalline Platinum Original Research Article
Pages 295-303
C.-M. Pradier, E. Margot, Y. Berthier, G. Cordier

Surface Chemistry and Catalysis with Organic Nitro Compounds, Looking for the Key to Higher Selectivities Original Research Article
Pages 305-312
P.A.J.M. Angevaare, A. Maltha, T.L.F. Favre, A.P. Zuur, V. Ponec

Preparation of Orthophenylenediamine From 4-Chloro-2-Nitroaniline Original Research Article
Pages 313-320
J.L. Margitfalvi, M. Hegedüs, S. Göbölös, E. Táles

Chemoselective Hydrogenation of Aromatic Chloronitro Compounds with Amidine Modified Nickel Catalysts. Original Research Article
Pages 321-328
P. Baumeister, H.U. Blaser, W. Scherrer

Intermediates Formation in the Catalytic Hydrogenation of Nitriles Original Research Article
Pages 329-334
Ph. Marion, P. Grenouiilet, J. Jenck, M. Joucla

Reductive Amination of Acetone on Tin Modified Skeletal Nickel Catalysts Original Research Article
Pages 335-342
S. Göbölös, E. Talas, M. Hegedüs, J.L. Margitfalvi, J. Ryczkowski

Synthesis of Dimethylalkylamines from Acids and Esters over Promoted Copper Catalysts. Original Research Article
Pages 343-350
J. Barrault, G. Delahay, N. Essayem, Z. Gaizi, C. Forquy, R. Brouard

Tertiary Amine Preparation by Reductive Alkylation of Aliphatic Secondary Amines with Ketones Original Research Article
Pages 351-358
R.E. Malz Jr., H. Greenfield

Effect of Promoters on Pt/Sio2 Catalysts for the N-Alkylation of Sterically Hindered Anilines in the Vapor Phase Original Research Article
Pages 359-365
Milos Rusek

Polyfunctionality of Zn-CrO(Pd) Catalyst for the Synthesis of Pyrazines from Diamines and Glycols Original Research Article
Pages 367-376
Lucio Forni, Roberta Miglio

From Surfaces to Discrete Molecules as Catalysts for Alkene Epoxidation Original Research Article
Pages 377-384
Karl Anker Jørgensen

On the oxygen tolerance of noble metal catalysts in liquid phase alcohol oxidations the influence of the support on catalyst deactivation Original Research Article
Pages 385-394
P. Vinke, W. van der Poel, H. van Bekkum

Iron-Phthallocyanines Encaged in Zeolite Y and Vpi-5 Molecular Sieve as Catalysts for the Oxyfunctionalization of n-Alkanes Original Research Article
Pages 395-403
Rudy F. Parton, Lieve Uytterhoeven, Peter A. Jacobs

Mild Oxidation of Cyclic C6-C10 Hydrocarbons in Liquid Phase at Room Temperature by Heterogeneous Photocatalysis Original Research Article
Pages 405-412
J.M. Herrmann, W. Mu, P. Pichat

Oxidative Dehydrogenation of 3-Hydroxy-4-Methye 4-Penten-2-One to 4-Methyl-4-Penten-2,3-Dione over Cuo-Based Catalysts Original Research Article
Pages 413-421
Hans G.-J. Lansink Rotgerink, Gerhard Penn, Peter C. Fünfschilling, Alfons Baiker

Partial Oxidation of Toluene to Benzaldehyde Original Research Article
Pages 423-430
M. Ai

New Polydentate Mo(vi) - Grafted Poly(Amido Amine) Resins as Heterogeneous Epoxidation Catalysts Original Research Article
Pages 431-436
P. Ferruti, E. Tempesti, L. Giuffre, R. Ranucci, C. Mazzocchia

Selective Oxidation of Methyl Ethyl Ketone to Diacetyl Over Vanadium Phosphorus Oxide Catalysts. Original Research Article
Pages 437-444
E. McCullagh, J.B. McMonagle, B.K. Hodnett

(Heterogeneous) Photocatalytic Oxidation of Toluene Using Pure and Iron-Doped Titania Catalysts Original Research Article
Pages 445-453
J.A. Navio, M. Garcia Gomez, M.A. Pradera Adrian, J. Fuentes Mota

Synthesis of Nitriles by Reaction of p-Xylene with no Over Cr2O3-Al2O3 Catalysts Original Research Article
Pages 455-462
S. Zine, A. Ghorbel

Selective Electrocatalytic Oxidation of Glyoxal in Aqueous Medium Original Research Article
Pages 463-470
E.M. Belgsir, H. Huser, C. Lamy, J.-M. Leger

Nitric Acid Associated with Inorganic Solids: A Versatile Reagent and Catalyst in the Chemistry of Aromatics Original Research Article
Pages 471-478
M.H. Gubelmann, C. Doussain, P.J. Tirel, J.M. Popa

Dehydration of Carboxamides to Nitriles Using Sulphated Zirconia Catalyst Original Research Article
Pages 479-486
R.A. Rajadhyaksha, G.W. Joshi

Saturated and Unsaturated Ketones Manufactured by Heterogeneous Catalysis Original Research Article
Pages 487-494
W. Reith, M. Dettmer, H. Widdecke, B. Fleischer

Condensation of Methyl N-Phenyl Carbamate with Solid Acid Catalysts Original Research Article
Pages 495-502
Jae S. Lee, Chul W. Lee, Sang M. Lee, Jae S. Oh, Kwang H. Park

Zeolites as Base Catalysts. Preparation of Calcium Antagonists Intermediates by Condensation of Benzaldehyde with Ethyl Acetoacetate. Original Research Article
Pages 503-511
A. Corma, R.M. Martín-Aranda, F. Sánchez

Mechanism of Phenylacetate Transformation on Zeolites Original Research Article
Pages 513-522
Y. Pouilloux, J-P. Bodibo, I. Neves, M. Gubelmann, G. Perot, M. Guisnet

Orthoselective Alkylation of 2-Ethyl Aniline With Methanol on Ferric Oxide Catalysts Original Research Article
Pages 523-530
J. Valyon, R.M. Mihalyi, D. Kallo

Rearrangement of Cyclohexanone Oxime to Caprolactam Over Solid Acid Catalysts. Original Research Article
Pages 531-538
T. Curtin, J.B. McMonagle, B.K. Hodnett

Beckmann Rearrangement Reactions on Acidic Solids Original Research Article
Pages 539-547
E. Gutierrez, A.J. Aznar, E. Ruiz-Hitzky

Selective Ring-Opening of Isomeric 2-Methyl-3-Phenyloxiranes on Oxide Catalysts Original Research Article
Pages 549-556
Árpád Molnár, Imre Bucsi, Mihály Bartók

MONO and Tridirectional 12-Membered Ring Zeolites as Acid Catalysts for Carbonyl Group Reactions Original Research Article
Pages 557-564
M.J. Climent, A. Corma, H. Garcia, S. Iborra, J. Primo

Triple Bond Hydration Using Zeolites as Catalysts Original Research Article
Pages 565-571
A. Finiels, P. Geneste, M. Lasperas, F. Marichez, P. Moreau

Rearrangement of Epoxides Using Modified Zeolites Original Research Article
Pages 573-579
M. Chamoumi, D. Brunel, P. Geneste, P. Moreau, J. Solofo

The Gas Phase Isomerisation of Substituted Halobenzenes on Zeolites Original Research Article
Pages 581-588
B. Coq, J. Pardillos, F. Figueras

Kaolin Promoted Wittig Olefination and Aromatic Nitration Original Research Article
Pages 589-596
C. Collet, P. Laszlo

Author Index
Pages 597-600

Subject Index
Pages 601-603

Studies in Surface Science and Catalysis
Pages 605-608