Handbook of Stimuli-Responsive Materials

Handbook of Stimuli-Responsive Materials......Page 5
Contents......Page 7
Preface......Page 13
List of Contributors......Page 17
1.1 Introduction......Page 21
1.2 Controlled Free Radical Polymerization of Stimuli-Responsive Polymers......Page 23
1.3 Synthesis of Stimuli-Responsive Colloidal Dispersions......Page 31
References......Page 41
2.1 Introduction......Page 47
2.2.1.1 Glucose-Responsive Systems Based on Glucose-GOx......Page 48
2.2.1.2 Glucose-Responsive Systems Based on ConA......Page 49
2.2.1.3 Glucose-Responsive Systems Based on Boronic Acid-Diol Complexation......Page 50
2.2.2 Enzyme-Responsive Polymers......Page 52
2.2.3 Antigen-Responsive Polymers......Page 53
2.2.4 Redox-/Thiol-Responsive Polymers......Page 55
2.3.1 Electroresponsive Polymers......Page 59
2.3.2 Magnetoresponsive Polymers......Page 60
2.3.3 Ultrasound-Responsive Polymers......Page 62
2.3.4 Photoresponsive Polymers......Page 63
2.4 Conclusions......Page 66
References......Page 67
3.1 Introduction......Page 79
3.2.1 Continuum Equations......Page 81
3.2.2 Formulation of the Gel Lattice Spring Model (gLSM)......Page 83
3.2.3 Model Parameters and Correspondence between Simulations and Experiments......Page 87
3.3.1.1 Linear Stability Analysis in Limiting Cases......Page 89
3.3.1.2 Oscillations Induced by the Release of Confinement......Page 92
3.3.1.3 Behavior of Partially Confined Samples......Page 94
3.3.2.1 Modeling the Photosensitivity of the BZ Gels......Page 97
3.3.2.2 Autonomous Motion toward the Dark Region......Page 98
3.3.2.3 Light-Guided Motion along Complex Paths......Page 101
3.4 Conclusions......Page 107
References......Page 109
4.1 Introduction......Page 113
4.2 Damage and Repair Mechanisms in Polymers......Page 117
4.2.1.1 Angstrom-Level Repairs......Page 119
4.2.1.2 Nanometer-Level Repairs......Page 127
4.2.1.3 Micrometer-Level Repairs......Page 130
4.2.1.4 Millimeter-Level Repairs......Page 132
4.3 Summary......Page 133
References......Page 134
5.1 Introduction......Page 137
5.2 Excimer-Forming Sensor Molecules......Page 138
5.3 Fluorescent Mechanochromic Sensors......Page 141
5.4 Thermochromic Sensors......Page 149
5.5 Chemical Sensing with Excimer-Forming Dyes......Page 153
5.6 Summary and Outlook......Page 155
References......Page 156
6.2.1 High-Density and Low-Density Self-Assembled Monolayers......Page 159
6.2.2 Self-Assembled Monolayers with Hydroquinone Incorporation......Page 161
6.3.1 Molecules Containing Azobenzene Units......Page 162
6.3.2 Molecules Containing Spiropyran Units......Page 163
6.3.3 Photoresponsive Shape-Memory Polymers......Page 164
6.4 pH-Responsive Materials......Page 165
6.4.2 pH-Switchable Surfaces Based on Polymer Brushes......Page 166
6.5.1 Temperature-Dependent Switching Based on Poly(N-iso-propylacrylamide) (PNIPAAm)......Page 167
6.5.3 Thermoresponsive Shape-Memory Polymers......Page 169
6.6 Switchable Surfaces Based on Supramolecular Shuttles......Page 170
6.6.1 Rotaxane Shuttles......Page 171
6.6.2 Switches Based on Catenanes......Page 172
6.7.1 DNA-Based Surface Switches......Page 173
6.7.2 Switches Based on Aptamers......Page 174
6.7.4 Switchable Surfaces of Elastinlike Polypeptides (ELP)......Page 175
References......Page 177
7.1 Introduction......Page 185
7.2 Fabrication of Multilayer Polymer Coatings......Page 187
7.3.1 Salt Concentration Change......Page 189
7.3.2 pH Alternation......Page 190
7.3.3 Temperature Variation......Page 195
7.3.4 Light Radiation......Page 198
7.3.5 Electrochemical Stimuli......Page 201
7.3.6 Specific Molecular Interaction......Page 203
7.4 Conclusion and Outlook......Page 204
References......Page 205
Further Reading......Page 210
8.1 Introduction......Page 211
8.2.1 Charge Generation and Transport in Polymers......Page 213
8.2.2 Electro-Optic Response in Polymers......Page 220
8.2.3 Formation of Photorefractive Gratings......Page 224
8.3 The Two-Beam Coupling Effect......Page 225
8.4.1 Guest–Host Polymer Systems......Page 226
8.4.2 Functionalized Polymer Systems......Page 231
8.5.1 Photoconductivity and Electro-Optic Responses......Page 233
8.5.2 Two-Beam Coupling......Page 234
8.5.3 Diffraction Efficiency and Response Time......Page 236
References......Page 238
9.1 Introduction......Page 243
9.2.1 Influence of Molecular Structures......Page 244
9.2.2 Environmental Effects......Page 246
9.2.3 Kinetics of Photoreactions......Page 247
9.3.1 Azobenzenes......Page 249
9.3.2 Spiropyrans......Page 251
9.3.3 Diarylethenes......Page 254
9.3.4 Fulgides......Page 257
9.4 Outlook of Photochromic Materials......Page 258
References......Page 260
10.1 Introduction......Page 267
10.2 Electrodeposited Coatings......Page 268
10.3 Electrografted Coatings......Page 269
10.4.1 Aliphatic Primary Amines......Page 270
10.4.2 Arylacetates......Page 272
10.4.3 Primary Alcohols......Page 273
10.5.1 Aryldiazonium Salts......Page 274
10.5.2 (Meth)acrylic Monomers......Page 278
10.5.3 Iodide Derivatives......Page 283
10.6 Conclusions......Page 284
References......Page 285
Index......Page 289