کلمات کلیدی مربوط به کتاب فمتوشیمی: شیمی و صنایع شیمیایی، شیمی عمومی، نظری و معدنی
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Wiley, 2001. — 447 p.
Фемтохимия - за работы в этой области
А. Зивэйл получил Нобелевскую премию по химии 1999 г.: «за
исследования химических реакций в реальном масштабе времени с
помощью фемтосекундной спектроскопии». Главный результат работ
состоит в том, что появилась возможность наблюдать за
протеканием элементарных химических реакций "в реальном
масштабе времени" и тем самым создан новый раздел химии –
фемто-химия, который изучает химические процессы в
фемтосекундном временном диапазоне (10^-15 – 10^-12 секунды).
Изучением элементарных реакций занимается специальный раздел
химии – химическая динамика. Основная задача химической
динамики – определить структуру переходного состояния и
проследить динамику его образования и распада в реальном
времени.
Contents
Femtochemistry: Atomic-Scale Dynamics
of the Chemical Bond Using Ultrafast Lasers (Nobel
Lecture)
Transition State Theory and Reaction Dynamics - An
Overview
Organic Femtochemistry: Diradicals, theory and
Experiments
The Coulomb Explosion Imaging Method and excited-State
Proton-Transfer Reactions
Femtosecond Dynamics at Conical Intersections
Femtosecond Spectroscopy of Molecular Caging: Quantum and
Classical Approaches
Ultrafast Geometrical Relaxation in Polydiacetylene Induced by
Sub-5-fs-Pulses
Ultrafast Probing and Control of Molecular Dynamics: Beyond the
Pump-Probe Method
Quantum Control of Ultrafast Laser-Driven isomerization
Reactions: Proton Transfer and Selective Preparation of
Enantiomers
Controlling the Vibration and Dissociation Dynamics in Small
Moleculesand Clusters
Two-Dimensional Optical Nonlinear Spectroscopy in Liquids
Femtosecond Diffuse Reflectance Spectroscopy and Photochemistry
of Organic Molecules
Impurity Rydberg States as Probes of Local Dynamics in the
Condensed Phase
Photoelectron Spectroscopy as a Probe for Investigating
Chemical Dynamics
Femtochemistry in Nanocavities
Energy- and Angle-Resolved Femtosecond Photoelectron Spectra
from Rotating Molecules
Femtosecond Time-resolved Fluorescence and Anisotropy Decay
Spectroscopy of a Dendrimer with Eight Chromophores at the
Rim
Excited-State Dynamics of Conjugated Polymers and
Oligomers
Excited-State Intramolecular Proton Transfer (ESIPT) and Energy
Relaxation Processes in Hydroxyphenylbenzotriazole Derivatives:
A Femtosecond Laser Study
Direct Detection of the Charge-Shift Reaction in Aromatic Vinyl
Polymers by means of Transient Absorption and Dichroism
Measurements
Femtosecond Chemical Events of Intramolecular Charge Transfer
and Intermolecular Hydrogen Bond Breaking after Electronic
Excitation: Structural Dynamics in the Condensed Phase
Vibrational Coherence in Electron Donor-Acceptor Complexes:
Assignment of the Oscillatory Mode
Femtosecond Studies of the Initial Events in the Photocycle of
Photozctive Yellow Protein (PYP)
Elementary Reactions in the Condensed Phase: Bond Breaking,
Isomerization, and Electron Transfer
Primary Processes in Photosynthesis by Femtosecond Nonlinear
Spectroscopy
Femtosecond Studies of Intramolecular Bond Twisting in Solution