Encyclopedia of Inorganic Chemistry, Second Edition (10 Volume Set)

Actinides: Inorganic &\rCoordination Chemistry......Page 1
Actinides: Organometallic\rChemistry......Page 32
Alkali Metals: Inorganic\rChemistry......Page 59
Alkali Metals:\rOrganometallic Chemistry......Page 83
Alkaline Earth Metals:\rInorganic Chemistry......Page 94
Alloys......Page 116
Aluminum: Inorganic\rChemistry......Page 130
Aluminum:\rOrganometallic Chemistry......Page 146
Ammonia & N-donor\rLigands......Page 171
Analytical Chemistry of\rthe Transition Elements......Page 198
Antimony: Inorganic\rChemistry......Page 210
Antimony: Organometallic\rChemistry......Page 218
Arsenic: Inorganic\rChemistry......Page 227
Arsenic: Organoarsenic\rChemistry......Page 248
Asymmetric Synthesis by Homogeneous Catalysis......Page 270
Beryllium & Magnesium:\rOrganometallic Chemistry......Page 293
Biomineralization......Page 320
Bismuth: Inorganic Chemistry......Page 333
Bismuth: Organometallic\rChemistry......Page 354
Bonding Energetics of\rOrganometallic\rCompounds......Page 370
Borates: Solid-stateChemistry......Page 389
Borides: Solid-stateChemistry......Page 399
Boron Hydrides......Page 412
Boron: Inorganic\rChemistry......Page 417
Boron:\rMetallacarbaboranes......Page 442
Boron–Nitrogen\rCompounds......Page 464
Boron: Organoboranes......Page 480
Boron: Polyhedral\rCarboranes......Page 519
Cadmium: Inorganic &\rCoordination Chemistry......Page 523
Cadmium: Organometallic\rChemistry......Page 541
Calcium-binding Proteins......Page 551
Carbides: Transition Metal\rSolid-state Chemistry......Page 587
Carbon: Fullerenes......Page 603
Carbon: Inorganic\rChemistry......Page 626
Carbonyl Complexes of the\rTransition Metals......Page 639
Carbonylation Processes\rby Homogeneous Catalysis......Page 657
Cation-activated Enzymes......Page 690
Chalcogenides: Solid-state\rChemistry......Page 699
Chlorine, Bromine, Iodine,\r& Astatine: Inorganic\rChemistry......Page 738
Chromium: Biological\rRelevance......Page 759
Chromium: Inorganic &\rCoordination Chemistry......Page 765
Chromium:\rOrganometallic Chemistry......Page 779
Cobalt: B12 Enzymes &\rCoenzymes......Page 797
Cobalt: Inorganic &\rCoordination Chemistry......Page 817
Cobalt: Organometallic\rChemistry......Page 842
Coordination Chemistry:\rHistory......Page 879
Coordination Numbers &\rGeometries......Page 903
Coordination &\rOrganometallic\rChemistry: Principles......Page 915
Copper: Hemocyanin/\rTyrosinase Models......Page 931
Copper: Inorganic &\rCoordination Chemistry......Page 940
Copper: Organometallic\rChemistry......Page 959
Copper Proteins with\rDinuclear Active Sites......Page 974
Copper Proteins: Oxidases......Page 989
Copper Proteins with\rType 1 Sites......Page 1015
Cyanide Complexes of the\rTransition Metals......Page 1043
Cytochrome Oxidase......Page 1054
Decarbonylation Catalysis......Page 1066
Defects in Solids......Page 1072
Dielectric Polarizabilities\rof Oxides & Fluorides......Page 1091
Diffraction Methods in\rInorganic Chemistry......Page 1099
Dinuclear Organometallic\rCluster Complexes......Page 1135
Dioxygen & Related\rLigands......Page 1162
Electrochemistry:\rApplications in Inorganic\rChemistry......Page 1170
Electron Transfer in\rCoordination Compounds......Page 1176
Electron Transfer\rReactions: Theory......Page 1198
Electronic Structure of\rClusters......Page 1213
Electronic Structure of\rMain-group Compounds......Page 1233
Electronic Structure of\rOrganometallic\rCompounds......Page 1261
Electronic Structure of\rSolids......Page 1286
Fluorides: Solid-state\rChemistry......Page 1312
Fluorine: Inorganic\rChemistry......Page 1338
Gallium: Inorganic\rChemistry......Page 1363
Gallium: Organometallic\rChemistry......Page 1396
Germanium: Inorganic\rChemistry......Page 1404
Germanium:\rOrganometallic Chemistry......Page 1425
Gold: Inorganic &\rCoordination Chemistry......Page 1448
Gold: Organometallic\rChemistry......Page 1463
Halides: Solid-state\rChemistry......Page 1474
Heterogeneous Catalysis\rby Metals......Page 1494
High Pressure Synthesis of\rSolids......Page 1511
Hydride Complexes of the\rTransition Metals......Page 1527
Hydrides: Solid State\rTransition Metal\rComplexes......Page 1535
Hydroboration Catalysis......Page 1568
Hydrocyanation by\rHomogeneous Catalysis......Page 1577
Hydrodesulfurization &\rHydrodenitrogenation......Page 1583
Hydrogen: Inorganic\rChemistry......Page 1600
Hydrogenation &\rIsomerization of Alkenes......Page 1624
Hydrosilation Catalysis......Page 1643
Hypervalent Compounds......Page 1655
Indium: Inorganic\rChemistry......Page 1676
Indium: Organometallic\rChemistry......Page 1693
Cluster Compounds:\rInorganometallic\rCompounds Containing\rTransition Metal & Main\rGroup Elements......Page 1742
Intercalation Chemistry......Page 1763
Ionic Conductors......Page 1800
Iridium: Inorganic &\rCoordination Chemistry......Page 1834
Iridium: Organometallic\rChemistry......Page 1852
Iron: Heme Proteins &\rDioxygen Transport &\rStorage......Page 1870
Iron: Heme Proteins &\rElectron Transport......Page 1884
Iron: Heme Proteins,\rMono- & Dioxygenases......Page 1905
Iron: Heme Proteins,\rPeroxidases, Catalases &\rCatalase-peroxidases......Page 1935
Iron: Inorganic &\rCoordination Chemistry......Page 1956
Iron: Models of Proteins\rwith Dinuclear Active Sites......Page 2001
Iron: Organometallic\rChemistry......Page 2013
Iron Porphyrin Chemistry......Page 2097
Iron Proteins with\rDinuclear Active Sites......Page 2229
Iron Proteins with\rMononuclear Active Sites......Page 2244
Iron Proteins for Storage\r& Transport & their\rSynthetic Analogs......Page 2265
Iron–Sulfur Models of\rProtein Active Sites......Page 2287
Iron–Sulfur Proteins......Page 2298
Iron Transport:\rSiderophores......Page 2329
Lead: Inorganic Chemistry......Page 2356
Lead: Organometallic\rChemistry......Page 2370
Ligand Field Theory &\rSpectra......Page 2379
Luminescence......Page 2399
Macrocyclic Ligands......Page 2417
Magnetic Oxides......Page 2437
Magnetism of Extended\rArrays in Inorganic Solids......Page 2472
Magnetism of Transition\rMetal Ions......Page 2496
Manganese: Inorganic &\rCoordination Chemistry......Page 2507
Manganese:\rOrganometallic Chemistry......Page 2520
Manganese: The\rOxygen-evolving Complex\r&Models......Page 2536
Manganese Proteins with\rMono- & Dinuclear Sites......Page 2551
Mechanisms of Reaction of\rOrganometallic Complexes......Page 2562
Mercury: Inorganic &\rCoordination Chemistry......Page 2582
Mercury: Organometallic\rChemistry......Page 2597
Metal Ion Toxicity......Page 2606
Metal Vapor Synthesis of\rTransition Metal\rCompounds......Page 2617
Metallic Materials\rDeposition: Metal-organic\rPrecursors......Page 2628
Metalloregulation......Page 2651
Metallothioneins......Page 2667
Metathesis Polymerization\rProcesses by Homogeneous\rCatalysis......Page 2680
Mixed Donor Ligands......Page 2691
Mixed Valence Compounds......Page 2713
Molecular Orbital Theory......Page 2726
Molybdenum: Inorganic &\rCoordination Chemistry......Page 2750
Molybdenum:\rMPT-containing Enzymes......Page 2778
Molybdenum:\rOrganometallic Chemistry......Page 2798
Mossbauer Spectroscopy......Page 2816
Nickel Enzymes &\rCofactors......Page 2843
Nickel: Inorganic &\rCoordination Chemistry......Page 2859
Nickel: Models of Protein\rActive Sites......Page 2891
Nickel: Organometallic\rChemistry......Page 2909
Niobium & Tantalum:\rInorganic & Coordination\rChemistry......Page 2929
Niobium & Tantalum:\rOrganometallic Chemistry......Page 2954
Nitrogen Monoxide (Nitric\rOxide): Bioinorganic\rChemistry......Page 2983
Nitrides: Transition Metal\rSolid-state Chemistry......Page 3004
Nitrogen: Inorganic\rChemistry......Page 3021
Nitrogenase: Metal Cluster\rModels......Page 3090
Nitrogenase Catalysis &\rAssembly......Page 3104
Noble Gases: Inorganic\rChemistry......Page 3121
Noncrystalline Solids......Page 3140
Nucleic Acid–Metal Ion\rInteractions......Page 3158
Nutritional Aspects of\rMetals & Trace Elements......Page 3192
Oligomerization &\rPolymerization by\rHomogeneous Catalysis......Page 3200
Organic Synthesis using\rTransition Metal Carbonyl\rComplexes......Page 3216
Organic Synthesis using\rTransition Metal\rComplexes Containing\rπ-Bonded Ligands......Page 3281
Osmium: Inorganic &\rCoordination Chemistry......Page 3336
Osmium: Organometallic\rChemistry......Page 3360
Oxidation Catalysis by\rTransition Metal\rComplexes......Page 3378
Oxide Catalysts in\rSolid-state Chemistry......Page 3384
Oxides: Solid-state\rChemistry......Page 3405
Oxygen: Inorganic\rChemistry......Page 3453
P-donor Ligands......Page 3499
Palladium: Inorganic &\rCoordination Chemistry......Page 3526
Palladium: Organometallic\rChemistry......Page 3546
Paramagnetic\rOrganometallic Complexes......Page 3587
Peptide–Metal Interactions......Page 3599
Periodic Table: Trends in\rthe Properties of the\rElements......Page 3613
Phosphates: Solid-state\rChemistry......Page 3627
Phosphides: Solid-state\rChemistry......Page 3643
Phosphorus: Inorganic\rChemistry......Page 3696
Phosphorus–Nitrogen\rCompounds......Page 3717
Phosphorus:\rOrganophosphorus\rChemistry......Page 3744
Photochemistry of\rTransition Metal\rComplexes......Page 3762
Photochemistry of\rTransition Metal\rComplexes: Theory......Page 3807
Photoelectron\rSpectroscopy of Transition\rMetal Systems......Page 3822
Photosynthesis......Page 3850
Platinum-based Anticancer\rDrugs......Page 3878
Platinum: Inorganic &\rCoordination Chemistry......Page 3889
Platinum: Organometallic\rChemistry......Page 3898
Polonium: Inorganic\rChemistry......Page 3934
Polonium: Organometallic\rChemistry......Page 3942
Polyhedra......Page 3945
Polynuclear\rOrganometallic Cluster\rComplexes......Page 3949
Polyoxometalates......Page 3966
Polyphosphazenes......Page 3977
Polysiloxanes & Polysilanes......Page 3984
Quasicrystals......Page 4002
Rhenium: Organometallic\rChemistry......Page 4005
Rhodium: Inorganic &\rCoordination Chemistry......Page 4052
Rhodium: Organometallic\rChemistry......Page 4082
Ruthenium: Inorganic &\rCoordination Chemistry......Page 4117
Ruthenium:\rOrganometallic Chemistry......Page 4139
S-donor Ligands......Page 4171
Scandium, Yttrium & the\rLanthanides: Inorganic &\rCoordination Chemistry......Page 4198
Scandium, Yttrium & the\rLanthanides:\rOrganometallic Chemistry......Page 4238
Selenium: Inorganic\rChemistry......Page 4291
Selenium: Organoselenium\rChemistry......Page 4315
Selenium Proteins\rContaining Selenocysteine......Page 4330
Semiconductor Interfaces......Page 4340
Semiconductors......Page 4357
Short-lived Intermediates......Page 4373
Silicon: Inorganic\rChemistry......Page 4403
Silicon: Organosilicon\rChemistry......Page 4452
Silver: Inorganic &\rCoordination Chemistry......Page 4482
Silver: Organometallic\rChemistry......Page 4492
Sol–Gel Synthesis of Solids......Page 4499
Solids: Characterization by\rPowder Diffraction......Page 4510
Solids: Computer\rModeling......Page 4528
Stability Constants & their\rDetermination......Page 4545
Stereochemical Nonrigidity\rof Organometallic\rComplexes......Page 4554
Structure & Property\rMaps for Inorganic Solids......Page 4588
Sulfur: Inorganic\rChemistry......Page 4607
Sulfur–Nitrogen\rCompounds......Page 4643
Sulfur: Organic\rPolysulfanes......Page 4669
Superconductivity......Page 4703
Supported\rOrganotransition Metal\rCompounds......Page 4716
Surfaces......Page 4726
Symmetry Point Groups......Page 4751
Technetium & Rhenium:\rInorganic & Coordination\rChemistry......Page 4755
Technetium:\rOrganometallic Chemistry......Page 4772
Tellurium: Inorganic\rChemistry......Page 4782
Tellurium:\rOrganotellurium\rChemistry......Page 4805
Thallium: Inorganic\rChemistry......Page 4823
Thallium: Organometallic\rChemistry......Page 4835
Thin Film Synthesis of\rSolids......Page 4848
Tin: Inorganic Chemistry......Page 4856
Tin: Organometallic\rChemistry......Page 4871
Titanium: Inorganic &\rCoordination Chemistry......Page 4900
Titanium: Organometallic\rChemistry......Page 4911
Transition Metal\rCarbonyls: Infrared\rSpectra......Page 4941
Tungsten: Inorganic &\rCoordination Chemistry......Page 4956
Tungsten: Organometallic\rChemistry......Page 4981
Tungsten Proteins......Page 5002
Vanadium in Biology......Page 5010
Vanadium: Inorganic &\rCoordination Chemistry......Page 5022
Vanadium:\rOrganometallic Chemistry......Page 5039
Water & O-donor Ligands......Page 5059
Zeolites......Page 5077
Zinc: DNA-binding\rProteins......Page 5113
Zinc Enzymes......Page 5131
Zinc: Inorganic &\rCoordination Chemistry......Page 5174
Zinc: Organometallic\rChemistry......Page 5200
Zintl Compounds......Page 5253
Zirconium & Hafnium:\rInorganic & Coordination\rChemistry......Page 5262
Zirconium & Hafnium:\rOrganometallic Chemistry......Page 5286
Alkaline Earth Metals:\rOrganometallic Chemistry......Page 5324
Biomimetic Synthesis of\rNanoparticles......Page 5355
Bond Lengths in Inorganic\rSolids & Liquids......Page 5376
Metal-related Diseases of\rGenetic Origin......Page 5383
Hard & Soft Acids and\rBases......Page 5397
Long-range Electron\rTransfer in Biology......Page 5402
Luminescence Behavior &\rPhotochemistry of\rOrganotransition Metal\rCompounds......Page 5414
Metal-based Drugs......Page 5445
Metal-based Imaging\rAgents......Page 5474
Metal-mediated Protein\rModification......Page 5494
Metallocenter Biosynthesis\r& Assembly......Page 5507
Metallochaperones &\rMetal Ion Homeostasis......Page 5515
Metalloprotein Design &\rEngineering......Page 5522
Multi-Heme Cytochromes\r& Enzymes......Page 5556
Semiconductor\rNanocrystal Quantum Dots......Page 5573
Organic Synthesis Using\rMetal-mediated Metathesis\rReactions......Page 5595
Organic Synthesis Using\rMetal-mediated Coupling\rReactions......Page 5640
Porous Inorganic Materials......Page 5660
Self-assembled Inorganic\rArchitectures......Page 5681
Periodic Table: Historical\rAspects......Page 5726
Hydrogen Bonding &\rDihydrogen Bonding......Page 5736
Dihydrogen Complexes &\rRelated Sigma Complexes......Page 5741
Carbon–Carbon &\rCarbon–Heteroatom\rActivation......Page 5747
Carbene Complexes......Page 5753
Low Coordinated Group\r13 Chelates......Page 5761
Main Group Carbenes......Page 5765
Main Group: Multiple\rBonding......Page 5784
Copper Proteins with\rType 2 Sites......Page 5791
Copper Enzymes in\rDenitrification......Page 5816
Beryllium: Inorganic\rChemistry......Page 5827
Low Oxidation State Main\rGroup......Page 5833
Alkane Carbon–Hydrogen\rBond Activation......Page 5845
Transition Metal\rComplexes with Bulky\rAllyl Ligands......Page 5852
Subvalent Compounds......Page 5858
Group 14 Multiple\rBonding......Page 5876
Sol–Gel Encapsulation of\rMetal and Semiconductor\rNanocrystals......Page 5917
Metal Nanoparticles,\rSynthesis of......Page 5926
Metal Nanoparticles,\rOrganization &\rApplications of......Page 5940
Carbon: Nanotubes......Page 5958
Inorganic Ring Systems......Page 5992
High-Energy Electron Diffraction......Page 6020
High Resolution Electron Energy-Loss Spectroscopy......Page 6047
Magnetic Circular Dichroism (MCD) Spectroscopy......Page 6065
Metal Analysis......Page 6081
Microwave Rotational Spectroscopy......Page 6102
Neutron Diffraction......Page 6118
Neutron Scattering......Page 6137
Nuclear Magnetic Resonance (NMR) Spectroscopy of\rInorganic/Organometallic Molecules......Page 6160
Nuclear Magnetic Resonance (NMR) Spectroscopy of\rMetallobiomolecules......Page 6201
Nuclear Quadrupole Resonance (NQR) Spectroscopy......Page 6229
Nuclear Resonance Vibrational Spectroscopy (NRVS)......Page 6244
Perturbed Angular Correlations of γ -rays (PAC)\rSpectroscopy......Page 6265
Photoelectron Spectroscopy......Page 6282
Photoluminescence and Electroluminescence, Solid State......Page 6301
Rapid Scan, Stopped-Flow Kinetics......Page 6309
Resonance Raman\rSpectroscopy......Page 6328
Vibrational Spectroscopy......Page 6365
X-Ray Absorption Spectroscopy......Page 6389
X-Ray Powder Diffraction......Page 6405
Circular Dichroism (CD) Spectroscopy......Page 6436
Electrochemistry......Page 6452
Electron Paramagnetic Resonance (EPR) Spectroscopy......Page 6474
Electron Spin Echo Envelope Modulation (ESEEM)\rSpectroscopy......Page 6490
Electronic Spectroscopy......Page 6513
Electron-Nuclear Double Resonance (ENDOR)\rSpectroscopy......Page 6533
Freeze-Quench Kinetics......Page 6559
Gold in Homogeneous\rCatalysis......Page 6577
N-Heterocyclic\rCarbene-Containing Metal\rComplexes......Page 6615