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دانلود کتاب Comprehensive Inorganic Chemistry III
دانلود کتاب شیمی معدنی جامع III
مشخصات کتاب
Comprehensive Inorganic Chemistry III
ویرایش:
نویسندگان: Ram Seshadri. Serena Cussen
سری:
ISBN (شابک) : 9780128231449
ناشر: Elsevier
سال نشر: 2023
تعداد صفحات: 387
زبان: English
فرمت فایل : PDF (درصورت درخواست کاربر به PDF، EPUB یا AZW3 تبدیل می شود)
حجم فایل: 18 مگابایت
قیمت کتاب (تومان) : 80,000
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فهرست مطالب
Cover Half Title Comprehensive Inorganic Chemistry III. Volume 5: Inorganic Materials Chemistry Copyright Contents of Volume 5 Editor Biographies Volume Editors Contributors to Volume 5 Preface Vol. 1: Synthesis, Structure, and Bonding in Inorganic Molecular Systems Vol. 2: Bioinorganic Chemistry and Homogeneous Biomimetic Inorganic Catalysis Vol. 3: Theory and Bonding of Inorganic Non-molecular Systems Vol. 4: Solid State Inorganic Chemistry Vol. 5: Inorganic Materials Chemistry Vol. 6: Heterogeneous Inorganic Catalysis Vol. 7: Inorganic Electrochemistry Vol. 8: Inorganic Photochemistry Vol. 9: NMR of Inorganic Nuclei Vol. 10: X-ray, Neutron and Electron Scattering Methods in Inorganic Chemistry 5.01. Introduction: Inorganic materials chemistry Abstract 5.02. Data-driven materials discovery and synthesis using machine learning methods Content Abbreviations Abstract 5.02.1 Introduction to experimental and computational machine learning validation 5.02.2 Training dataset size organization of validation articles 5.02.2.1 1–100 Training datapoints 5.02.2.1.1 Bayesian optimization (BO) and adaptive design (AD) techniques 5.02.2.1.2 Non-Bayesian optimization (BO) 5.02.2.2 101–10,000 Training datapoints 5.02.2.2.1 Support vector machine (SVM) and adaptive design (AD) 5.02.2.2.2 Support vector machine (SVM) and cluster resolution feature selection (CR-FS) 5.02.2.2.3 General support vector machine (SVM) 5.02.2.2.4 Non-support vector machine (SVM) 5.02.2.3 10,000D Training datapoints 5.02.2.3.1 Artificial neural network (ANN) 5.02.2.3.2 Random forest (RF) 5.02.2.3.3 Decision tree (DT) 5.02.2.3.4 Bayesian optimization (BO) 5.02.3 A caution about cross-validation (CV) 5.02.4 An eye towards extraordinary predictions 5.02.5 Conclusion References 5.03. Metathesis routes to materials Content Abstract 5.03.1 Introduction 5.03.2 Descriptive chemistry of metathesis reactions 5.03.2.1 Binary products 5.03.2.1.1 Self-propagating reactions 5.03.2.1.2 Thermally-controlled metathesis 5.03.2.1.3 Transport-promoted metathesis 5.03.2.2 Ternary and multinary products 5.03.2.2.1 Ternary metathesis 5.03.2.2.2 Assisted metathesis 5.03.2.2.3 Heteroanionic metathesis 5.03.3 Thermodynamics and kinetics of metathesis reactions 5.03.3.1 Maximizing DG 5.03.3.2 Metathesis kinetics 5.03.3.3 Avoiding thermodynamic sinks 5.03.3.4 Targeting metastable phases via metathesis 5.03.4 Conclusion Acknowledgements References 5.04. Solvothermal and hydrothermal methods for preparative solid-state chemistry Content Abstract 5.04.1 Introduction and definitions 5.04.2 Historical and practical aspects 5.04.3 Classes of materials prepared under solvothermal conditions 5.04.3.1 Porous inorganic materials 5.04.3.1.1 Zeolites 5.04.3.1.2 Zeotypes 5.04.3.1.3 Open-framework oxides and other chalcogenides 5.04.3.1.4 Other open-framework inorganic materials 5.04.3.2 Hybrid organic-inorganic materials 5.04.3.2.1 Hybrid metal oxides and coordination polymers 5.04.3.2.2 Metal-organic frameworks 5.04.3.3 Some oxyanion analogs of minerals 5.04.3.4 Condensed materials 5.04.3.4.1 Binary oxides 5.04.3.4.2 Multinary oxides 5.04.3.4.3 Sulfides, selenides, tellurides 5.04.3.4.4 Nitrides, phosphides and arsenides 5.04.3.4.5 Carbides and carbons 5.04.3.4.6 Halides 5.04.3.4.7 Metals and intermetallics 5.04.3.5 Layered materials 5.04.3.6 Composite materials 5.04.4 Mechanistic aspects of solvothermal crystallization 5.04.4.1 Exploration of synthetic variables 5.04.4.2 Crystallization mechanism 5.04.4.3 In situ studies of solvothermal crystallization 5.04.5 Conclusions Acknowledgment References 5.05. Spark plasma sintering routes to consolidated inorganic functional materials Content Abstract 5.05.1 Introduction 5.05.2 The context and understanding of SPS 5.05.2.1 The influence of temperature 5.05.3 Considerations for densifying a new material using SPS 5.05.3.1 Material chemistry considerations 5.05.3.2 From a bulk powder to a dense pellet 5.05.3.3 Simultaneous reaction and consolidation 5.05.3.4 From a dense pellet to characterization 5.05.4 Example applications of SPS routes to inorganic functional materials 5.05.4.1 Energy materials 5.05.4.1.1 Phosphors 5.05.4.1.2 Thermoelectrics 5.05.4.1.3 All solid state batteries 5.05.4.2 Amorphous materials 5.05.4.3 Insulating electroceramics 5.05.4.3.1 Dielectrics 5.05.4.3.2 Piezoelectrics 5.05.4.3.3 Ferroelectrics References 5.06. Hydride precursors in materials synthesis Content Abstract 5.06.1 Introduction 5.06.2 Hydrides as reducing agents for the synthesis of reduced oxides and oxyhydrides 5.06.2.1 Reduced oxides 5.06.2.1.1 Ternary perovskites and perovskite-like 5.06.2.1.2 Multinary perovskites and perovskites-like with substitution in the B-site 5.06.2.1.3 Multinary perovskites and perovskites-like oxides with the substitution in A-site 5.06.2.2 Reduced oxides obtained from non-perovskite phases 5.06.2.3 Oxyhydrides 5.06.3 Hydrides as an unintentional source of hydrogen and hydrogenous Zintl phases 5.06.4 Hydrides as a source of alkali, alkaline earth, and rare earth metals 5.06.5 Hydrides in SPS and high-pressure synthesis 5.06.6 Hydrides for the synthesis of nanoparticles 5.06.7 Conclusion and outlook Acknowledgment References 5.07. Metal chalcogenide materials: Synthesis, structure and properties Content Abstract 5.07.1 Introduction 5.07.2 Crystal structures of metal chalcogenides 5.07.2.1 Heavy metal-based chalcogenides 5.07.2.1.1 Lead, tin and germanium chalcogenides 5.07.2.1.2 Bismuth and antimony chalcogenides 5.07.2.1.3 Thallium and indium chalcogenides 5.07.2.1.4 Ternary metal chalcogenides 5.07.2.2 Transition metal-based chalcogenides 5.07.3 Synthetic methodologies 5.07.3.1 Solid-state melting method 5.07.3.2 Use of fluxes 5.07.3.3 Chemical vapor deposition (CVD) 5.07.3.4 Single crystal growth 5.07.3.5 Synthesis of nanocrystals and nanosheets 5.07.4 Properties and applications of metal chalcogenides 5.07.4.1 Superconductivity 5.07.4.1.1 Iron chalcogenides 5.07.4.1.2 Transition metal dichalcogenides 5.07.4.2 Topological insulator 5.07.4.3 Thermoelectrics 5.07.4.4 Non-linear optical properties 5.07.4.5 Water purification 5.07.4.5.1 Three-dimensional metal sulfides 5.07.4.5.2 Layered metal sulfides 5.07.5 Conclusions and future outlook Acknowledgments References 5.08. Preparation of magnetocaloric materials Content Abstract 5.08.1 Introduction to magnetocaloric materials 5.08.1.1 Brief history of magnetocaloric effect and magnetic refrigeration 5.08.1.2 Thermodynamics of magnetocaloric effect and material requirements 5.08.1.2.1 MCE in bulk crystalline materials 5.08.1.2.2 Measurements of magnetocaloric effect 5.08.1.2.3 Ferrofluids and magnetocaloric fluids 5.08.1.3 Material design criteria 5.08.2 Single crystal growth of magnetocaloric materials 5.08.2.1 Bridgman single crystal growth 5.08.2.2 Tri-arc single crystal growth 5.08.2.3 Recrystallization 5.08.2.4 Flux single crystal growth 5.08.3 Preparation of bulk magnetocaloric materials 5.08.3.1 Synthesis of the polycrystalline materials 5.08.3.1.1 Arc-melting 5.08.3.1.2 Sintering 5.08.3.1.3 Preparation in sealed Nb or Ta tubes. RF induction heating 5.08.3.1.4 Mechanical alloying 5.08.3.1.5 Spark plasma sintering 5.08.3.1.6 Solid-vapor synthesis 5.08.3.1.7 Microwave synthesis 5.08.3.2 Amorphous materials and their preparation 5.08.4 Conclusions Acknowledgment References 5.09. Materials synthesis for Na-ion batteries Content Abstract 5.09.1 General introduction to sodium-ion batteries 5.09.2 Anode materials 5.09.2.1 Hard carbons 5.09.2.1.1 Structure and sodiation mechanism 5.09.2.1.2 Precursor choice 5.09.2.1.3 Heteroatom doping 5.09.2.1.4 Thermal treatment 5.09.2.1.5 Hydrothermal synthesis 5.09.2.2 Conversion and alloy-type materials 5.09.3 Cathode materials 5.09.3.1 Sodium transition metal oxides 5.09.3.2 Polyanionic compounds 5.09.3.3 Prussian blue analogs 5.09.4 Conclusion References 5.10. Crystalline inorganic materials from supertetrahedral chalcogenide clusters Content Abstract 5.10.1 Introduction 5.10.1.1 Origin of supertetrahedral chalcogenide clusters 5.10.1.2 Classification of supertetrahedral chalcogenide clusters 5.10.1.2.1 Tn-type chalcogenide clusters 5.10.1.2.2 Pn-type of chalcogenide clusters 5.10.1.2.3 Cn-type of chalcogenide clusters 5.10.1.2.4 o-Tn type of chalcogenide clusters 5.10.1.2.5 Tp,q type of chalcogenide clusters 5.10.1.3 Bottom-up assembly and crystallization 5.10.1.3.1 Protonated organic amines-assisted solvothermal synthesis 5.10.1.3.2 Hydrated inorganic cation-assisted solvothermal synthesis 5.10.1.3.3 Ionothermal synthesis 5.10.1.4 From a supertetrahedral cluster to a cluster-based superlattice 5.10.1.4.1 Non-bonding packing 5.10.1.4.2 Intercluster assembly into cluster-based chalcogenide frameworks 5.10.1.4.3 Hybrid assemblies of different supertetrahedral clusters into chalcogenide frameworks 5.10.1.4.4 Framework topology of 3D cluster-based open frameworks 5.10.1.5 Discrete clusters in crystal lattice and their dispersibility in solvent 5.10.1.6 Functionalization and applications 5.10.1.6.1 Photoelectric performance 5.10.1.6.2 Photoluminescence (PL) performance 5.10.1.6.3 Electrochemiluminescence (ECL) behavior 5.10.1.6.4 Intercluster or intracluster charge transfer in cluster-based chalcogenides 5.10.1.6.5 Ion-exchange and host-guest chemistry 5.10.1.6.6 Photo /electrocatalytic applications 5.10.1.7 Conclusions and prospects References 5.11. Designing new polar materials Content Abstract 5.11.1 Introduction: Polar materials in context 5.11.2 Theoretical background and definitions 5.11.2.1 Dielectrics 5.11.2.2 Pyroelectrics, ferroelectrics and relaxors 5.11.2.3 Order-disorder and displacive descriptions of polar materials 5.11.2.3.1 Order-disorder polar phases 5.11.2.3.2 Displacive polar phases 5.11.2.3.3 The order parameter 5.11.2.4 Symmetry requirements for polar crystalline materials 5.11.2.5 Summary 5.11.3 Strategies for designing polar materials 5.11.3.1 The cation sublattice 5.11.3.1.1 The second-order Jahn-Teller effect (SOJT) for d0 ions 5.11.3.1.1.1 Perovskites 5.11.3.1.1.2 Hexagonal and tetragonal tungsten bronzes 5.11.3.1.2 The cation sublattice: Second-order Jahn-Teller effect (SOJT) for ns2np0 ions 5.11.3.1.2.1 Perovskites 5.11.3.1.2.2 Layered perovskite-related materials 5.11.3.1.2.2.1 Aurivillius phases 5.11.3.1.2.2.2 Dion-Jacobson phases 5.11.3.1.3 Exceptions: Geometric and topological ferroelectrics 5.11.3.1.4 Summary 5.11.3.2 The cation sublattice: Cation ordering 5.11.3.2.1 Corundum-derived structures 5.11.3.2.1.1 Corundum-derived LiNbO3-type materials 5.11.3.2.1.2 Corundum-derived ordered-ilmenite materials 5.11.3.2.1.3 Corundum-derived Ni3TeO6-type materials 5.11.3.2.1.4 Cation ordering in other structure types, and summary 5.11.3.3 The anion sublattice: Non-centrosymmetric structural units 5.11.3.3.1 Homoleptic units 5.11.3.3.1.1 Brownmillerites 5.11.3.3.2 Heteroleptic units 5.11.3.3.3 Summary 5.11.3.4 The anion sublattice: Coupled non-polar distortions (hybrid-improper ferroelectricity) 5.11.3.4.1 Hybrid-improper mechanisms in Ruddlesden-Popper phases 5.11.3.4.2 Hybrid-improper mechanisms in Dion-Jacobson phases 5.11.3.4.3 Summary 5.11.3.5 Magnetoelectrics 5.11.3.5.1 Introduction to magnetic order 5.11.3.5.2 Introduction to magnetoelectrics 5.11.3.5.3 Magnetostriction-driven polarization 5.11.3.5.4 Spin-current driven polarization 5.11.3.5.5 Metal-ligand hybridization driven polarization 5.11.3.5.6 Summary of spin-driven polarization 5.11.3.6 Future directions 5.11.4 Experimental methods 5.11.4.1 Synthesis methods and sample preparation 5.11.4.2 Structural characterization 5.11.4.3 Property measurements 5.11.5 Conclusions References 5.12. Max phases and mxenes Content Abstract 5.12.1 Introduction to MAX phases and MXenes 5.12.2 Structure 5.12.2.1 Ordered MAX phases 5.12.2.1.1 o-MAX 5.12.2.1.2 i-MAX 5.12.2.2 MXenes 5.12.3 Stability/“Formability”/“Exfoliability” 5.12.4 Synthesis of MAX phases and MXenes 5.12.4.1 Bulk MAX phases 5.12.4.1.1 Focus: Microwave heating 5.12.4.1.2 Focus: Sol-gel based synthesis 5.12.4.2 Thin film MAX phases 5.12.4.3 MXenes 5.12.4.3.1 Variations to the standard techniques References 5.13. Amorphization of hybrid framework materials Content Abstract 5.13.1 Introduction to hybrid framework materials 5.13.2 Ball-milling induced amorphization 5.13.2.1 Mechanosynthesis 5.13.2.2 Structural collapse upon ball-milling 5.13.2.3 Mechanistic aspects of collapse 5.13.2.4 Defect introduction 5.13.2.5 Proposed application and outlook 5.13.3 Thermal characterization of MOFs 5.13.3.1 Thermogravimetric analysis (TGA) and thermal decomposition 5.13.3.2 Differential scanning calorimetry 5.13.4 Melting and glass formation in metal-organic frameworks 5.13.4.1 Theory 5.13.4.2 Melting in coordination polymers and MOFs 5.13.4.3 Hybrid melt quenched glass examples 5.13.4.3.1 Zeolitic imidazolate frameworks 5.13.4.3.2 Hybrid organic-inorganic perovskite structures 5.13.4.3.3 Other three-dimensional coordination framework materials 5.13.4.3.4 Lower dimensional coordination polymers 5.13.5 Pressure and temperature induced polymorphism and collapse 5.13.5.1 Rich MOF polymorphism in PT space 5.13.5.2 Melting curves 5.13.6 Conclusion References 5.14. Total scattering and pair distribution function analysis for studies of nanomaterials Content Abstract 5.14.1 Introduction 5.14.2 Analysis of nanoparticle structure from scattering data in Q-space: From Rietveld refinement to total scattering analysis 5.14.3 Analysis of nanostructure in r-space: PDF analysis 5.14.3.1 Introduction to the PDF 5.14.3.2 Data analysis in real space: Model free analysis of total scattering data 5.14.3.3 Real space Rietveld refinement on total scattering data 5.14.3.4 Discrete structure modeling of nanomaterials 5.14.3.5 Reverse Monte Carlo methods 5.14.3.6 d-PDF studies 5.14.4 Combination of characterization techniques and complex modeling 5.14.5 Time- and position-resolved studies of nanoparticle chemistry 5.14.6 Conclusion and outlook References 5.15. In situ/in operando diffraction studies of electrode materials in battery applications Content Abstract 5.15.1 Introduction 5.15.2 Cell designs for in situ/in operando characterization of electrode materials using X-ray, synchrotron or neutron radiation 5.15.2.1 In situ electrochemical cells for X-ray scattering 5.15.2.2 In situ\\in operando electrochemical cells for neutron scattering 5.15.2.2.1 Neutron diffraction 5.15.2.2.2 In situ/in operando small angle neutron scattering (SANS) 5.15.2.2.3 In situ/in operando neutron reflectometry 5.15.2.2.4 In situ/in operando neutron imaging 5.15.2.2.5 In situ/in operando neutron depth profiling (NDP) 5.15.3 Characterization of electrode materials 5.15.3.1 Neutron diffraction 5.15.3.1.1 In situ/in operando characterization of electrode materials with neutron diffraction 5.15.3.1.2 In situ/in operando neutron diffraction studies on commercial cells 5.15.3.1.3 In situ/in operando spatially-resolved neutron diffraction studies 5.15.3.2 Diffraction of X-ray\\synchrotron radiation 5.15.3.2.1 In situ/in operando characterization of structural evolution for selected electrode materials 5.15.3.2.1.1 Structural behavior of NMC electrodes 5.15.3.2.1.2 In situ/in operando behavior of LiFePO4 olivine-type cathode 5.15.3.2.2 In situ pair distribution function (PDF) 5.15.3.2.3 In situ X-ray diffraction radiography and tomography 5.15.3.2.3.1 Attenuation-based imaging 5.15.3.2.3.2 X-ray diffraction tomography 5.15.3.3 Electron diffraction 5.15.4 Perspectives Acknowledgments References
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