Chemistry of Functional Materials Surfaces and Interfaces: Fundamentals and Applications

Front-Matter_2021_Chemistry-of-Functional-Materials-Surfaces-and-Interfaces
	Front Matter
Copyright_2021_Chemistry-of-Functional-Materials-Surfaces-and-Interfaces
	Copyright
Preface_2021_Chemistry-of-Functional-Materials-Surfaces-and-Interfaces
	Preface
Chapter-1---Introduct_2021_Chemistry-of-Functional-Materials-Surfaces-and-In
	Introduction
		Reference
Chapter-2---Thermal-energy-_2021_Chemistry-of-Functional-Materials-Surfaces-
	Thermal energy scale kT
		Reference
Chapter-3---Surfaces-and-in_2021_Chemistry-of-Functional-Materials-Surfaces-
	Surfaces and interfaces
		Surface tension of liquids
		Predictive models for calculating the surface tension of liquids
		Interfacial tension between liquids
		Relating surface tension to surface energy
		Surface and interfacial energy of solids
		Solid-liquid interfaces
		Scaling effects: When surface tension dominates gravity
			Case study: How surface tension of liquids affects life at small scale and in outer space?
		Capillary rise
		Capillary number
			Curved liquid surfaces, Laplace pressure, Young-Laplace equation
			Case study: Emulsions and foams
		Kelvin equation
		Case study: Surface tension of liquids at the nanoscale and in nanopores
		Methods for measuring the surface and interfacial tensions of liquids
			Case study: Aerosol spray coatings and the importance of the dynamic surface tension
		Measuring ultralow interfacial tension-The spinning drop tensiometer
			Case study: Role of interfacial tension in enhanced oil recovery
		Surface and interfacial tensions with temperature
		References
Chapter-4---Surfactants-and-a_2021_Chemistry-of-Functional-Materials-Surface
	Surfactants and amphiphiles
		Introduction
		Brief historical account of surfactants
		Major classes of surfactants
			Anionic surfactants
			Cationic surfactants
			Zwitterionic and amphoteric
			Nonionic surfactants
		Other important classes of surfactants
			Specialty surfactants
			Gemini surfactants
			Biosurfactants
		Self-assembly of surfactants
			Self-assembly in ternary systems, foams, and emulsions
			Attempting to quantify amphiphilicity with HLB
		Case study: An intuitive understanding of the structure-activity relationship in surfactants
			Amphiphilicity beyond the molecular scale-Janus particles
		Supra-amphiphiles
		Surfactants and the environment
		References
Chapter-5---Wettability-of-surfaces--nanopa_2021_Chemistry-of-Functional-Mat
	Wettability of surfaces, nanoparticles, and biomimetic functional surfaces
		Contact angle of liquids on macroscopic surfaces
			From macroscopic to microscopic sessile droplets
		Classification of surface hydrophobicity vs. the magnitude of the contact angle with water
		Dynamic, advancing, and receding contact angle
		Contact angle hysteresis
		Wettability of liquids on rough and nanostructured surfaces-Wenzel model
		Wettability of liquids on heterogeneously flat surfaces-Cassie-Baxter model
		Transition from Cassie-Baxter to Wenzel state
			Case study: Wettability of antifogging surfaces-From mirrors to solar panels
		Roll-off and sliding angles of a sessile droplet
			Case study: Waterproof clothing
		Measurement of the contact angle with the captive bubble method
		Natural and biomimetic functional surfaces
			Case study: Water collecting surfaces and surface directional transport of droplets
			Marangoni flow
			Case study: Nonstick ``omniphobic´´ surfaces-From mobile phone screens to car interior surfaces
			Case study: Research in ``icephobic´´ surfaces for the aircraft industry, biomimicry inspired by penguins, and ca ...
		Adhesion of cells on rough and nanostructured surfaces
		Spreading and superspreading in the presence of surfactants
			The autophobic and autophilic effects
			Case study: Superwetting agents in agriculture and surface cleaning
			Surface cleaning mechanism
		Contact angle of micro- and nanoparticles
			Wettability of (nano-)powders, nanofibers, and porous materials-Washburn method
			Case study: Ore separation by flotation
		References
Chapter-6---The-fundamental-equati_2021_Chemistry-of-Functional-Materials-Su
	The fundamental equations of interfaces
		The thermodynamic perspective-Energy of adhesion
		Fowkes model for the energy of adhesion
		Owens, Wendt, Rabel, and Kaelble (OWRK) method
		Girifalco-Good equation of state
		Neumann's equation of state
		Van Oss, Choudhury, and Good (OCG) model
		Fox-Zisman model
		Case study: Usefulness of interfacial models in applications
		Case study: Wetting envelope
		Case study: Pickering emulsions and energy of adhesion of nanoparticles to immiscible phases
		References
Chapter-7---Elements-of-thermodyna_2021_Chemistry-of-Functional-Materials-Su
	Elements of thermodynamics of interfaces
		Gibbs-Duhem equation for interfaces
		Gibbs adsorption isotherm
		Choice of the boundary thickness, Gibbs dividing line, and excess function
		Interfacial adsorption isotherms and surface tension
		References
Chapter-8---Populated-interfaces-a_2021_Chemistry-of-Functional-Materials-Su
	Populated interfaces and their reactivity
		Partitioning of solute between immiscible phases
		Partitioning and adsorption at liquid interfaces
		Soluble films-Gibbs monolayers
		Insoluble films-Langmuir monolayers
		Langmuir-Blodgett monolayers-Manipulation of a monolayer of molecules
		Self-assembled monolayers
		References
Chapter-9---Metal-organic-interfaces-in-_2021_Chemistry-of-Functional-Materi
	Metal-organic interfaces in organic and unimolecular electronics
		Energy levels at metal-organic interfaces
		Electron transport across metal-organic interface
		Basic organic electronic devices and their metal-organic interfaces
		Role of interfacial tension in organic electronic devices
		Unimolecular electronics
			Making electrical contacts to single molecules vs monolayers of oriented molecules
			Metal-organic interfaces: Weak vs strong coupling
			Transport mechanism through MOMs
			Archetypal unimolecular device-The unimolecular rectifier and rectification mechanism
		References
Chapter-10---Main-interaction-forces-be_2021_Chemistry-of-Functional-Materia
	Main interaction forces between molecules and interfaces
		van der Waals interactions between molecules and between interfaces
			Attractive and repulsive van der Waals interactions
			Combining laws applied to van der Waals interactions
			Surface tension and surface energies from intermolecular forces
		Hydrogen bonding
		Dipole-dipole interactions
		Hydrophobic interaction
		Repulsive hydration force
		Hildebrand and Hansen solubility parameters
		Flory-Huggins interaction parameter
		References
Chapter-11---Interactions-between-elec_2021_Chemistry-of-Functional-Material
	Interactions between electrically charged interfaces
		Electric double layer
		Distribution of counterions in the absence of electrolyte
		Distribution of counterions around a charged surface in the presence of electrolyte
		Grahame equation and Debye length
		Double-layer interaction forces and energies
		DLVO theory
		Zeta potential
		Case study: Constructing the interaction potentials between nanoparticles with DLVO and non-DLVO forces
		References
Chapter-12---Colloids-and-nan_2021_Chemistry-of-Functional-Materials-Surface
	Colloids and nanoparticles
		Lyophobic colloids
		Preparation of the lyophobic colloids
		Preparation of colloids by solvent replacement and physical condensation
		Chemical synthesis of lyophobic colloids
		Interfacial forces and stability of lyophobic colloids
		Lyophilic colloids
		References
Chapter-13---Role-of-interfaces-in-the-synthes_2021_Chemistry-of-Functional-
	Role of interfaces in the synthesis of polymeric nanoparticles and nanostructured materials
		Case study: Synthesis of polymeric nanoparticles via emulsion polymerization
			Emulsion polymerization in the presence of surfactants
				Surfactant-free emulsion polymerization
				Emulsion polymerization with polymerizable surfactants-Synthesis of surfactant-free nanoparticles
			Miniemulsion polymerization
			Microemulsion polymerization
			Ultrasonic-assisted surfactant-free emulsion polymerization
			Seeded emulsion polymerization for preparation of core-shell and asymmetric Janus nanoparticles
		Case study: Synthesis of nanostructured materials from Pickering emulsions
			Bulk polymerization of Pickering emulsion droplets
			Interfacial polymerization of Pickering emulsion droplets
		References
Chapter-14---Adsorption-and-interactio_2021_Chemistry-of-Functional-Material
	Adsorption and interaction of particles at interfaces
		Adsorption of nanoparticles at interfaces
		Interfacial adsorption dynamics and mechanism
		Interaction between nanoparticles at interfaces
		Langmuir-Blodgett assembly of nanoparticles into 2D crystals
		Templated self-assembly of nanoparticles at interfaces
		References
Chapter-15---A-short-account-of-the-role-of-_2021_Chemistry-of-Functional-Ma
	A short account of the role of interfaces in Integrated Circuits manufacturing
		Introduction of photolithography and Integrated Circuits manufacturing
		Role of interfaces in photolithography
			Surface tension and pattern collapse of nanometer scale structures
			Particle removal in IC manufacturing
		References
Index_2021_Chemistry-of-Functional-Materials-Surfaces-and-Interfaces
	Index
		A
		B
		C
		D
		E
		F
		G
		H
		I
		J
		K
		L
		M
		N
		O
		Pp
		Q
		R
		S
		T
		U
		V
		W
		X
		Y
		Z