Aqueous Organometallic Chemistry and Catalysis

Front Matter....Pages i-xviii
Summary of the Round Table Discussion of the State of the Art and Future Directions of Aqueous Organometallic Chemistry and Catalysis....Pages 1-13
Transition Metal Catalyzed Reactions of Olefins in Water: Olefin Metathesis and Isomerization....Pages 15-22
Aqueous Organometallic Chemistry. Effects of a Reactive Solvent....Pages 23-32
Aqueous Chemistry and Catalytic Activity of Organometallic Iridium Complexes....Pages 33-45
Organometallic Radical Chemistry in Aqueous Solution....Pages 47-60
The Use of 1,3,5-Triaza-7-Phosphaadamantane (PTA), A Water-Soluble , Air Stable Ligand, in Organometallic Chemistry and Catalysis....Pages 61-80
Recent Developments in Metal Catalyzed Biphasic Reactions....Pages 81-95
Counter Phase Transfer Catalysis by Water-Soluble Phosphine Complexes....Pages 97-110
Metal-Catalysed Hydrophosphination as a Route to Water-Soluble Phosphines....Pages 111-122
Aqueous Media in the Intramolecular Heck Reaction....Pages 123-125
New Efficient Water-Soluble Catalysts for Two-Phase Olefin Hydroformylation....Pages 127-129
Rhodium and Palladium Water-Soluble Complexes in the Carbonylation Reactions. Improvement in the Transfer between the Organic and Aqueous Phases....Pages 131-147
New Water Soluble Phosphines for Organometallic Chemistry and Catalysis in the Aqueous Phase....Pages 149-158
Hexaaquaruthenate(II) as Catalyst Precursor in Aqueous Organometallic Catalysis....Pages 159-171
Ruthenium-Catalyzed Oxidation of Chlorinated Hydrocarbons in Aqueous Medium....Pages 173-175
Hydrosoluble Ligands for a New Technology....Pages 177-181
Comparative Study of Biphase Reduction of Carbonyl Compounds Catalyzed by Homogeneous and Water Soluble Ru Catalysts....Pages 183-185
Three Approaches to Catalytic Aqueous Organometallic Chemistry Involving Water Soluble Ligands, Some Modified Cyclodextrins as Ligands, and Reactions in an Aluminophosphate Cavity....Pages 187-194
Models for Supported Aqueous-Phase Catalysis....Pages 195-197
Stoichiometric and Exhaustive Hydrolysis of N,N ,-Dialkylcarbamates....Pages 199-209
Composite Hydrogels of the Polysaccharide / Polyvalent Metal Type....Pages 211-213
Organometallic Catalysis in Water and in a Two-Phase System....Pages 215-230
Chiral Sulfonated Phosphines in Enantioselective Catalysis....Pages 231-244
Asymmetric Complex Catalysis in Micellar Systems....Pages 245-257
Bioorganometallic Chemistry: The Reactions of a (η 5 -Pentamethylcyclopentadienyl)rhodium Aqua Complex with Nucleobases, Nucleosides, Nucleotides, and Oligonucleotides....Pages 259-276
On Nature’s Aqueous Organometallic and Radical Chemistry with B 12 -Derivatives....Pages 277-279
Catalytic Hydrogenation of Biological Membranes: The Effects on Membrane Physical State and Functions....Pages 281-287
Aqueous Phospholipid Dispersions as Vectors for Selective Homogeneous Catalysis....Pages 289-304
Modification of Biomembranes by Catalytic Hydrogenation....Pages 305-311
Back Matter....Pages 313-317