Advances in Solution Chemistry

Front Matter....Pages i-ix
Solute-Solvent Interactions as Required for the Existence of a Liquid....Pages 1-12
Thermodynamics of Aqueous Dilute Solutions of Non-Charged Molecules....Pages 13-40
Classical Ionic Fluids in the Mean Spherical Approximation....Pages 41-65
A Comparison Between Structures of Aqua and Ammine Complexes in Solutions as Studied by an X-Ray Diffraction Method....Pages 67-79
Copper(II) Chelate Complexes-Solute and/or Solvent Interactions....Pages 81-89
Photo-Induced Ligand-Solvent Interchange in Transition Metal Complexes....Pages 91-104
Mechanism of Octahedral Substitutions on Transition Metal Complexes. Attempts to Distinguish Between D and I d Mechanisms....Pages 105-114
Use of Electron Paramagnetic Resonance Spectroscopy to Study the Interaction Between Cobalt Schiff Base Complexes and Phosphines or Phosphites in Solution....Pages 115-128
An NMR Study of Solvent Interactions in a Paramagnetic System....Pages 129-137
Protonation and Complexation Equilibria of Macromolecular Bioligands in Aqueous and Mixed Solvent Solutions. The Solvent Effect....Pages 139-148
Intramolecular Hydrophobic and Aromatic-Ring Stacking Interactions in Ternary Complexes in Solution....Pages 149-159
Study on Some Dioxygen Carriers - New Models of Natural Systems....Pages 161-174
Direct NMR Studies of Ionic Solvation....Pages 175-190
NMR Studies of Calcium and Magnesium in Biological Systems....Pages 191-208
Synthetic Molecular Membranes and their Functions....Pages 209-220
New Insights into the Host-Guest Solvent Interaction of some Inclusion Complexes. Reaction Path Control in Cyclodextrin Inclusion as a Lyase Model: Solvolysis of β-Bromethyl-1-Naphthalene....Pages 221-230
The Composite Physical and Chemical Approach to the Solution Spatial Structure of Polypeptide Neurotoxins....Pages 231-251
Metalloenzymes and Model Systems. Carbonic Anhydrase: Solvent and Buffer Participation, Isotope Effects, Activation Parameters and Anionic Inhibition....Pages 253-274
Pyridinium-N-Phenoxide Betaine Dyes as Solvent Polarity Indicators. Some New Findings....Pages 275-293
Some Applications of Liquid Crystals in Organic Chemistry....Pages 295-308
Reactions and Behaviour of Organic Anions in Two-Phase Systems....Pages 309-318
Solute-Solvent Interactions in Ring Formation....Pages 319-330
Hydrogen Acidities and Brønsted Relations....Pages 331-340
Solvent Effects on Some Nucleophilic Substitutions....Pages 341-354
Initial State and Transition State Solvent Effects: Reactions in Protic and Dipolar Aprotic Media....Pages 355-371
Solvation Energies in Acid Catalyzed Processes....Pages 373-383
Back Matter....Pages 385-387