Advanced biological active polyfunctional compounds and composites: Health, cultural heritage and environmental protection

ADVANCED BIOLOGICALLY ACTIVE POLYFUNCTIONAL COMPOUNDS AND COMPOSITES: HEALTH, CULTURAL HERITAGE AND ENVIRONMENTAL PROTECTION......Page 4
CONTENTS......Page 6
PREFACE......Page 10
PART 1. CHEMISTRY, USE AND MOLECULAR MODELLING OF BIOLOGICALLY ACTIVE COMPOUNDS......Page 18
ABSTRACT......Page 20
RESULTS AND DISCUSSION......Page 21
MOLECULAR DESIGN OF THE 1-HYDROXYCYCLOHEXYL HYDROPEROXIDE - ALK4NBR COMPLEX......Page 22
KINETIC FEATURES OF THE ACTIVATED  HYDROPEROXIDE DECOMPOSITION......Page 24
REFERENCES......Page 27
ABSTRACT......Page 30
REFERENCES......Page 40
ABBREVIATIONS......Page 44
INTRODUCTION......Page 45
RESULTS AND DISCUSSION......Page 46
REFERENCES......Page 51
ABSTRACT......Page 54
2. EXPERIMENTAL......Page 55
3.1. Synthesis and Quantum-Chemical Investigation of Adamantane-Containing Anilides and Nitroanilides......Page 56
3.2. Models of Physical Properties of Adamantine-Containing Anylides and Nitroanylides......Page 68
3.3. Preliminary evaluation of the bioactivity of the synthesized anilides......Page 72
3.4. Study of Bioactive Properties of Adamantane-Containing Anilides and Nitroanilides......Page 74
REFERENCES......Page 76
INTRODUCTION......Page 80
RESULTS AND DISCUSSION......Page 82
REFERENCES......Page 85
AIMS AND BACKGROUND......Page 88
MATERIALS AND METHODS......Page 89
RESULTS AND DISCUSSION......Page 90
REFERENCES......Page 97
INTRODUCTION......Page 100
DISCUSSION OF RESULTS......Page 101
REFERENCES......Page 104
ABSTRACT......Page 106
AIMS AND BACKGROUND......Page 107
EXPERIMENTAL......Page 108
RESULTS AND DISCUSSIONS......Page 109
REFERENCES......Page 116
PART 2. PHYSICS, THERMODYNAMICS AND KINETICS OF HOMOGENEOUS AND HETEROGENEOUS NANOSYSTEMS......Page 120
ABSTRACT......Page 122
INTRODUCTION......Page 123
METHODOLOGY......Page 124
INSTRUMENTATION, HIGH-PRESSURE UNIT  AND ELECTROCHEMICAL MEASUREMENTS......Page 125
THEORETICAL BACKGROUND......Page 126
EXPERIMENTAL RESULTS (CYTC)......Page 129
MECHANISTIC PATTERNS FOR CYTC......Page 131
BROKEN ERGODICITY FOR ET......Page 136
RESULTS AND DISCUSSION FOR ET IN RTIL......Page 138
ACKNOWLEDGMENTS......Page 145
REFERENCES......Page 146
ABSTRACT......Page 148
INTRODUCTION......Page 149
RESULTS......Page 151
DISCUSSION......Page 157
REFERENCES......Page 160
ABSTRACT......Page 166
Materials......Page 167
Microstructure of the Samples......Page 168
REFERENCES......Page 172
ABSTRACT......Page 174
2. EXPERIMENTAL......Page 175
3. RESULTS AND DISCUSSIONS......Page 176
REFERENCES......Page 184
INTRODUCTION......Page 186
Spectroscopic Measurements......Page 187
Spectrophotometric Studying of Thermodynamics and Kinetics......Page 188
Reactions of (AcO)CrTPP with H2S, Im and Py......Page 189
Reactions of O=Mo(OH)TPP with H2S, Im and Py......Page 193
Reactions of O=W(Oh)TPP with H2s, Im and Py......Page 195
REFERENCES......Page 196
ABSTRACT......Page 198
RESULTS AND DISCUSSIONS......Page 199
REFERENCES......Page 203
INTRODUCTION......Page 204
Materials and Methods......Page 206
DISCUSSION OF RESULTS......Page 207
REFERENCES......Page 210
PART 3. NEW COMPOUNDS FOR MEDICINE......Page 212
INTRODUCTION......Page 214
GENERAL RESULTS......Page 215
REFERENCES......Page 218
AIMS AND BACKGROUND......Page 220
PREPARATION OF N-METHYL-N/-(Β-D-GLUCOSYL)- N-NITROSOUREA......Page 222
PREPARATION OF N-METHYL-N/-(Β-D-XYLOSYL)-N-NITROSOUREA......Page 223
REFERENCES......Page 224
PART 4. BIOFIBERS......Page 226
INTRODUCTION......Page 228
Materials and Methods......Page 232
Procedure of Grafting by Cold Plasma......Page 234
2.1. XPS Analysis of the Fibres Surface......Page 235
3.1. FT-IR Spectra Results......Page 236
REFERENCES......Page 257
ABSTRACT......Page 262
MOTIVATION AND LITERATURE REVIEW......Page 263
HEAD ARTICULATION OF THE BEETLE......Page 264
MATERIALS AND SAMPLE PREPARATION......Page 267
SHAPE AND STRUCTURE OF THE CUTICLE......Page 268
SURFACE ROUGHNESS......Page 269
MECHANICAL PROPERTIES......Page 272
WAX-COATED PLANT SURFACES......Page 276
MATERIALS AND SAMPLE PREPARATION......Page 279
STRUCTURE OF WAX LAYER......Page 280
MECHANICAL PROPERTIES......Page 281
WAX COVERINGS AND INSECT ATTACHMENT PADS......Page 285
REFERENCES......Page 286
PART 5. COMPOUNDS FOR ANTIBIOCORROSIVE COVERS AND PROTECTORS......Page 292
ABSTRACT......Page 294
EXPERIMENTAL......Page 295
RESULTS AND DISCUSSION......Page 296
CONCLUSIONS......Page 310
REFERENCES......Page 311
INTRODUCTION......Page 314
Synthesis......Page 316
Crystal Structure of [(I-Bu)3asch2i]+I3-......Page 318
BIOACTIVITY OF SOME SYNTHESIZED COMPOUNDS......Page 320
REFERENCES......Page 323
PART 6. ENVIRONMENTAL CHEMISTRY......Page 326
ABSTRACT......Page 328
REFERENCES......Page 334
PART 7. PERSONALLY......Page 336
ABSTRACT......Page 338
INDEX......Page 350