Acid-Base Catalysis II: Proceedings of the International Symposium on Acid-Base Catalysis Ii, Sapporo, December 2-4, 1993

Content: 
Edited by
Page iii

Copyright page
Page iv

Organizing Committee
Page v

Scientific Advisory Board
Page v

List of Contributors
Pages vii-xx

Preface
Page xxvii
Hideshi Hattori, Makoto Misono, Yoshio Ono

1.1 Acidic Salts of Heteropolyacids as Solid Acid Catalysts for Liquid-phase Organic Reactions Original Research Article
Pages 1-8
Y. Izumi, K. Urabe

1.2 Inorganic Solid Supported Reagents as Acids and Bases Original Research Article
Pages 9-20
Takashi Ando

1.3 Heteropoly Acids as Catalysts for Organic Reactions Original Research Article
Pages 21-34
Ivan V. Kozhevnikov

1.4 Methanol-Based Synthetic Reactions over Solid-Base Catalysts Original Research Article
Pages 35-46
W. Ueda, H. Ohowa, K. Iwasaki, T. Kuwabara, T. Ohshida, Y. Morikawa

1.5 Novel Direct Hydrogenation Process of Aromatic Carboxylic Acids to the Corresponding Aldehydes with Zirconia Catalyst Original Research Article
Pages 47-58
T. Yokoyama, T. Setoyama, N. Fujita, T. Maki

1.6 Role of Acid and Base Properties of V2O5-Base Metal Oxide Catalysts for Partial Oxidation of p-Substituted Toluene Original Research Article
Pages 59-66
Michio Ueshima, Noboru Saito, Noboru Shimizu

1.7 The Role of Alcohols on Lactam Selectivity in the Vapor-Phase Beckmann Rearrangement Reaction Original Research Article
Pages 67-70
M. Kitamura, H. Ichihashi

1.8 Direct Amination of Lower Alkenes with Ammonia over Zeolite Catalysts Original Research Article
Pages 71-76
Noritaka Mizuno, Masahiro Tabata, Takeshi Uematsu, Masakazu Iwamoto

1.9 Etherification of Diethylene Glycol with Ethanol on Heteropolyacid Original Research Article
Pages 77-84
Qi Yunshi, Liu Jingfun, Wu Haixia, Su Xiaoli

1.10 Acidic Clay-Directed Polymerization-Cyclization of Aldehydes and Pyrrole to Porphyrins Original Research Article
Pages 85-88
Makoto Onaka, Tomotaka Shinoda, Yusuke Izumi, Ernest Nolen

1.11 Acid-catalyzed Rearrangement of Pentacyclic Cage Compound via an Unexpected Route [Part II]: Application of PM3 Calculations to the Reaction Mechanism Original Research Article
Pages 89-92
K. Hirao, H. Takahashi

1.12 Formylation of Aromatic Compounds under Atmospheric CO Pressure Original Research Article
Pages 93-96
Y. Souma, M. Tanaka

1.13 Friedel-Crafts Polyalkylation of Mesitylene with Trichlorotoluene: A Synthesis of 1,3-Connected Polyarylmethanes as Precursors for Organic Magnets Original Research Article
Pages 97-100
Y. Imizu, T. Iino, N. Tanaka, N. Okazaki, H. Itoh, A. Tada, K. Tokumitsu, H. Kakegawa

1.14 Selective Hydrogenation of CFC-12 to HFC-32 on Zr-Pd/C Catalyst Original Research Article
Pages 101-104
R. Ohnishi, W.-L. Wang, M. Ichikawa

2.1 NMR Studies Concerning the Acidity and Catalysis in Zeolites Original Research Article
Pages 105-116
D. Freude, H. Ernst, T. Mildner, H. Pfeifer, I. Wolf

2.2 Catalytic Properties and Physicochemical Nature of Highly Active Protons in Partially Reduced Ag3PW12O40 Original Research Article
Pages 117-128
Toshihide Baba, Mamoru Nomura, Yoshio Ono, Yo-ichi Ohno

2.3 Extra-Framework Sites in H-Al MFI and H-GaMFI Zeolite Catalysts Original Research Article
Pages 129-134
Susan M. Bradley, Sharelle M. Cambell, Jim Hook, Ken Jackson, Leon Van Gorkom, Russell F. Howe

2.4 Solid-state 109Ag-MASNMR Spectroscopic Studies of Trisilver Dodecatungstophosphates Original Research Article
Pages 135-140
Shin-ichi Nakata, Yoshinori Tanaka, Toshihide Baba, Yoshio Ono

2.5 Exchange of Isotopic Hydrogen over Solid Acid/Base Catalysts Original Research Article
Pages 141-146
D. Pfeiler, S. John, K. Thomke, O.M.E. El-Dusouqui

2.6 Elementary Steps of Acid-Base Catalyzed Reactions in Molecular Sieves: Elementary Steps of Acid-Base Catalyzed Reactions in Molecular Sieves Original Research Article
Pages 147-156
Johannes A. Lercher, Gabriele Mirth, Michael Stockenhuber, Thomas Narbeshuber, Andreas Kogelbauer

2.7 Infrared Spectroscopic Observation of N2 Species Adsorbed on Brønsted and Lewis Acid Sites of H-Zeolites at Low Temperatures Original Research Article
Pages 157-162
Fumitaka Wakabayashi, Junko Kondo, Kazunari Domen, Chiaki Hirose

2.8 Studies of Adsorption of Benzene on the Acid and Base Sites of KH ß Zeolite by IR in Situ Original Research Article
Pages 163-168
Jian-ping Shen, Jun Ma, Tie Sun, Zheng Xu, Da-zhen Jiang, En-ze Min

2.9 Interaction of NH3 with O2 at the Surface of MgO Original Research Article
Pages 169-175
G. Martra, E. Borello, E. Giamello, S. Coluccia

2.10 Behavior of CO Monomers Adsorbed on MgO Surfaces at Low Temperatures Original Research Article
Pages 177-182
T. Ito, R.-B. Sim, T. Tashiro, K. Toi, H. Kobayashi

2.11 UV-Vis Study of the Condensation Reaction of Carbonylic Compounds on MgO and Hydrotalcites Original Research Article
Pages 183-193
E. Garrone, D. Bartalini, S. Coluccia, G. Martra, D. Tichit, F. Figueras

2.12 O2-Formation through N2O on ZrO2 Surface: O2− Formation through N2O on ZrO2 Surface Original Research Article
Pages 195-200
Ken-ichi Aika, Eiji Iwamatsu

2.13 Oxygen Isotope Exchange between CO2 Adsorbate and MgO Surfaces Original Research Article
Pages 201-206
K. Takaoka, S. Yamabe, Y. Yanagisawa

2.14 Evaluation of Basicity of Alkali Metal-doped MgO in the Scope of Change of Carbonate Species Original Research Article
Pages 207-212
Tohru Kanno, Masayoshi Kobayashi

2.15 IR Characterization of Base Heterogeneity of Solid Catalysts Original Research Article
Pages 213-216
Hui Wang, Shishao Tan, Fu Zhi

2.16 Structure and Dynamics of Exchanged Cations in Zeolites as Investigated by Molecular Dynamics and Computer Graphics Original Research Article
Pages 217-227
A. Miyamoto, H. Himei, E. Maruya, M. Katagiri, R. Vetrivel, M. Kubo

2.17 Acid Strength of Binary Mixed Oxides: –Estimation by Neural Network and Experimental Verification Original Research Article
Pages 229-232
T. Hattori, S. Kito, H. Niwa, Yenni Westi, A. Satsuma, Y. Murakami

2.18 Quantum Chemical Study on Reactions of Small Molecules on Various MgO Surfaces Original Research Article
Pages 233-243
Hisayoshi Kobayashi, Dennis R. Salahub, Tomoyasu Ito

2.19 Acidic Properties of Sepiolite Original Research Article
Pages 245-250
Y. Kitayama, M. Nomura

3.1 Synthesis of Solid Superacid of Borate Supported on Zirconium Oxides Original Research Article
Pages 251-256
Hiromi Matsuhashi, Kazuyoshi Kato, Kazushi Arata

3.2 Preparation of Platinum-Supported Alumina Lewis Superacid Catalyst Using a CVD Method Original Research Article
Pages 257-262
Akimi Ayame, Kazunori Honda

3.3 Synthesis and Catalytic Properties of Sulfate Ion-Promoted Zr-Pillared Clays Original Research Article
Pages 263-268
M. Katoh, H. Fujisawa, T. Yamaguchi

3.4 The Role of Sulphate in the Stabilisation of Zirconia Original Research Article
Pages 269-272
C.J. Norman, P.A. Goulding, P.J. Moles

3.5 Catalytic Properties of Interlayer Acid Sites of Cation-Exchanged Synthetic Taeniolites Original Research Article
Pages 273-278
T. Uematsu, H. Shoji, T. Odashima, S. Shimazu

3.6 Alkylation of Isobutane with Butene over Layered Double Hydroxide Pillared Heteropolyoxometalate Acid-Base Catalysts Original Research Article
Pages 279-284
Xu Zheng, Wu Yue, He Heming, Jiang Dazhen

3.7 Intercalation of n-Alkylamines into Perovskite-related Layered Niobic Acid HBiNb2O7·nH2O Original Research Article
Pages 285-290
Teruyuki Nakato, Masato Nakade, Kazuyuki Kuroda, Chuzo Kato

3.8 Controlled Pore Opening of VPI-5 by Partial Removal of Water Molecules Original Research Article
Pages 291-294
S. Prasad, Shang-Bin Liu, R. Vetrivel

3.9 Incorporation of Aluminum and Antimony into Mordenite Framework by Atom-planting Method Original Research Article
Pages 295-298
P. Wu, T. Nakano, T. Komatsu, T. Yashima

3.10 A New Method for Preparing High Silica ZSM-48 Catalysts Original Research Article
Pages 299-302
Li Jianquan, Liu Guanghuan, Dong Jinxiang

3.11 Preparation and Catalytic Properties of Composite Zirconium Phosphonates Original Research Article
Pages 303-310
K. Segawa, N. Kihara, S. Nakata

3.12 Grinding of Zirconium Pyrophosphate and its Catalytic Activity for 1-Butene Isomerization Original Research Article
Pages 311-316
Akio Tada, Mitsuru Oishi, Noriyasu Okazaki, Hidenobu Itoh, Yuzo Imizu

3.13 Preparation of Amorphous Metal-substituted Aluminum Phosphates and Their Acid-Base Properties Original Research Article
Pages 317-320
H. Itoh, S. Matsuyama, N. Okazaki, Y. Imizu, A. Tada

3.14 Surface Properties and Catalytic Activities of Superconducting Bi-Pb-Sr-Ca-Cu Oxides for 1-Butene Isomerization Original Research Article
Pages 321-326
Akio Tada, Ryouichi Ishida, Noriyasu Okazaki, Yuzo Imizu, Hidenobu Itoh

3.15 Preparation and Properties of a New Kind of Acid Catalyst of Zeolite Coating on Metal Surface Original Research Article
Pages 327-331
Li Jianquan, Dong Jinxiang, Liu Guanghuan

3.16 Acidic Property of Silica Monolayers on Metal Oxides Prepared by CVD Method Original Research Article
Pages 333-338
Naonobu Katada, Miki Niwa, Yuichi Murakami

3.17 Preparation of Silica-Deposited Alumina Catalyst by Utilizing Organosilicon Complexes as Building Blocks for the Synthesis of Acidic Sites Original Research Article
Pages 339-342
Y. Imizu, K. Takahara, N. Okazaki, H. Itoh, A. Tada, R. Ohnishi, M. Ichikawa

3.18 Activity Enhancement of Men+/SiO2 Catalysts by Sulfiding with Hydrogen Sulfide for Acid-Catalyzed Reactions Original Research Article
Pages 343-348
Masatoshi Sugioka, Nobuyuki Sato, Daisuke Uchida

3.19 Preparation of Basic Zeolite Original Research Article
Pages 349-354
F. Yagi, N. Kanuka, H. Tsuji, H. Kita, H. Hattori

4.1 Prominent Change in Reaction Characteristics of High Silica Zeolite Induced by Isomorphous Substitution with Transition Metals Original Research Article
Pages 355-366
T. Inui, K. Matsuba

4.2 Aromatization of Short Chain Alkanes on Ga MFI Catalysts Original Research Article
Pages 367-378
M. Guisnet, D. Lukyanov

4.3 Shape Selective Alkylation of Aromatics on Metallosilicates Original Research Article
Pages 379-389
T. Yashima, J.-H. Kim, H. Ohta, S. Namba, T. Komatsu

4.4 Alkylation of Naphthalene with Propene to 2,6-Diisopropylnaphthalene on Mordenite Catalysts Original Research Article
Pages 391-396
E. Kikuchi, K. Sawada, M. Maeda, T. Matsuda

4.5 Shape-selective Isopropylation of Naphthalene and Biphenyl over Dealuminated H-Mordenites Original Research Article
Pages 397-408
Y. Sugi, T. Matsuzaki, T. Hanaoka, Y. Kubota, J.H. Kim, X. Tu, M. Matsumoto

4.6 Promotion Effect of Hydrogen on Catalytic Decomposition of Nitrous Oxide (N2O) by H-ZSM-5 Catalyst Original Research Article
Pages 409-412
K. Ebitani, N. Ohshio, A. Morikawa

4.7 Acid-Base Properties of ALPO-5 Molecular Sieves Modified by Nickel and Molybdenum Original Research Article
Pages 413-418
Yu. Kalvachev, A. Spojakina, N. Kostova, L. Dimitrov

4.8 Novel Catalysis of Cesium Salt of Heteropoly Acid and its Characterization by Solid-state NMR Original Research Article
Pages 419-428
T. Okuhara, T. Nishimura, H. Watanabe, K. Na, M. Misono

4.9 The Role of Acid-Base and Redox Features in the Catalytic Behavior of Vanadium-Phosphorous-Oxygen Formulations Original Research Article
Pages 429-440
Laura M. Cornaglia, Eduardo A. Lombardo

4.10 Role of Acidic Sites on Metal Phosphates in the Catalytic Oxidation of iso-Butane Original Research Article
Pages 441-446
Y. Takita, K. Kurosaki, T. Ito, Y. Mizuhara, T. Ishihara

4.11 Production of Silane and Dialkoxysilane by the Disproportionation of Trimethoxy- and Triethoxysilanes over Solid Base Catalysts Original Research Article
Pages 447-450
Y. Nomoto, E. Suzuki, Y. Ono

4.12 Oxidative Dehydrogenation of Ethane over Modified Magnesium Oxides Original Research Article
Pages 451-456
Xiao-ming Zheng, Jian-xin Mao, Bing-xin Cai, Jin-hua Fei, Song-shou Jin

4.13 Hydrogenation of 1,3-Dienes over Tetramethyltin-Promoted Zinc Oxide Catalyst Original Research Article
Pages 457-460
Y. Imizu, M. Toyofuku, N. Okazaki, H. Itoh, A. Tada

4.14 Dehydrogenation of Ethylbenzene over KFeO2: –Catalyst Structure and Reaction Intermediate Original Research Article
Pages 461-466
Hiroshi Miura, Hiroiku Kawai, Tomohiro Taguchi

4.15 Acid-Base Nature of Antimony Oxides Original Research Article
Pages 467-472
S. Tsuchiya, T. Yamada, K. Ishikawa, Y. Sakata, H. Imamura

4.16 Base Sites of Magnesium Oxide Dispersed on Silica as Active Sites for CO Photooxidation Original Research Article
Pages 473-478
Hisao Yoshida, Tsunehiro Tanaka, Kazuhiro Nakatsuka, Takuzo Funabiki, Satohiro Yoshida

4.17 Dynamics of the Adsorption and Hydrogenation of CO on Active ZrO2 Catalyst: –In Situ Photoluminescence, FT-IR, and ESR Investigations– Original Research Article
Pages 479-484
Sang-Chul Moon, Hiromi Yamashita, Masakazu Anpo

4.18 Photocatalytic Oxidation of Ethanol over Tantalum Oxide Supported on Silica Original Research Article
Pages 485-490
Tsunehiro Tanaka, Sakae Takenaka, Takuzo Funabiki, Satohiro Yoshida

4.19 The Relationship between the Absolute Acidities of Monoatomic Cations and their Catalytic Activities in a Few Heterogeneous Systems Original Research Article
Pages 491-494
R. Notoya, A. Matsuda

4.20 The Role of Support in Methane Reforming with CO2 over Rhodium Catalysts Original Research Article
Pages 495-500
Junji Nakamura, Keita Aikawa, Koichi Sato, Toshio Uchijima

4.21 Laser Stimulated CO + H2 to Form C2H4 on the Surface of Nickel Sulfate Original Research Article
Pages 501-506
Wen Li, Shunhe Zhong

4.22 Characterization of Solid Superacidity by n-Alkane Isomerization Reactions at Low Temperature Original Research Article
Pages 507-518
Gao Zi, Chen Jian-min, Hua Wei-ming, Tang Yi

4.23 Sulfated Zirconia for n-Butane Isomerization Experimental and Theoretical Approaches Original Research Article
Pages 519-529
F. Babou, B. Bigot, G. Coudurier, P. Sautet, J.C. Védrine

4.24 Modification of Isomerization Activity and Selectivity over Sulfated Zirconia Catalysts Original Research Article
Pages 531-536
S.L. Soled, E. Iglesia, G.M. Kramer

4.25 Butene Dimerization over Sulfate and Tungstate Modified Solid Acids Original Research Article
Pages 537-541
S. Soled, N. Dispenziere, R. Saleh

4.26 Alkylation of Isobutane with Butenes over Silica-supported SO42--ZrO2 Original Research Article
Pages 543-548
Canxiong Guo, Zhongwei Yu, Zaihu Qian, Jiasheng Huang, Yide Xu

4.27 Acid Property and Metathesis Activity of WO3-ZrO2 Catalysts Original Research Article
Pages 549-554
Masataka Kudo, Yusuke Yoshinaga, Sadao Hasegawa

Key Words Index
Pages 555-557