12th International Congress on Catalysis

Front Cover......Page 1
12th INTERNATIONAL CONGRESS ON CATALYSIS......Page 4
Copyright Page......Page 5
TABLE OF CONTENTS......Page 10
PL-1. In Situ Characterization of Catalysts......Page 66
PL-2. Pollution Abatement through Heterogeneous Catalysis for Preserving Clean Air......Page 88
PL-3. Molecular Design of Heterogeneous Catalysts......Page 114
PL-4. Millisecond Chemical Reactions and Reactors......Page 126
PL-5. Catalysis for Oil Refining and Petrochemistry, Recent Developments and Future Trends......Page 148
New Catalysis from Metal Oxide Surface Science......Page 170
KN-1 From Unit Operations to Elementary Processes: A Molecular and multidisciplinary approach to catalyst preparation......Page 180
KN-2 Acidity in Zeolite Catalysis......Page 192
KN-3 Engineered Solid Catalysis for Synthesis of Fine Chemicals in Multiphasic Reactant System......Page 202
KN-4 New Solid Acid Based Breakthrough Technologies......Page 212
KN-5 Application of Titanium Oxide Photocatalysts and Unique Second-Generation TiO2 Photocatalysts able to Operate under Visible Light Irradiation for the Reduction of Environmental Toxins on a Global Scale......Page 222
KN-6 Catalysis for Fine Chemicals: an Industrial Perspective......Page 232
KN-7 Oxidative Methanol Reforming Reactions for the Production of Hydrogen......Page 242
KN-8 Supported Metallocenes: Monosite and Multisite Catalysts for Olefin Polimerization......Page 252
A01 A New Method for Preparing Nanometer-size Perovskitic Catalysts for CH4 Flameless Combustion......Page 262
A02 Experimental Investigation and Modelling of Platinum Adsorption onto Ion-modified Silica and Alumina......Page 268
A03 Nanocrystalline Thin Films as a Model System for Sulfated Zirconia......Page 274
A04 Nanoparticle Arrays as Model Catalysts: Microstructure, Thermal Stability and Reactivity of Pr/SiO2 Fabricated by Electron Beam Lithography......Page 280
A05 Epoxidation of Olefins on M-SiO2 (M=Ti, Fe, V) Catalysts with Highly Isolated Transition Metal Ions Prepared by Ion Beam Implantation......Page 286
A06 Cyclohexane Ring Opening on Metal-Oxide Catalysts......Page 292
A07 Olefins from Chlorocarbons: Reactions of 1,2-Dichloroethane Catalyzed by Pt-Cu......Page 298
A08 Artificial Control of Selectivity by Dynamic Lattice Displacement of Acoustic Wave Effects: Decomposition and Oxidation of Alcohol on Ag and Pd catalysts......Page 304
A09 The Effect of Hydrogen Concentration on Propyne Hydrogenation over a Carbon Supported Palladium Catalyst Studied under Continuous Flow Conditions......Page 310
A10 Suggestion of a New Alternative Mechanism of the Sulfuric Acid Catalyzed Isoparaffin-Olefin Alkylation......Page 316
A11 Hydroisomerization of n-Decane in the Presence of Sulfur and Nitrogen......Page 322
A12 State of Metals in the Supported Bimetallic Pt-Pd/SO42-/ZrO2 System......Page 328
A13 Dehydroisomerization of n-Butane over Pt Promoted Ga-Substituted Silico-aluminophosphates......Page 334
A14 Pore Mouth Catalysis over Acidic Zeolites. Nature of Active Species......Page 340
A15 Rediscovery of the Paring Reaction: The Conversion of l,2,4 Trimethyl- Benzene over HZSM5 at Elevated Temperature......Page 346
A16 SAPO-34 Catalyst for Dimethylether Production......Page 352
A17 Catalytic Performances of Pillared Beidellites Compared to Ultrastable Y Zeolites in Hydrocracking and Hydroisomerization Reactions......Page 358
A18 Effect of Ni on K-Doped Molybdenum-on-Carbon Catalysts: Temperature- Programmed Reduction and Reactivity to Higher-Alcohol Formation......Page 364
A19 Quantitative Determination of the Number of Active Surface Sites and the Turnover Frequencies for Methanol Oxidation over Metal Oxide Catalysts......Page 370
A20 Metal Particles on Oxide Surfaces: Structure and Adsorption Behaviour......Page 376
A21 An Atomic XAFS Study of the Metal-Support Interaction in Pt/SiO2-Al2O3 and Pt/MgO-Al2O3 Catalysts: An Increase in Ionization Potential of Platinum with Increasing Electronegativity of the Support Oxygen Ions......Page 382
A22 Transition State and Diffusion Controlled Selectivity in Skeletal Isomerization of Olefins......Page 388
A23 Development and Application of 3-Dimensional Transmission Electron Microscopy (3D-TEM) for the Characterisation of Metal-Zeolite Catalyst Systems......Page 394
A24 Interrogative Kinetic Characterisation of Active Catalyst Sites Using TAP Pulse Experiment......Page 400
A25 UV Resonance Raman Spectroscopic Identification of Transition Metal Ions Incorporated in the Framework of Molecular Sieves......Page 406
A26 Surface Mobility of Oxygen Species on Mixed-Oxides Supported Metals......Page 412
A27 SO2-Promoted Propane Oxidation over Pt/Al2O3 Catalysts......Page 418
A28 Selective Oxidation of Toluene to Benzaldehyde: Investigation of Structure- Reactivity Relationships by in situ-Methods......Page 424
A29 Observation of Unstable Reaction Intermediate by Picosecond Tunable Infrared Laser Pulses......Page 430
A30 Changes in Morphology of γ-Al2O3-Supported Pt Clusters under Reaction Conditions: Evidence from In-Situ EXAFS Spectroscopy......Page 436
A31 In Situ FT-IR Investigation of Hydrocarbon Reactions over Zeolite Based Bifunctional Catalysts......Page 442
B01 A Steady State Isotopic Transient Kinetic Analysis of the Fischer-Tropsch Synthesis Reaction over a Cobalt-Based Catalyst......Page 448
B02 Use of Membranes in Fischer-Tropsch Reactors......Page 454
B03 Egg-Shell Catalyst for the Synthesis of Middle Distillates......Page 460
B04 Computer Aided Design of Novel Heterogeneous Catalysts – A Combinatorial Computational Chemistry Approach......Page 466
B05 Applications of Density Functional Theory to Identify Reaction Pathways for Processes Occuring in Zeolites and on Dispersed Metal Oxides......Page 472
B06 Electrocatalytic Synthesis of Ammonia at Atmospheric Pressure......Page 478
B07 Electrocatalysis at a Pt Electrode Surface in a Fuel Cell as Observed In Situ from Pt-H and Pt-O Shape Resonances and EXAFS Scattering in Pt L2,3 XANES......Page 484
B08 In situ Catalytic and Electrocatalytic Studies of Internal Reforming in Solid Oxide Fuel Cells Running on Natural Gas......Page 490
B09 Effect of Gd2O3 Doping and Steam/Carbon Ratio on the Activity of Catalyst for Internal Steam Reforming in Molten Carbonate Fuel Cell......Page 496
B10 A Microstructured Catalytic Reactor/Heat Exchanger for the Controlled Catalytic Reaction between H2 and O2......Page 502
B11 Catalytic Water Denitrification in Membrane Reactor......Page 508
B12 Reactivity and Thermal Profile of Metahne Partial Oxidation ar Very Short Residence Time......Page 514
B13 Supercritical Synthesis of Dimethyl Carbonate from CO2 and Methanol......Page 526
B14 A New Catalyst for an Old Process Driven by Environmental Issues......Page 520
B15 Mechanism of HDN over Mo and Nb-Mo Carbide Catalysts......Page 532
B16 In Situ Characterisation of Transition Metal Sulfide Catalysts by IR Probe Molecules Adsorption and Model Reactions......Page 544
B17 Comprehension of the Promoting Effect in the MCr2S4 Mixed Sulfide Catalysts......Page 538
B18 Potassium at Catalytic Surfaces – Stability, Electronic Promotion and Excitation......Page 550
B19 Heterogeneous Catalysis of Aldolisations on Activated Hydrotalcites......Page 556
B20 The Influence of Metal-Support Interactions During Liquid-Phase Hydrogenation of an α,β-Unsaturated Aldehyde over Pt......Page 562
B21 Tailoring of Acido-basic Properties and Metallic Function in Catalysts Obtained from LDHs for the Hydrogenation of Nitriles and of α,β-Unsaturated Aldehydes......Page 568
B22 Chemical versus Enzymatic Catalysis for the Regioselective Synthesis of Sucrose Esters of Fatty Acids......Page 574
B23 The Higly Selective Conversion of Toluene into 4-Nitrotoluene and 2,4- Dinitrotoluene Using Zeolite H-Beta......Page 580
B24 Catalytic Asymmetric Heterogeneous Aziridination and Epoxidation of Alkenes using Modified Microporous and Mesoporous Materials......Page 586
B25 Catalytic Hydrogenation of Nitriles to prim., sec. and tert. Amines over Supported Mono- and Bimetallic Catalysts......Page 592
B26 Alkali Promoted Regio-Selective Hydrogenation of Styrene Oxide to β- Phenethyl Alcohol......Page 598
B27 Production of Fatty Alcohols by Heterogeneous Catalysis at Supercritical Single-Phase Conditions......Page 604
B28 Regioselective Oxidation of Primary Hydroxyl Groups of Sugar and its Derivatives Using a New Catalytic System Mediated by TEMPO......Page 610
B29 Aspects of Regioselective Control in the Hydroformylation of Methyl Methacrylate with the in situ Formed (o-Thiomethylphenyl) diphenyl- phosphine Rhodium Complex......Page 616
B30 Highly Efficient Synthesis of N,N-Dialkylformamides from Carbon Dioxide and Dialkylamines over Ruthenium-Silica Hybrid Gels......Page 622
B31 Metal Complex Catalyzed Functionalization of Naturally Occurring Monoterpenes: Oxidation, Hydroformylation, Alkoxicarbonylation......Page 628
C01 Adsocat: Adsorption/Catalytic Combustion for VOC and Odour Control......Page 634
C02 Structure Sensitivity of the Hydrocarbon Combustion Reaction over Alumina-Supported Platinum Catalysts......Page 640
C03 Ceria-Zirconia-Supported Platinum Catalyst for Hydrocarbons Combustion: Low-Temperature Activity, Deactivation and Regeneration......Page 646
C04 Characterisation of a γ-MnO2 Catalyst Used in VOC Abatement......Page 652
C05 New Aluminai/Aluminium Monoliths for the Catalytic Elimination of VOCs......Page 658
C06 Hydrotalcite-Derived Catalysts for Removal of Nitrogen-Containing Volatil Organic Compounds......Page 664
C07 Surface Catalytic Reactions Assisted by Gas Phase Molecules on Supported Co-ensemble Catalysts......Page 670
C08 Fresh and Used V2O5- WO3/TiO2 SCR EUROCAT Standard Catalyst: An European Collaborative Characterization......Page 676
C09 Lean NOx Reduction over Sn1-xZrxO2 Solid Solutions......Page 682
C10 Concentration Programmed Adsorption-Desorption / Surface Reaction Study of the SCR-DeNOx Reaction......Page 688
C11 Bifunctional Nature of SnO2/γ-Al2O3 Catalysts in the Selective Reduction of NOx......Page 694
C12 SO2 Resistant Fe/ZSM-5 Catalyst for the Conversion of Nitrogen Oxides......Page 700
C13 Mechanistic Studies of the NOx Reduction by Hydrocarbons in Oxidative Atmosphere......Page 706
C14 NO Reduction in Presence of Methane and Ethanol on Pd-Mo/Al2O3 Catalysts......Page 712
C15 Fe-Vanadyl Phosphates/TiO2 as SCR Catalysts......Page 718
C16 Photoinduced Non-Oxidative Methane Coupling over Silica-Alumina......Page 724
C17 Photocatalytic Oxidation of Gaseous Toluene on Polycrystalline TiO2: FT-IR Investigation of Surface Reactivity of Different Types of Catalysts......Page 730
C18 Investigation of Environmental Photocatalysis by Solid-State NMR Spectroscopy......Page 736
C19 A Study of CH4 Reforming by CO2 and H2O on Ceria-Supported Pd......Page 742
C20 Catalytic Behaviour on Ni Containing Catalysts in Vaporeforming of Methane with Low H2O/CH4 Ratio and Free Carbon Deposition......Page 748
C21 Carbon Deposition and Reaction Steps in CO2/CH4 Reforming over Ni-La2O3/5A Catalyst......Page 754
C22 The Autothermal Partial Oxidation Kinetics of Methanol to Produce Hydrogen......Page 760
C23 New Reaction Mechanism for Methane Formation in CO Hydrogenation over Pd/CeO2......Page 766
C24 Methane Coupling over SrCoO3-Based Perovskites in the Absence of Gas-Phase Oxygen......Page 772
C25 Novel Conception of the Methanol Synthesis Mechanism on Conventional Cu-Containing Catalysts......Page 778
C26 “Real ” and “Inverse ’’ Model Catalysts for Studies of Metal-Support Interactions: CO Hydrogenation on Titania and Vanadia Supported Rh......Page 784
C27 Agglomeration of Pt Particles and Potential Commercial Application for Selective Hydrodechlorination of CCl4......Page 790
C28 Catalytic Diesel Soot Elimination on Co-K/La2O3 Catalysts: Reaction Mechanism and the Effect of NO Addition......Page 796
C29 Environmentally Benign Carbonylation of Nitrobenzene and Aniline......Page 802
C30 Nitrous Oxide – Waste to Value......Page 808
C31 Catalytic Wet Peroxide Oxidation over Mixed (Al-Fe) Pillared Clays......Page 814
D01 A new Iron Phosphate Crystalline Phase and its Catalytic Activity in Oxidative Dehydrogenation of Lactic Acid and Glycolic Acid......Page 820
D02 Dynamic of the Oxidative Dehydrogenation of Propane over VMgO Catalysts Studied by In Situ Electrical Conductivity and Step Transients......Page 826
D03 Effect of Potassium on the Structure and Reactivity of Vanadium Species in VOx/Al2O3 Catalysts......Page 832
D04 Strategies for Combining Light Paraffin Dehydrogenation (DH) with Selective Hydrogen Combustion (SHC)......Page 838
D05 Oxidative Dehydrogenation over Promoted Chromia Catalysts at Short Contact Times......Page 844
D06 Propane Oxidative Dehydrogenation by Continuous and Periodic Operating Flow Reactor with a Nickel Molybdate Catalyst......Page 850
D07 A Novel Catalyst of Copper Hydroxyphosphate (Cu2(OH)PO4) with High Activity in Hydroxylation of Phenol by Hydrogen Peroxide......Page 856
D08 Oxidation of Alkanes with Hydrogen Peroxide Catalyzed by di-Iron- Substituted Inorganic Synzyme......Page 862
D09 Vanadyl-Aluminum Binary Phosphate: Effect of Thermal Treatment over its Structure and Catalytic Properties in Selective Oxidation of Aromatic Hydrocarbons......Page 868
D10 Direct Synthesis of Phenol from Benzene with O2 over VMo-Oxide/SiO2 Catalyst......Page 874
D11 Eu-Ti-Pt-Catalytic System for Direct Hydroxylation of Benzene by O2 and H2 under Mild Conditions......Page 880
D12 High Yield Butane to Maleic Anhydride Direct Oxidation on New Supported Catalysts......Page 886
D13 Propylene Epoxidation over Gold-Titania Catalysts......Page 892
D14 Vapor-Phase Epoxidation of Propene using H2 and O2 over Au/Ti- MCM-41 and Au/Ti-MCM-48......Page 898
D15 Ring-Opening Reactions of Ethyl- and Vinyloxirane on HZSM-5 and Cu-ZSM-5 Catalysts......Page 904
D16 Controlling the Distribution of Framework Aluminum in High-Silica Zeolites......Page 910
D17 Toluene Disproportionation Catalysis Using EUO Type Zeolites: Initial Optimisation and Development......Page 916
D18 Influence of the Aluminium Content on the Acidity and Catalytic Activity of MTW-Type Zeolites......Page 922
D19 Synthesis of Ethylbenzene from 1,3-Butadiene Using Basic Zeolite Catalysts......Page 928
D20 Activity/Selectivity and Ligation of the Co Ions in Zeolites in Ammoxidation of Ethane to Acetonitrile......Page 934
D21 Room-Temperature Oxidation of Hydrocarbons over FeZSM-5 Zeolite......Page 940
D22 Selective Oxidation of Hydrocarbons by Active Oxygen Formed from N2O on ZSM-5 at Moderate Temperatures......Page 946
D23 Redox Molecular Sieve Catalysts for the Aerobic Selective Oxidation of Hydrocarbons......Page 952
D24 Catalytic Behaviour of H-Y Type Zeolites in the Decomposition of Chlorinated VOCs......Page 958
D25 Coupling Alkane Dehydrogenation with Hydrogenation Reactions on Cation-Exchanged Zeolites......Page 964
D26 Water Vapor Tolerance of Pd/HZSM-5 in the NO-Methane-O2 Reaction: Its Relation with Very Strong Solid Acidity of Zeolite Support......Page 970
D27 Simultaneous NO and N2O Decomposition on Cu-ZSM5......Page 976
D28 Catalytic Properties of Silica-Supported Tantalum and Tungsten Hydrides in the Cleavage and Formation of C-C Bonds of Alkanes......Page 982
D29 Characteristics of Ethylene Polymerization Catalyzed over Ziegler-Natta / Metallocene Hybrid Catalysts: Comparison between Silica-Based and Magnesium-Based Supports......Page 988
D30 Ethylene Polymerization with Zirconocene-MAO Supported on Molecular Sieves......Page 994
D31 In Situ and Ex Situ Study of Propylene Polymerization with a MgCl2- Supported Ziegler-Natta Catalyst......Page 1000
Front Cover......Page 1006
12th International Congress on Catalysis......Page 1009
Copyright Page......Page 1010
Table of Contents......Page 1028
P001. Nanoheterogeneous Metal-Polymer Composites as the New Type of Effective Selective Catalysts......Page 1071
P002. Design of Heteropolyacid-Polymer Composite Films as Catalytic Materials for Heterogeneous Reactions......Page 1077
P003. Catalyts Based on Heteropolyacids Supported on Zirconia......Page 1083
P004. Dependence of structure and physico-chemical properties of the catalysts containing heteropolyacids on the conjugated polymer matrix......Page 1089
P005. Mesoporous Silica Supported Solid Acid Catalysts......Page 1095
P006. Study of Acidic and Catalytic Properties of Sulfated Zirconia Prepared by Sol-Gel Process: Influence of Preparation Conditions......Page 1101
P007. Synthesis and Characterization of Ta-Pillared Ilerite......Page 1107
P008. Al-Pillared Hectorite and Montmorillonite Prepared from Concentrated Suspensions: Structural, Textural and Catalyic Properties......Page 1113
P009. Synthesis of High Surface Area Transition Metal Carbide Catalysts......Page 1119
P010. Use of Carbon Fabrics as Support for Hydrogenation Catalysts Usable in Polyphasic Reactors......Page 1125
P011. Preparation, Characterization and Reactivity of Activated Carbon Supported Platinum Catalysts by Fluidized Bed Organometallic Chemical Vapor Deposition (FBMOCVD)......Page 1131
P012. Metal-Carbon Aerogels as Catalysts and Catalyst Supports......Page 1137
P013. Preparation and Characterisation of Carbon Supported Pt-CeO2 Catalysts......Page 1143
P014. Highly Dispersed Pd Based Catalysts for Selective Hydrogenation Reactions......Page 1149
P015. Preparation of New Type of Supported Sn-Pt Bimetallic Catalysts Containig Lewis Acid Sites Anchored to the Platinun......Page 1155
P016. Influence of Small Amounts of Rhodium on the Structure and the Reducibility of Cu/Al2O3 and Cu/CeO2-Al2O3 Catalysts......Page 1161
P017. Synthesis, Characterization and Catalytic Properties of Chromium Silicate Xerogel......Page 1167
P018. Thermal Chemistry of Oxide-Supported Platinum Catalysts: A Comparative Study......Page 1173
P019. Geochemistry and Catalysts Preparation: Alumina as a Chemical Reactant in the Synthesis of MoOx/Al2O3 and WOx/Al2O3 Systems......Page 1179
P020. Chemistry of the Preparation of Silica-Supported Cobalt Catalysts from Co(II) and Co(III) Complexes: Grafting versus Phyllosilicate Formation......Page 1185
P021. New Method of the Preparation of Heterogeneous Ni(0) Complexes for Ethylene Oligomerization......Page 1191
P022. Synthesis, Characterization and Catalytic Activity of [Cu(NH3)4]2+ Supported on Hydrous Oxides......Page 1197
P023. Preparation and Characterization of Cu/ZnO and Pd/ZnO Catalysts for Partial Oxidation of Methanol. Control of Catalyst Surface Area and Particle Size Using Microemulsion Technique......Page 1203
P024. Mechanism of Silation of Alumina and Silica with Hexamethyldisilazane......Page 1209
P025. Solvent Influence in Silica-Alumina Sol-Gel Synthesis......Page 1215
P026. Ru, Co and RuCo/SiOz Catalyst Prepared by Sol-Gel Methods......Page 1221
P027. Structure and Catalytic Properties of Co-Re Bimetallic Catalysts Prepared by SOL/GEL Method and by Ion Exchange in NaY Zeolite......Page 1227
P028. On the Effect of the Preparation Conditions on the Localization and the Size of Platinum Particles on Zeolite NaX......Page 1233
P029. Hollow Metallic Particles Obtained by Oxidation/Reduction Treatment of Organometallic Precursors......Page 1239
P030. Synthesis, Characterization and Catalytic Application of Inorganic Nanotubes......Page 1245
P031. Nanostructuring Surfaces by Lithography: The Production and use of Model Catalysts......Page 1251
P032. New Catalyst Supports and Catalytic Systems on the Basis of Metallic Gauzes Coated with II-IV Group Element Oxides......Page 1257
P033. Precipitated Iron Fischer-Tropsch Catalysts: The Effect of Sulfide Ions......Page 1263
P034. The Nature of the Active Phase in Iron Fischer-Tropsch Catalysts......Page 1269
P035. Selective Inhibition: The Intrinsic Feature of Fisher-Tropsch Synthesis: Transient Initial Episodes in FT Synthesis on Cobalt Catalysts......Page 1275
P036. Effects of Support on Methane Selectivity in Cobalt-Catalyzed Fischer-Tropsch Synthesis: A Kinetic Model......Page 1281
P037. Does Mono-Atomic Ru Catalyse the Fischer-Trosph Synthesis?......Page 1287
P038. Fischer-Tropsch Synthesis Using Monolithic Catalysts......Page 1293
P039. The Design of catalysts Surfaces by the Use of Stochastic Optimisation Algorithms......Page 1299
P040. Modeling of Structure and Properties of Active Centers of Catalysts on the Base of Metalorganosiloxanes......Page 1305
P041. Theoretical Study on Active sites of Molybdena-Alumina Catalyst for Olefin Metathesis......Page 1311
P042. Modeling the Oxygen Activation on Dinuclear Iron MMO Mimics, a Quantum Mechanic Study......Page 1317
P043. Quantum-Chemical and Experimental Study of an Interaction between CO2 and Propylene over Rh-Co/Al2-O3 Catalysts......Page 1323
P044. Ab-Initio Study of the Vacancy Formation in Keggin and Linqvist Heteropolyanion......Page 1329
P045. Theoretical Studies of the Interaction of Butane and Butene Isomers in H-Ferrierite and H-Mordenite......Page 1335
P046. Theoretical Investigation of the Intrinsic Reaction Path (IRC) of the Methylation of mono-Substituted Aromatic Molecules over Faujasite Catalysts......Page 1341
P047. Catalysts or Combustion of Halogenated Volatile Organis Compounds......Page 1347
P048. Non-Stoichiometry and Catalytic Activity in ABO3 Perovskites: LaMnO3 and LaFeO3......Page 1353
P049. Deep Catalytic Oxidation of Chlorinated VOC Mixtures from Groundwater Stripping Emissions......Page 1359
P050. Transformation of Chlorinated Compounds on Different Zeolites under Oxidative and Reductive Conditions......Page 1365
P051. Biofiltration of Gasoline VOCs with Diferent Support Media......Page 1371
P052. An Unified View on Nitrogen Oxide Abatement......Page 1377
P053. Measuring the Adsorption of Reactive Probes as a Tool for Understanding the Catalytic Properties of De-NOx Catalysts......Page 1383
P054. Reactivity of the NOx Sugace Species Formed Afrer Co-adsorption of NO + O2 on a WO3/ZrO2 Catalyst: An FTIR Spectroscopic Study......Page 1389
P055. The Mechanism of the Selective NOx Adsorption on 12-Tungstophoshoric Acid hexa-Hydrate (HPW)......Page 1395
P056. Activity and DRIFT Spectroscopy Studies of NO Oxidation, and Reduction by C3H6 in Excess O2 over Al2O3 and Au/Al2O3......Page 1401
P057. Transient Study of NO, N2O, C3H6 and C3H8 Interactions over a Silica-Supported Pt Catalyst......Page 1407
P058. Electrochemical Promotion of NO Reduction by C3H6 on Rh/YSZ Catalyst-Electrodes and Investigation of the Origin of the Promoting Action Using TPD and WF Measurements......Page 1413
P059. The Reaction of Propane with Mixtures of NO, N2O and O2 Over Platinum, Palladium and Rhodium Catalysts......Page 1419
P060. Kinetics of NO Reduction by CO on Rh(111): A Molecular Beam Study......Page 1425
P061. The Surface Migration of NOx Adspecies as a Factor Determininig the Reactivity of Supported Pt Catalysts for the Treatment of Lean Burn Engine Emissions......Page 1431
P062. Pd/SnO2 as deN0x Catalysts: Preparation, Characterization and Activity......Page 1437
P063. Decomposition of NO Over Copper-Manganese Oxide Catalysts at Room Temperature......Page 1443
P064. Catalytic Performance of SrTiO3-Based Catalysts for NO Direct Decomposition......Page 1449
P065. CO and NO Elimination over Pd-Cu Catalysts......Page 1455
P066. NOx Storage and Reduction over Pt/Ba/Al2O3......Page 1461
P067. Nitrogen Emission Process in the Decomposition of Nitrogen Oxides on Pd(110): An Angular and Velocity Distribution Study......Page 1467
P068. Reduction of NO by Propylene over ModiJied Rh/TiO2 Catalysts in the Presence of Oxygen......Page 1473
P069. Effect of sulfur on the oxygen storage/release capacity of Rh/CeO2 and Rh/CeO2-ZrO2 model TWCs......Page 1479
P070. Thermal Stability and Oxygen Storage Capacity of Noble Metal/Ceria- Zirconia Catalysts for the Automotive Converters with the On-Board Diagnostics (OBD)......Page 1485
P071. N2O Formation over CeO2-ZrO2 Mixed Oxides Supported Metal (Pt, Pd, Rh), Catalysts for Automotive Exhaust Control......Page 1491
P072. Model Studies of Automobile Exhaust Catalysis Using Single Crystals of Rhodium and Ceria/Zirconia......Page 1497
P073. Thermally Stable, High-Surface-Area, PrOy-CeO2-Based Mixed Oxides for Use in Automotive-Exhaust Catalysts......Page 1503
P074. Improvement of Three Way Catalytic Perfomance by Optimizing Ceria and Promoters in Pd only Catalyst Prepared bu Sol-Gel Method......Page 1509
P075. Flue Gas NOx Removal by SCR with NH3 on CuO/AC at Low Temperatures......Page 1515
P076. Low temperature Monolithic SCR Catalysts for Tail Gas Treatment in Nitric Acid Plants......Page 1521
P077. Effect of La2O3 Concentration in La2O3-Al2O3 Supports and Pd/La2O3-Al2O3 Catalysts in Reduction of NO by H2......Page 1527
P078. Molecular Basis for the Design of Transition-Metal Oxide Catalysts for Selective Catalytic Reduction of NO by Hydrocarbons......Page 1533
P079. Silver as Promoter for the Catalytic Decomposition of NOx under Oxygen-Excess Condition: Evidence for Oxygen Spillover from Noble Metals to Silver......Page 1539
P080. Reactivity of Surface Species in the Reduction of NOx by Ethanol on Ag/Al2O3 Catalyst......Page 1545
P081. Modelling of Uncatalysed and Barium Catalysed NO Reduction by Activated Carbon......Page 1551
P082. Selective Catalytic Reduction of NOx with C3H6 under Lean-Burn Conditions on Activated Carbon-Supported Metals......Page 1557
P083. Role of Acidic Sites in the de-NOx Process on Supported Tin Oxides......Page 1563
P084. Sulphated-ZrO2 Prepared by Impregnation with Ammonium, Sodium or Copper Sulphate: Catalytic Activity for NO Abatement with Propene in the Presence of Oxygen......Page 1569
P085. Co. Based ex-THlc for the Decomposition of N2O: Tailoring Catalysts for Active and Stable Operation......Page 1575
P086. Cold Start Vehicle Emission Control Using Trapping and Catalyst Technology......Page 1581
P087. Oscillation of the NOx Concentration in its Selective Catalytic Reduction on Platinum Containing Zeolite Catalysts......Page 1587
P088. Experimental and Theoretical Description of Transition Metal Ion Structures in Zeolites Relevant to deNOx Catalysis......Page 1593
P089. Cooperation of Pt and Pd over H-Mordenite for the Lean SCR of NOx by Methane......Page 1599
P090. The Selective Catalytic Reduction of N2O by NH3 on a Fe-BEA Catalysts......Page 1605
P091. A New Mechanism for the Selective Catalytic Reduction of NOx by NH3 on Cu-zeolite Catalysts......Page 1611
P092. In Situ FT-IR Study of the Selective Catalytic Reduction of NO by Propane on Cu-ZSM-5: Evidence of a Reaction Pathway by Oxygen Pulses......Page 1617
P093. Catalytic Removal of NO: the Effect of Cu Loading and Type of Binder on Catalytic Properties of Cu/ZSM-5 Catalyst......Page 1623
P094. Changes in Cation Coordination during Deactivation of Cu-ZSM-5 deNOx Catalysts......Page 1629
P095. On the Role of oxygen in the Selective Reaction of NO Reduction with Methane over Co/ZSM-5 Catalyst......Page 1635
P096. Effect of Si/Al Ratio of Mordenite and ZSM-5 Type Zeolite Catalysts on Hydrothermal Stability for NO Reduction by Hydrocarbons......Page 1641
P097. Precipitation of MnO2 onto the External Surface of Zeolite Microcrystals. Structure of the Manganese Oxide and its Role in the Removal of NOx by NH3......Page 1647
P098. Catalytic Properties of Mesoporous Molecular Sieves for the Reduction of NOx......Page 1653
P099. Catalytic Activity of High Surface Area Mesoporous Mn-Based Mixed Oxides for the Deep Oxidation of Methane and Lean-NOx Reduction......Page 1659
P100. Characterization of the Role of Pt on CoPt and InPt Ferrierite Activity and Stability upon the SCR of NO with CH4......Page 1665
P101. Cu-Cr Oxide Catalysts for Complete Oxidation of Aromatic Hydrocarbons......Page 1671
P102. Ag/La0.6 Sr0.4 MnO3/γ-Al2O3 Catalyst for Complete Oxidation of Methanol at Low Concentration......Page 1677
P103. Treatment of Aqueous Solutions of Organic Pollutants by Heterogeneous Catalytic Wet Air Oxidation (CWAO)......Page 1683
P104. Effect of the Support for Pt Catalysts on Soot Oxidation......Page 1689
P105. Dimethyl Carbonate Synthesis From Carbon Dioxide and Methanol over Ni-Cu/MoSiO (VSiO) Catalysts......Page 1695
P106. Promotion of Support in Synthesis of Propylene Carbonate fiom CO2 and Propylene Oxide......Page 1701
P107. A Novel Process for the Removal of Nitrates fiom Drinking Water......Page 1707
P108. Greenhouse Gases and Emissions Control by New Catalysts Free of Precious Metals......Page 1713
P109. Study on the Initial Steps of the Polyethylene Cracking over Different acid Catalysts......Page 1719
P110. Catalytic Conversion of Traces in Biomass Gasification Fuel Gases with Nickel Activated Ceramic Filters......Page 1725
P111. An Environmental Friendly Catalyst for the High Temperature Shift Reaction......Page 1731
P112. Direct Catalytic Conversion of Chloromethane to Higher Hydrocarbons over Various Protonic and Cationic Zeolite Catalysts as Studied by In-Situ FTIR and Catalytic Testing......Page 1737
P113. Catalytic Conversion of 2-Chloropropane in Oxidizing Conditions: A FT-IR and Flow Reaction Study......Page 1743
P114. Catalyst Degradation of Polychlorinated Biphenyls at Low Temperature......Page 1749
P115. Microwave Effects in Exhaust Catalysis......Page 1755
P116. A New Way to Ti-containing Zeolite Beta Catalysts for Selective Oxidation......Page 1761
P117. Synthesis of Organically Modified Titania Silica Aerogels: Application for Epoxidation of Cyclohexenol......Page 1767
P118. Characterization and Catalytic Properties of Titanium Pillared Clays in the Epoxidation of Allylic Alcohols......Page 1773
P119. Epoxidation of Allylic Alcohol by Vanadium-Montmorillonite Catalyst......Page 1779
P120. Activity and Stability of Thermally Stable Polyimide Supported Mo(VI) Complexes for Epoxidation of Olefins......Page 1785
P121. Epoxidation of Soybean Oil Catalysed by CH3ReO3/H2O2......Page 1791
P122. Epoxidation of Limonene with Layered Double Hydroxides as Catalysts......Page 1797
P123. Epoxidation of Electron-Deficient Alkenes Using Heterogeneous Basic Catalysts......Page 1803
P124. Hydroxylation of Benzene to Phenol with Nitrous Oxide on Fe-Silicalites......Page 1809
P125. Ammoxidation of Propane to Acrylonitrile over V-Sb-Al-Oxide Catalysts – Influence of Catalyst Preparation on Reaction Kinetics......Page 1815
P126. Ammoxidation of Propylene to Acrylonitrile Catalyzed by Multimetal Molybdate- and Iron Antimoniate-Based Active Compounds Dispersed in Oxidic Matrixes: The Effect of the Dispersing Oxide on the Catalytic Performance......Page 1821
P127. Mastering of Chemical State of Mo at the Surface of Oxide Catalysts in the Selective Oxidation of Hydrocarbons: Towards a Fine Optimization of Catalytic Performances......Page 1827
P128. Oligomerization of Higher Olefins and Oxidation in a Series of Isobutanol – Isobutyric Aldehyde – Isobutyric Acid in the Presence of Some Heteropoly Compounds......Page 1833
P129. Modifications of Vanadium Phosporous Oxides by Aluminium Phosphate for n-Butane Oxidation to Maleic Anhydride......Page 1839
P130. Selective Oxidation of n-Butane over Novel V-P-O/Silica-Composites Prepared Through Intercalation and Exfoliation of Layered Precursor......Page 1845
P131. Molecular Structure-Reactivity Relationships in n-Butane Oxidation over Bulk VPO and Supported Vanadia Catalysts: Lessons for Molecular Engineering of New Selective Catalysts for Alkane Oxidation......Page 1851
P132. The Nature of the Cobalt Salt Affects the Catalytic Properties of Promoted VPO......Page 1857
P133. Oxidation of Toluene to Benzaldehyde over VSb1-x,TixO4 Catayst. Kinetic Studies......Page 1863
P134. Interaction of Surface- and Bulk-Oxygen in Mo/V-Mixed Oxides during the Partial Oxidation of an Unsaturated Aldehyde – A Concentration-Programmed-Reduction Study......Page 1869
P135. Steady State and Transient Kinetic Experiments for Rational Catalyst Design: Differences of Acrolein and Methacrolein Oxidation on Mixed Oxide Catalysts......Page 1875
P136. The Effects of Particle Size on the Performance of Er2O3 and 30 mol% BaCI2/Er2O3 Catalysts in the Selective Oxidation of Ethane to Ethene......Page 1881
P137. Perovskite Type Chloro Oxide SrCoO3-δClσ: A Novel and Durable Catalyst for the Selective Oxidation of Ethane to Ethene......Page 1887
P138.Preparation and Activity of Copper, Nickel and Copper-Nickel-Al Mixed Oxides via Hydrotalcite-Like Precursors for the Oxidation of Phenol Aqueous Solutions......Page 1893
P139. Influence of Temperature and Catalyst Loading on the Aqueous-Phase Catalytic Oxidation of Phenol......Page 1899
P140. Glyoxal Synthesis by Vapour – Phase Ethylene Glycol Oxidation on a Silver and Copper Catalysts......Page 1905
P141. Production of Alkenes through Oxidative Cracking of n-Butane over OCM Catalysts......Page 1911
P142. Selective Oxidation of Monosaccharides using Pt and Pd-Containing Cctalysts......Page 1917
P143. Synthesis of New Neocarboxylic Acids via Rearragement and Oxidation of 1,3-Dioxanes......Page 1923
P144. Low Temperature Radical Oxidation of Butane over In-Situ Prepared Silica Species......Page 1929
P145. Mechanochemical Preparation of V-Ti-O Catalysts for o-Xylene Low Temperature Oxidation......Page 1935
P146. A Common Concept Accounting for Selectivity in Mild and Total Oxidation Reactions: The Optical Basicity of Catalysts......Page 1941
P147. Copper Species in CuCl2/γ-Al2O3 Catalyst for Ethylene Oxychlorination......Page 1947
P148. A Study of the Main Path and of Side-Reactions upon Ethylene Oxychlorination over CuCl2-Al2O3 Based Catalysts......Page 1953
P149. Oxidative Dehydrogenation of Ethane on Lithium Promoted Oxide Catalysis......Page 1959
P150. Oxidative Dehydrogenation of Ethane to Ethylene over NiO/Al2O3 Catalysts......Page 1965
P151. Oxidative Dehydrogenation of Ethane over Catalysts Prepared Via Heteropolycompounds......Page 1971
P152. The Importance of Nonstoichiometric Oxygen in NiO for the Catalytic Oxidative Dehydrogenation of Ethane......Page 1977
P153. Oxidative Dehydrogenation of Ethane on Vanadium-Phosphorus Oxide Catalysts......Page 1983
P154. High Throughput Synthesis and Screening of Nb and Ta Containing Mixed Metal Oxide Libraries for Ethane Oxidative Dehydrogenation......Page 1989
P155. Chromium-Impregnated Mesoporous Silica as Catalysts for the Oxidative Dehydrogenation of Propane......Page 1995
P156. Transient Kinetic Studies of the Propane Oxidehydrogenation on V2O5/TiO2......Page 2001
P157. Vanadium-Doped Titania-Pillared Montmorillonites as Catalysts for the Oxidative Dehydrogenation of Propane......Page 2007
P158. Oxidative Dehydrogenation of Propane over Alkali-Mo Catalysts Supported on Sol-Gel Silica-Titania Mixed Oxides......Page 2013
P159. Vanadium Oxide Supported on Gallium and Indium Oxides: Synthesis, Physicochemical and Catalytic Properties......Page 2019
P160. Oxidative Dehydrogenation of Cyclohexane over Heteropolymolybdates......Page 2025
P161. Transient Response Studies of Isobutane Oxidative Dehydrogenation over Molybdenum Catalysts......Page 2031
P162. Olefins Formation by Oxidative Dehydrogenation of Propane over Monoliths at Short Contact Times......Page 2037
P163. Experimental and Theoretical Investigation on the Roles of Heterogeneous and Homogeneous Phases in the Oxidative Dehydrogenation of Light Paraffins in Novel Short Contact Time Reactors......Page 2043
P164. Composite Nickel-Oxide Surfaces, Modified by Palladium......Page 2049
P165. Photocatalyst-Coated Acrylic Waveguides for Oxidation of Organic Compounds......Page 2055
P166. Preparation of Efficient Titanium Oxide Photocatalysts by an Ionizer Cluster Beam Method and Their Application for the Degradation of Propanol Diluted in Water......Page 2061
P167. Thermal Treatment of Titanium Alkoxides in Organic Media: Novel Synthesis Methods for Titanium (IV) Oxide Photocatalyst of Ultra-High Activity......Page 2067
P168. Photocataliytic Water Decomposition by Layered Perovskites......Page 2073
P169. Catalyst Preparation and Reactor Design for Gas-Phase Photocatalytic Oxidation of Trichloroethylene (TCE) Pollutant......Page 2079
P170. Formation of Ethylene Oxide by Photooxidation of Ethylene over Silica Modified with Copper......Page 2085
P171. Photocatalytic Oxidation of n-Butane at a Steady Rate over Rb-Modified Vanadium Oxide Supported on Silica......Page 2091
P172. Photocatalytic Oxidation of Toluene on Platinum/Titania Catalysts......Page 2097
P173. Photocatalytic Degradation of Toluene in Aqueous Suspensions of Polycrystalline TiO2 in the Presence of the Surfactant Tetradecyldimethylamino-Oxide......Page 2103
P174. Photooxidation of Benzene to Phenol by Ru Complex Occluded in Mesoporous FSM-16......Page 2109