Trends in Interfacial Electrochemistry

Front Matter....Pages i-viii
Components of the Electrode Potential. Concepts and Problems....Pages 1-24
Potentials of Zero Charge. What They Suggest About the Structure of the Interfacial Region....Pages 25-48
Temperature Effects of Interfacial Properties....Pages 49-70
Electrochemistry on Well-Defined Solid Metal Electrodes....Pages 71-81
Trends in Experimental Electrochemistry on sp and sd Metal Single Crystal Electrodes....Pages 83-102
Structure of the Double Layer and Rates of Ion Crossings at “Single” Immiscible Liquid/Liquid (L/L) Interfaces....Pages 103-185
Electrical Double Layers at Interfaces between Colloidal Materials and Ionic Solutions....Pages 187-204
Phase Transitions in Adsorbed Layers....Pages 205-253
Surface Science Model Studies of the Electrochemical Interface....Pages 255-280
Solvent Effects upon Electrochemical Kinetics: Influences of Interfacial Solvation and Solvent Relaxation Dynamics....Pages 281-299
UV-Visible Reflectance Spectroscopy in the Study of the Metal-Electrolyte Interface....Pages 301-330
Molecular Structure and Orientation in the Electrode/Electrolyte Solution Interface — In Situ IR Spectroscopy....Pages 331-358
Structure, Thermodynamics and Kinetics of Water at Interfaces....Pages 359-371
Models of the Electrical Double Layer....Pages 373-385
Monolayer Models of Metal-Water Interphases and their use in the Interpretation of Differential Capacity Curves and of Organic Adsorption....Pages 387-452
The Capacity of the Metal/Liquid Electrolyte Interphase: Contribution of the Metal....Pages 453-472
Recent Developments in the Theory of Electrified Interfaces....Pages 473-521
The Semiconductor-Electrolyte Interface....Pages 523-546
Back Matter....Pages 547-568