Transition Metal Carbyne Complexes

Front Matter....Pages i-xxii
Olefin Metathesis by Well-Characterized Re(VII) Alkylidene/Alkylidyne Complexes....Pages 1-22
Protonation Reactions of Alkylidyne (Carbaborane) Complexes of the Group 6 Metals....Pages 23-37
Cyclometalated Aryloxy(Chloro)Neopentylidene – Tungsten Complexes. Syntheses from Neopentylidyne Complexes and Catalytic Properties in Olefin Metathesis....Pages 39-50
Reaction of Some Alkylidyne Complexes of Tungsten with Inorganic Oxides: A General Route towards Active Supported W Based Metathesis Catalysts?....Pages 51-53
On the Route from Stoichiometric to Catalytic Reactions of Carbyne Complexes. Part XX (1)....Pages 55-66
Ylide Nickel Catalysis: Progress in Acetylene Polymerization....Pages 67-69
Conjugated Complexes and Polymers Derived from Metal-Alkylidyne Building Blocks....Pages 71-73
Methylidyne Complexes: Structures, Spectra, and Bonding....Pages 75-77
Novel Cyclizations Involving Cationic Carbyne Complexes....Pages 79-84
New Addition and Cycloaddition Reactions of the Cationic Carbyne Complexes [Cp(CO)(L)M≡CR] + (M = Mn, Re; L = CO, PPh 3 ; R = Me, Tolyl)....Pages 85-96
Alkynylcarbene Complexes of Transition Metals as Suitable Substrates for Stereoselective Cycloadditions....Pages 97-99
Reaction of Alkynols with Alkynylalkoxycarbene Metal (Cr,W) Complexes....Pages 101-103
Chemistry and Electrochemistry of Alkyne-and Isocyanide-Derived Carbyne Complexes of Rhenium, Molybdenum or Tungsten....Pages 105-121
Photooxidation of Molybdenum and Tungsten Carbynes....Pages 123-125
The Determination of the Chemical Bonds in Some Metal-Carbyne Complexes by Structural Studies....Pages 127-129
Planar Tetracoordinate Carbon -Experimental Determination of the Charge Density of Cp 2 Zr(μ-η 1 ,η 2 -Me 3 SiCCPh) (μ-CI)AIMe 2 (I) and Cp 2 Zr(μ-η 1 ,η 2 MeCCPh) (μ-CCPh)AIMe 2 (II)....Pages 131-135
Carbyne to Carbene Ligand Conversion in Dinuclear Complexes....Pages 137-147
Syntheses and Reactions of Heterodinuclear Alkoxycarbyne Complexes....Pages 149-150
Multicenter Ligand Transformations of Tetramethyl-Thiourea on Ruthenium Clusters....Pages 151-153
Carbyne Complexes of Ruthenium and Osmium....Pages 155-168
Towards the Synthesis of Carbine Complexes of Gold and Copper: New Carbene Complexes....Pages 169-173
Double and Triple Bonds to f-Elements: Structure and Chemistry of Actinide Complexes of Multielectron Pair Donor Ligands....Pages 175-188
Metal Carbenes and Metal Carbynes as Precursors for a Rational Synthesis of Carbido and Hydrocarbon Bridged Complexes....Pages 189-199
Some Chemistry of Tp’(CO) 2 W≡C-H, A Simple Terminal Carbyne....Pages 201-218
The Role of Nucleophiles and Electrophiles in Coupling Reactions of Alkylidyne Ligands....Pages 219-230
Dicarbonyl(η 5 -cyclopentadienyl)carbyne Complexes of Molybdenum and Tungsten as Building Blocks....Pages 231-238
Diversions En Route to Alkylidyne Complexes of Iron....Pages 239-248
Electron-Rich Tungsten Aminocarbyne Complexes with Cp* Ligands Synthesis and Protonation Reactions....Pages 249-254
Back Matter....Pages 255-268