The Rare Earths in Modern Science and Technology: Volume 3

Front Matter....Pages i-xxiii
Rare Earth Reminiscences....Pages 1-13
Magnetic Resonance Studies of Metal Cation Transport Across Biological Membranes: Use Of Paramagnetic Lanthanide Ions....Pages 15-20
Inter-Lanthanide Ion Energy Transfer Distance Measurements in Biological Systems....Pages 21-23
Gadolinium as an EPR and NMR Probe of Ca 2+ Sites in Biological Systems....Pages 25-30
Optical Activity of Mixed-Ligand Complexes of Tb(III) with Pyridine-2,6-Dicarboxylic Acid and Hydroxycarboxylic Acids....Pages 31-34
Terbium Luminescence as a Probe of Lanthanide Coordination in Solution....Pages 35-36
A 160 Tb(III) Probe of the Calcium Binding Sites of Muscle Calcium Binding Parvalbumin....Pages 37-44
The Lanthanides as Structural Probes in Peptides....Pages 45-51
Multinuclear NMR Study of Three Aqueous Lanthanide Shift Reagents: Complexes with EDTA and Two Macrocyclic Ligands....Pages 53-57
Structures of Dithiophosphinate Complexes of the Lanthanides in the Solid and Solution by X-Ray Diffraction and Paramagnetic NMR....Pages 59-60
Recent Advances in the Low Valent Approach to f-Element Organo-Metallic Chemistry....Pages 61-70
Laser Photochemistry of a Uranium Compound Tailored for 10µ Absorption: U(OCH 3 ) 6 ....Pages 71-76
New Stoichiometric and Catalytic Pentamethylcyclopentadienyl Organoactinide Chemistry....Pages 77-84
Choosing a Coordination Number for Ln(III): 1:1, 1:2, 2:1, 3:2 and 4:3 Complexes with Crown Ethers....Pages 85-86
A Systematic Study of the Complexation of Di- and Tri-Valent Lanthanide Ions by Macrocycles of Varying Size....Pages 87-90
Octahedral Compounds of Lanthanides: Trimethylphosphine Oxide (tmpo) as Ligand....Pages 91-93
Amine Complexes of Divalent Europium....Pages 95-96
High Coordination Polyhedra of Trivalent Rare Earth Ions....Pages 97-98
Erbium Chloride Complexation in Aqueous DMF....Pages 99-103
Lanthanide Hexafluoroantimonate Complexes of Hexamethylphosphoramide....Pages 105-108
Parametrisation of the MCD-Spectra of Rare Earths: Example of Pr 3>+ in PVA-Matrix....Pages 109-114
Ab-Initio Calculation of Lanthanide Crystal Field Parameters and Transition Probabilities....Pages 115-120
On the Origin of Resonance Lines in 3d Emission Spectra of Rare Earths....Pages 121-124
Transition Intensities for Nd 3+ in Crystals....Pages 125-126
Truncation Effects on Crystal Field Calculations for The 4f 6 (Eu 3+ ) Configuration in Solids....Pages 127-130
Study of M 4,5 -Level Soft X-Ray Appearance Potential Spectra of Selected Rare Earths....Pages 131-134
The Effect of Multiplet Splitting of the 4d Levels in Rare Earth Elements on Their X-Ray Spectra....Pages 135-138
Optical Spectra, Energy Levels, and Crystal-Field Analysis of Tripositive Rare Earth Ions in Y 2 O 3 : I. Kramers Ions in C 2 Sites....Pages 139-142
Sm 2+ Activated Mixed Fluorides: Synthesis and Fluorescence....Pages 143-146
Electric and Magnetic Dipole Strengths of f-f Transitions in Cubic Cs 2 NaYCl 6 :Ln 3+ Systems....Pages 147-152
Absorption Spectrophotometric Characterization of Sm(II), Sm(III), and Sm(II/III) Bromides and Sm(III) Oxybromide in the Solid State....Pages 153-158
Cascade Laser Action in Tm 3+ :YLF....Pages 159-160
Laser Induced Luminescence of Pr 3+ in CaF 2 Attributed to Different Local Site Symmetries....Pages 161-164
Photoconductivity Due to Autoionization of Divalent Rare Earth Impurities in Crystals Having the Fluorite Structure....Pages 165-169
The Effect of Structural Environment on the Absorption Spectra of Selected Lanthanide Sesquioxides....Pages 171-176
The Ce 3+ →Tb 3+ Transfer in Phosphate Host Lattices....Pages 177-178
Laser Excited Luminescence of Tb 3+ , Eu 3+ -Activated Ferroelectric Gadolinium Molybdate (GMO)....Pages 179-182
Luminescence of High-Pressure Phases of Eu 2+ Activated Alkaline Earth Borates and Silicates....Pages 183-186
PMR Spectroscopic Studies of Lanthanide Aminocarboxylate Complexes....Pages 187-191
The Interaction of 1:1 and 1:2 Lanthanide-Edta Chelates with Alkali Cations: Aqueous Relaxation Reagents for Metal Nuclide NMR....Pages 193-198
Luminescence of L-(-)-Tryptophan in DMSO at 77 K in the Presence of Tb 3+ ....Pages 199-202
Hypersensitivity in the 4 f −4 f Absorption Spectra of Er 3+ and Ho 3+ Complexes....Pages 203-206
Possible Symmetries of the Coordination Sphere of Eu 3+ in DMSO via a Correlation of Magnetic Circular Dichroism (MCD) with Absorption and Emission Spectra....Pages 207-211
Diphenyl-Phosphinyl-Morpholide (DPPM) Lanthanide Salt Adducts: Nd 3+ and Eu 3+ Spectra....Pages 213-216
Adducts of Lanthanide Trifluoromethanesulfonates and Tetramethylene Sulfoxide (TMSO)....Pages 217-221
Photoreduction of Ytterbium and Samarium....Pages 223-226
CeN: Phase Relationships and Enthalpies of Solution....Pages 227-236
Enthalpies of Solution and Lattice Constant Anomalies of Sm 3 S 4 - Sm 2 S 3 Solid Solutions....Pages 237-241
High Temperature Phase Diagram and Enthalpies of Solution of TmSe....Pages 243-248
Densities and Concentration of Defects in TmSe....Pages 249-254
Preparation and Thermoelectric Properties of Some Rare Earth Chalcogenides....Pages 255-256
Thermal Decomposition of Rare Earth Sulfate and Selenate Hydrates....Pages 257-263
Rare Earth Oxysulfide/Oxysulfate Equilibria At 1100–1500K....Pages 265-270
Phase Studies and Selective Oxidation in Rare Earth-Molybdenum-Oxide Systems, Ln 2 O 3 -MoO 2 -MoO 3 ....Pages 271-274
Correlation of Spectral and Heat-Capacity Schottky Contributions for Dy 2 O 3 , Er 2 O 3 , and Yb 2 O 3 ....Pages 275-278
Enthalpy of Formation of Barium Lanthanide(IV) Oxides: BaCeO 3 , BaPrO 3 , and BaTbO 3 ....Pages 279-282
On Mixed Crystals of Pr 1−y Tb y O x Grown Under High Oxygen Pressures....Pages 283-288
A Kinetic Study of the Oxidation of Zeta Phase Praseodymium Oxide: $$\frac{{10}}{9}{\Pr _9}{O_{16}} + \frac{1}{9}{O_2} \to {\Pr _{10}}{0_{18}}$$ ....Pages 289-290
Predicted Stabilities of Rare Earth Dihalides....Pages 291-292
Vaporization and Thermodynamic Properties of Samarium Dicarbide and Nonstoichiometric Disamarium Tricarbide....Pages 293-294
Complexity of Phase Equilibria in the MM-Co-Fe System Between 2:7 and 1:5 Stoichiometries....Pages 295-298
Low Temperature-High Magnetic Field Heat Capacity Studies of Weakly and Nearly Ferromagnetic and Mixed Valence Rare Earth Materials....Pages 299-300
Anomalous Behavior of Cerium and Europium Ions in Ternary Molybdenum Chalcogenides (Chevrel Phases)....Pages 301-313
New Fluorides with Ce IV , Pr IV , Nd IV , Tb IV , and Dy IV ....Pages 315-315
Ternary Halides of the Rare Earth Elements: Phases and Structures....Pages 317-321
Investigation of the “Diadochic” Incorporation of the Rare Earth Elements in CaF 2 at Elevated Temperature and Pressure....Pages 323-328
Crystal Structures of EumgF 4 , SmMgF 4 and SrMgF 4 ....Pages 329-334
Structural Phase Transitions in Cs 2 NaLnCl 6 ....Pages 335-338
Synthesis and Crystal Data for Alkaline Earth-Lanthanide Phosphates with the Eulytite Structure....Pages 339-340
The Crystal Structure and Stoichiometry of the Ca 2+x Nd 8-x (SiO 4 ) 6 O 2-1/2x System....Pages 341-344
Electron Beam-Induced Reduction of TbO 2−δ : A High Resolution Electron Microscope Study....Pages 345-346
Crystal Structure and Properties of (LaO) CuS and (LaO) AgS....Pages 347-350
The Crystal Chemistry of the Europium Arsenides....Pages 351-352
Crystal Structures and Phase Relationships within Ternary Systems: Rare Earth Metal-Noble Metal-Boron....Pages 353-356
Fast Diffusion and Electrotransport of Cobalt, Iron and Nickel in α-Yttrium....Pages 357-358
Ternary Compounds In RE(Au,Ga) 2 and RE(Ag,Ga) 2 Alloys....Pages 359-360
Magnetic Properties of ErM 3 , M = (Ni, Fe, Co)....Pages 361-365
Transport and Magnetic Properties of the Gd 4 (Co 1−x Ni x ) 3 Series (0≤×≤: 0.2)....Pages 367-371
Structures and Magnetism of Some Polycomponent 2:17 Rare Earth- Transition Metal Systems....Pages 373-376
Evidence for the Noncollinearity of the Magnetic Structure of Er 6 Mn 23 ....Pages 377-380
Mösbauer Investigation of the Effect of Annealing on the Ordering Temperature of Amorphous DyFe 2 ....Pages 381-384
Magnetization and 55 Mn Hyperfine Field in RMn 2 (R = Rare Earth) Intermetallic Compounds....Pages 385-389
Magnetic Properties of Cubic and Hexagonal HoMn 2 ....Pages 391-392
Susceptibility Densities in the Pauli Paramagnets YNi 5 and CeNi 5 ....Pages 393-397
Thermal Variation of Anisotropies of Cobalt in YCo 5 and NdCo 5 up to 450 K....Pages 399-402
The Magnetic Structure of Y(Mm 1−x Fe x ) 12 ....Pages 403-406
Magnetic Characteristics of the Intermetallic Compounds R 2 Ni 17−x Al x (R = Gd,Tb)....Pages 407-412
Observation of Spiral Spin Antiferromagnetic Domains in Single Crystal Terbium....Pages 413-417
Crystal Field and Quadrupolar Effects on the Third-Order Magnetic Susceptibility....Pages 419-422
Magnetic Properties of Some Single Crystal Rare Earth Tetraborides....Pages 423-426
Transferred Hyperfine Interactions and Quadrupole Effects for the Diamagnetic Ions in Rare-Earth Elpasolites, Cs 2 NaLnCl 6 ....Pages 427-430
Structure-Property Interplay in the System RTiO 3 : R = Lanthanide (III)....Pages 431-439
Some Magnetic Properties of the System La x Gd 1−x TiO 3 ....Pages 441-442
Zero Field Temperature Depencence of the Rare Earth Sublattice Magnetization in RTiO 3 ; R = Tb, Dy, Ho, Er and Tm....Pages 443-444
Magnetic and Structural Properties of CeSb 1−x Te x Mixed Compounds....Pages 445-449
Effects of the Non-Stoichiometry on the Transport Properties of CeSb....Pages 451-454
Low-Temperature Behavior of DyS, DySe, HoS and HoSe....Pages 455-458
Electrical Resistivity and Magnetic Field Effects of NdS 3−x V x S 4 ....Pages 459-463
Faraday Rotation of Rare Earth Alkali Germanate Glasses....Pages 465-469
Using NMR to Study the Properties of Rare-Earth Materials Containing Hydrogen....Pages 471-472
Magnetic and Structural Properties of Y 6 Mn 2 3 D 2 3 ....Pages 473-476
Magnetic and Structural Properties of Th 6 Mn 2 3 D x and Y 6 Mn 2 3 D x ....Pages 477-478
Valence Bonding, Atomic Volumes, and Coordination Numbers for Y 6 Mn 23 , Th 6 Mn 23 , and their Hydrides....Pages 479-480
Structure of Al, Cu and Si Substituted LaNi 5 and of the Corresponding β-Deuterides from Powder Neutron Diffraction. Localized Diffusion Mode of Hydrogen in LaNi 5 and Al and Mn Substituted Compounds from Quasielastic Neutron Scattering....Pages 481-486
Thermodynamic and Magnetic Properties of LaNi 5−x Fe x Compounds and Their Hydrides....Pages 487-488
Thermodynamic Properties of LaNi 4 M Compounds and Their Hydrides....Pages 489-492
Hydrogen Desorption Rates in LaNi 5−x Al x -H....Pages 493-498
Structure-Reactivity Studies on the Extraction of Lanthanides by Dialkyl Isopropylphosphonates....Pages 499-503
Separation of the Rare Earths and Some Polyvalent Cations on Inorganic Ion Exchangers....Pages 505-506
Solvent Extraction Behavior of Lanthanides with Di(2-Ethylhexyl) Isopropylphosphonate....Pages 507-511
Spectrophotometric Determination of Rare Earths in Ligand Buffer Masking Systems....Pages 513-516
Spectrophotometric Determination of Trace Amounts of Copper in High-Purity Rare Earth with α,ß,γ,δ-Tetra-(4-Trimethylammonium-Phenyl) Porphine....Pages 517-520
Rare Earth Ion Selective Electrodes: II. Europium and Praseodymium Compound Membranes....Pages 521-524
Analysis of Rare Earth Elements in Ore Concentrate Samples using Direct Current Plasma Spectrometry....Pages 525-529
Behavior of REE in Geological and Biological Systems....Pages 531-535
Trends in Rare Earth Metal Consumption for Steel Applications in the 1980’s....Pages 537-546
The Use of Rare Earths in Photovoltaics....Pages 547-556
Preparing Rare Earth Silicon Iron Alloys....Pages 557-560
Catalysis Using Rare Earth and Actinide Internetallics Containing Fe, Co, Ni and Cu....Pages 561-568
Electrochemical Corrosion of Lanthanum Chromite and Yttrium Chromite in Coal Slag....Pages 569-576
Back Matter....Pages 577-588