Structure and Reactivity of Surfaces

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Page iii

Copyright page
Page iv

Foreword
Page xiii

Acknowledgments
Page xiv

Photoluminescence, Photo-Induced Reactivities and Catalytic Properties of Na- and Li-Doped Mgo Original Research Article
Pages 1-10
M. Anpo, Y. Yamada, T. Doi, I. Matsuura, S. Coluccia, A. Zecchina, M. Che

The Characterisation of Supported Metal Catalysts by the Determination of Differential Heats of Adsorption Original Research Article
Pages 11-17
P.N. Aukett

Model Studies of the Smsi Phenomenon at the Tiox/Ru(0001) Interface Original Research Article
Pages 19-30
Jas Pal S. Badyal, Andrew J. Gellman, Robert W. Judd, Richard M. Lambert

Oxygen Reactivity as a Probe for the Surface Composition of Cao-Mno Solid Solutions Original Research Article
Pages 31-39
M. Bailes, B. Fubini, F.S. Stone

A First Approach to Gaseous Aminoacid-Oxide Interaction Original Research Article
Pages 41-48
Pietro Baraldi, Gianfranco Fabbri

Adsorption and Dissociation of Carbon Monoxide on Co(1120) Original Research Article
Pages 49-57
U. Bardi, G. Rovida

Low Pressure Oxidation of the Pt3Ti Alloy Studied by Electron Spectroscopy Original Research Article
Pages 59-68
U. Bardi, P.N. Ross, G. Rovida

Interaction of Atomic Hydrogen with the (111) and (100) Surfaces of Diamond-Like Crystals Original Research Article
Pages 69-73
Vincenzo Barone, Giancarlo Abbate, Nino Russo, Marirosa Toscano

A Transmission Ftir Study of the Adsorption of Carbon Monoxide and Cyclohexane on Evaporated Silver Films Original Research Article
Pages 75-83
J.E. Bateman, M.A. Chesters

Heat-Capacity Anomalies of Two-Dimensional Systems Studied by the Mcquistan-Hock Model Original Research Article
Pages 85-90
F. Battaglia, T.F. George, Y.S. Kim

Surface Chemistry of Carbonaceous Species Original Research Article
Pages 91-109
Alexis T. Bell

Polarization Conductivity of Amorphous Molybdenum Sulphides–Influence of the Oxidation Original Research Article
Pages 111-121
Y. Bensimon, J.C. Giuntini, P. Belougne, B. Deroide, J.V. Zanchetta

Metal-Support Interaction Phenomena in Some High Metal Loading Lanthana Supported Rhodium Catalysts Original Research Article
Pages 123-132
S. Bernal, F.J. Botana, R. Garcia, J.M. Rodriguez-Izquierdo

Spectroscopic Characterization of Silicalite and Titanium-Silicalite Original Research Article
Pages 133-144
M.R. Boccuti, K.M. Rao, A. Zecchina, G. Leofanti, G. Petrini

Surface Properties of Carbons Original Research Article
Pages 145-157
H.P. Boehm

A Comparison Between the Lewis Acidity of Non-D Metal Cations in Y-Zeolites and on Ionic Surfaces Original Research Article
Pages 159-166
V. Bolis, B. Fubini, E. Garrone, E. Giamello, C. Morterra

Promotion and Selective Poisoning of Supported Metal Catalysts Original Research Article
Pages 167-177
G.C. Bond, M.R. Gelsthorpe, R.R. Rajaram, R. Yahya

A Study of Supported Pt Catalysts by X-Ray Absorption Spectroscopy Original Research Article
Pages 179-189
M.J.P. Botman, A.J. den Hartog, V. Ponec

A Sims and Aes Study of Nickel Deposition on Tio2(100). Influence of the Stoichiometry of the Support Original Research Article
Pages 191-200
S. Bourgeois, D. Diakite, F. Jomard, M. Perdereau, R. Poirault

Structure and Bonding of Adsorbates: Investigations with Synchrotron Radiation Original Research Article
Pages 201-217
A.M. Bradshaw

Drifts and Raman Spectroscopic Study of Intrazeolite Metal Carbonyl Chemistry Original Research Article
Pages 219-228
C. Bremard, E. Denneulin, C. Depecker, P. Legrand

The Adsorption of Iodine at Gaas (100) Surfaces Via the Decomposition of Ch2I2 : A Model Study of Semiconductor Etching Original Research Article
Pages 229-237
D.S. Buhaenko, S.M. Francis, P.A. Goulding, M.E. Pemble

Effect of Cobalt on the Surface Properties of Zn-Cr and Cu-Zn-Cr Methanol Synthesis Catalysts Original Research Article
Pages 239-248
G. Busca, M.E. Pattuelli, F. Trifiro, A. Vaccari

A Study of the Adsorption of Acetylene on Cu(100) Using Auger Electron Spectroscopy Original Research Article
Pages 249-256
M.A. Chesters, D.R. Linder

Correlation of Transmission Ftir Spectra of Co Adsorbed on Pt/SiO2 At High Pressure and Ft-Rairs of Co Adsorbed on a Polycrystalline Foil in Uhv Original Research Article
Pages 257-262
M.A. Chesters, D. Coombs, S.F. Parker

The Adsorption of Carbon Tetrachloride on Ni(110) Original Research Article
Pages 263-268
M.A. Chesters, D. Lennon

Calcination-Dependence of Platinum Cluster Formation in NAY Zeolite: A Xenon-129 NMR Study Original Research Article
Pages 269-278
B.F. Chmelka, L.C. de Menorval, R. Csencsits, R. Ryoo, S.B. Liu, C.J. Radke, E.E. Petersen, A. Pines

Xps and Esr Study of Nickel Valency States in Nio-Mgo High Surface Area Solid Solutions Original Research Article
Pages 279-288
A. Cimino, D. Gazzoli, V. Indovina, M. Inversi, G. Moretti, M. Occhiuzzi

Surface Characterization of Ionic Microcrystalline Systems by Optical Spectroscopies Original Research Article
Pages 289-306
S. Coluccia

Photoreactivity of Iron-Doped Titanium Dioxide Powders for Dinitrogen Reduction to Ammonia Original Research Article
Pages 307-317
J.C. Conesa, J. Soria, V. Augugliaro, L. Palmisano

Angle-Resolved Ups Studies of Cn on Cu(110) and Cu(100) Original Research Article
Pages 319-326
M. Connolly, T. Mccabe, D.R. Lloyd, E. Taylor

Surface Reactions of Hydrocarbons as a Probe for the Characterization of Supported Ruthenium Bimetallic Catalysts. Original Research Article
Pages 327-334
B. Coq, A. Bittar, F. Figueras

Theoretical Calculations on the Stability of Carbide Layers at Transition Metal Surfaces Original Research Article
Pages 335-345
G.R. Darling, R.W. Joyner, J.B. Pendry

Critical Metal Concentration Effect on Average Size Selected (Pd-Ag) Clusters in the Selective Hydrogenation of 1,3-Butadiene Original Research Article
Pages 347-353
V. De Gouveia, B. Bellamy, A. Masson, M. Che

Comparison of Cu-Support Interaction in Model and Real Catalysts Original Research Article
Pages 355-361
V. Di Castro, C. Furlani, G. Polzonetti

Studies of Skeletal Rearrangements of Labeled Hexanes on Platinum-Ruthenium Catalysts. Correlation Between the Product Distributions and the Structure of the Catalysts Given by E.X.A.F.S. Original Research Article
Pages 363-374
G. Diaz, P. Esteban, L. Guczi, F. Garin, P. Bernhardt, J.-L. Schmitt, G. Maire

Surface Reactivity Under Oxygen Atmosphere of Os3(CO)12 Supported on Silica and Alumina. Original Research Article
Pages 375-384
C. Dossi, A. Fusi, R. Psaro, R. Ugo, R. Zanoni

AB Initio Study of the Periodic Carbon Monoxide Adsorption on the Basal Plane of Alpha-Alumina Original Research Article
Pages 385-393
R. Dovesi, C. Roetti, M. Causa, C. Pisani

Adsorbate-Adsorbate Interaction in Mixed Co-No Overlayers on NiO(100): An IR Investigation Original Research Article
Pages 395-403
E. Escalona Platero, E. Garrone, G. Spoto, A. Zecchina

Silanol as a Model for the Free Hydroxyl of Amorphous Silica: Non-Empirical Calculations of the Vibrational Features of H3SiOH. Original Research Article
Pages 405-413
E. Garrone, P. Ugliengo

AN IR Study of Ethylene Hydrogenation at RT on a Cu/ZnO Catalyst Original Research Article
Pages 415-425
G. Ghiotti, F. Boccuzzi, A. Chiorino

Effect of Water in the Encapsulation of the Metallic Phase During Smsi Generation in Pt/TiO2 Catalysts Original Research Article
Pages 427-436
A.R. Gonzalez-Elipe, P. Malet, J.P. Espinos, A. Caballero, G. Munuera

An Infrared Study of Co Adsorbed on a Ru/Zno Catalyst Original Research Article
Pages 437-446
E. Guglielminotti, F. Boccuzzi

The Concept of Structure-Sensitivity in Catalysis by Oxides Original Research Article
Pages 447-467
J. Haber

Catalyst Characterization and in situ FTIR Studies of Carbon Dioxide Methanation Over Ruthenium Supported on Titania Original Research Article
Pages 469-479
J.G. Highfield, P. Ruterana, K.R. Thampi, M. Graetzel

On the Role of Supports and Promotors in CO+H2 Reactions on Rhodium Based Catalysts Original Research Article
Pages 481-491
J.P. Hindermann, A. Kiennemann, S. Tazkritt

High Resolution Vibrational Spectra of Co Adsorbed on Clean and Potassium-Covered Platinum {111} Original Research Article
Pages 493-502
D. Hoge, M. Tushaus, P. Gardner, A.M. Bradshaw

A Particle Size Effect in the Oxygen Desorption from Platinum Supported within a Faujasite Matrix Original Research Article
Pages 503-513
N.I. Jaeger, A.L. Jourdan, G. Schulz-Ekloff, A. Svensson

Comparison of Copper and Palladium Catalysts in the Synthesis of Methanol from CO/H2 Mixtures Original Research Article
Pages 515-524
J.R. Jennings, M.S. Spencer

Molybdena on Niobium Oxide Catalysts: Preparation and Characterization Original Research Article
Pages 525-534
Y.S. Jin, A. Ouqour, A. Auroux, J.C. Vedrine

Change in the Reactivity of a Superalloy by Forming Surface Alloys Using Laser Glazing Technique Original Research Article
Pages 535-547
W.J. Quadakkers, H. Schuster, A.S. Khanna, K. Wissenbach, A. Gasser, E.W. Kreutz

Fourier Transform Infrared Spectroscopy of Oxidized Ultra-Fine α-Silicon Carbide Original Research Article
Pages 549-558
M. Kizling, R.J. Pugh

Electron Microscopy and Microdiffraction Study of the Interaction of Pd with SiO2 Original Research Article
Pages 559-565
R. Lamber, N. Jaeger, G. Schulz-Ekloff

Application of Optical Methods (50000-400 cm−1) to Study the Oxidation of Nickel. Theoretical Approach and Experience Original Research Article
Pages 567-573
M. Le Calvar, M. Lenglet

UV-Vis-NIR and FTIR Reflectance Studies of the Initial Stage of Oxidation of 80 Ni-20 Cr Alloy. Original Research Article
Pages 575-580
M. Le Calvar, M. Lenglet

Reactivity of Mixed Zn-Cr Oxide Towards Linear C4 Oxygenated Molecules by the Tpsr Method. Original Research Article
Pages 581-589
L. Lietti, E. Tronconi, P. Forzatti, I. Pasquon

“Surface Organometallic Chemistry : Newselective Bimetallic Ru-Sn/SiO2 Catalysts Prepared by Reaction of Tetra-N-Butyl Tin with RuO2 Supported on Silica” Original Research Article
Pages 591-600
P. Louessard, J.P. Candy, J.P. Bournonville, J.M. Basset

Infrared Spectra of Carbons X. The Spectral Profile of Medium-Temperature Chars Original Research Article
Pages 601-609
M.J.D. Low, C. Morterra

Preparation of Hydrotreating Catalysts by Kneading. Characterization of the Oxidic Phase by Laser Raman, X-Ray Photoelectron and Uv-Visible Spectroscopies Original Research Article
Pages 611-623
F. Luck, F. Viez

Characterization of the Growth of an Oxidation Precursor at Low Temperature on Ofhc Copper Original Research Article
Pages 625-632
J.-M. Machefert, M. Lenglet, D. Blavette, A. Menand, A.D' Huysser

XPS and SIMS Investigation on the Catalyst-Support Chemical Interaction for Ruox-Teflon Systems Original Research Article
Pages 633-641
C. Malitesia, G. Morea, L. Sabbatini, N. Tangari, V. Tortorella, P.G. Zambonin

Photoassisted Mechanisms in Heterogeneous Catalysis: The Role of Surface OH in the Decomposition of Ethanoic Acid on Magnesium Oxide Original Research Article
Pages 643-652
L. Marchese, S. Coluccia, E. Borello, L. Palmisano, A. Sclafani, M. Schiavello

The Pt/Al2O3 System: Infrared Studies Original Research Article
Pages 653-663
L. Marchese, M.R. Boccuti, S. Coluccia, S. Lavagnino, A. Zecchina, L. Bonneviot, M. Che

Free and Supported Metal Clusters: Structures and Reactivity Original Research Article
Pages 665-675
A. Masson

The Formation of Well Defined Rhodium Dicarbonyl and Dinitrosyl with Rhodium Supported on Highly Dealuminated Zeolite Y Original Research Article
Pages 677-684
H. Miessner, I. Burkhardt, D. Gutschick, A. Zecchina, C. Morterra, G. Spoto

Surface Characterization of Cu/SiO2 Catalysts Prepared by Ion-Exchange Original Research Article
Pages 685-693
A. Molnar, J.T. Kiss, G. Sirokman, M. Bartok

Methanol Decomposition on Pd/ThO2: Relation Between Activity and Surface Structure Original Research Article
Pages 695-702
X. Montagne, R. Boulet, E. Freund, J.C. Lavalley

Adsorbate-Adsorbate Interactions at the Surface of Polycrystalline Monoclinic Zirconia Original Research Article
Pages 703-712
Claudio Morterra, Renato Aschieri, Vera Bolis, Enzo Borello

Adsorption and Dissociation of CO2 on Lanthanide Ion Promoted Rh/Al2O3 Catalysts Original Research Article
Pages 713-722
J.A. Odriozola, I. Carrizosa, R. Alvero

A Structure Determination of the Tilted α3 State of Co on FE(001) by X-Ray Photoelectron Diffraction Original Research Article
Pages 723-728
J. Osterwalder, G.S. Herman, R.S. Saiki, M. Yamada, C.S. Fadley

A Competitive Reaction which is Able to Make Fine Distinctions Between Reacting Surfaces Original Research Article
Pages 729-737
I. Pálinkó, F. Notheisz, M. Bartók

Activity and Characterization of Alkali Doped Ni/MgO Catalysts Original Research Article
Pages 739-748
A. Parmaliana, F. Frusteri, F. Arena, N. Mondello, N. Giordano

Comparison of Alkali Promoters on Silica-Supported Ni and Ni (111) : Chemical State, Localization and Range of the Promoter Effect Original Research Article
Pages 749-757
H. Praliaud, B. Tardy, J.C. Bertolini, G.A. Martin

Metal Support Interaction Original Research Article
Pages 759-776
R. Prins, J.H.A. Martens, D.C. Koningsberger

Surface Acidity of Solid Acids and Superacids: A Ft-Ir Study of the Behaviour of Titania Doped with Phosphoric, Sulphuric, Tungstic and Molybdic Acids Original Research Article
Pages 777-786
G. Ramis, G. Busca, V. Lorenzelli

The nature and reactivity of chemisorbed oxygen and oxide overlayers at metal surfaces as revealed by photoelectron spectroscopy Original Research Article
Pages 787-797
M.W. Roberts

Support Effects in Test Reactions of Hexanes on Pt/UO2 Catalysts and on A UPt3 Intermetallic Compound. Original Research Article
Pages 799-808
M. Romeo, A. Dauscher, L. Hilaire, W. Muller, G. Maire

On the Reactivity of Diamond-Like Semiconductor Surfaces Original Research Article
Pages 809-816
N. Russo

Hydrogenation of Carbon Monoxide Over An Ru(0001) Single Crystal Surface Original Research Article
Pages 817-824
B. Sakakini, B. Steeples, N. Dunhill, J.C. Vickerman

Co Dissociation on Ni(100) Studied by Auger Electron Spectroscopy Original Research Article
Pages 825-833
A. Santoni, C. Astaldi, F. Della Valle, R. Rosei

On the Nature and the Number of Reaction Sites on Pt Catalysts Original Research Article
Pages 835-843
A. Sárkány

Infrared Study of the Effects of O-Containing Compounds on Co Preadsorbed on Pt/Cab-O-Sil Original Research Article
Pages 845-853
J. Sárkány, M. Bartók

In-Situ X-Ray Study of the Solid-State Reduction of Copper Catalysts Original Research Article
Pages 855-861
P.A. Sermon, M.S.W. Vong, K. Grant

Catalytic Properties and Characterization of LaPd3 Intermetallic Compound Original Research Article
Pages 863-870
K.S. Sim, L. Hilaire, F. Le Normand, R. Touroude, V. Paul-Boncour, A. Percheron-Guegan

Phase-Transition Induced Change of Electron-Surface Spin-Flip Scattering Revealed from Cesr on Metallic Li Globules Embedded in n-Irradiated LiF Original Research Article
Pages 871-880
A. Stesmans

Studies of the Initial Stages of the Adsorption of Pd on an Extensively Oxidised Zn(0001) Support Original Research Article
Pages 881-891
A.J. Swift, J.C. Vickerman

Nitric Oxide Adsorption on (111) and (001) Surfaces of Diamond-Like Crystals. A Theoretical Study on Model Finite Clusters Original Research Article
Pages 893-902
M. Toscano, N. Russo

Surface Analysis of the Activation of Getter Compounds Original Research Article
Pages 903-910
I. Vedel, L. Schlapbach

Microstructures of Copper Surfaces During Electroless Copper Deposition Original Research Article
Pages 911-917
Michael Wanner, Konrad G. Weil

Variation of Optical Emissivity During the First Stages of the Oxidation of Tungsten. Original Research Article
Pages 919-924
B. Weber, G. Sum Yuen, P. Pigeat, N. Pacia

Reactivity and Photodynamics of Size-Selected Metal Clusters Original Research Article
Pages 925-941
L. Wöste

Surface Chemistry of Zirconia-Supported Rhodium Carbonyl Clusters Original Research Article
Pages 943-953
T. Zerlia, A. Carimati, S. Marengo, S. Martinengo, L. Zanderighi

XPS and FTIR Investigation of V-Alumina Supported Catalysts Derived from H3Re3(CO)12 and NH4ReO4 : A Comparative Study Original Research Article
Pages 955-964
Z. Zsoldos, A. Beck, L. Guczi

Author Index
Pages 965-967

Studies in Surface Science and Catalysis
Pages 968-970