Smart Inorganic Polymers: Synthesis, Properties, and Emerging Applications in Materials and Life Sciences

Content: Cover
 Title Page
 Copyright
 Contents
 Preface
 Chapter 1 Current Status and Future Perspectives of Functional and Smart Materials in Daily Life
 1.1 Introduction
 1.2 Properties and Applications
 1.2.1 Applications Based on Mechanical and Rheological Properties
 1.2.2 Applications Based on Electronic Excitation
 1.2.3 Applications Based on Optical Features
 1.2.4 Applications Based on Supramolecular Recognition
 1.2.5 Applications Based on Chemical Reactivity
 1.2.6 Further Applications
 1.3 Perspective
 Acknowledgments
 References
 Chapter 2 Boron‐Containing Polymers Chapter 2.1 Group 13-Group 15 Element Bonds Replacing Carbon-Carbon Bonds in Main Group Polyolefin Analogs2.1.1 Introduction
 2.1.2 Group 13-Group 15 Element‐Containing Polyolefin Analogs with the Heteroatoms in the Main Chain
 2.1.2.1 Poly(phosphinoboranes)
 2.1.2.1.1 Metal Complexes as Catalysts for the Dehydrocoupling of Phosphine-Boranes
 2.1.2.1.2 Lewis Acid Promoted Dehydrocoupling of Phosphine-Boranes
 2.1.2.1.3 Lewis Base Promoted Dehydrocoupling of Phosphine-Boranes
 2.1.2.1.4 Poly(phosphinoborane)‐Based Materials
 2.1.2.1.5 Potenial Applications of Poly(phosphinoboranes) 2.1.2.2 Poly(aminoboranes)2.1.3 Group 13-Group 15 Element‐Containing Polyolefin Analogs with the Heteroatoms in the Side Chain
 2.1.3.1 Borazine‐Containing PS Analogs
 2.1.3.2 Azaborinine‐Containing PS Analogs
 2.1.4 Conclusion and Outlook
 Acknowledgments
 References
 Chapter 2.2 Highlighting the Binding Behavior of Icosahedral Boron Clusters Incorporated into Polymers: Synthons, Polymers Preparation, and Relevant Properties
 2.2.1 Introduction
 2.2.2 Conducting Organic Polymers Containing Icosahedral Boron Clusters
 2.2.2.1 Icosahedral Boron Clusters as Doping Agents in COPs 2.2.2.2 Icosahedral Boron Clusters in COPs Side Chains to Modify the Chemical Composition and Act as Doping Agent2.2.2.3 Icosahedral Boron Clusters Incorporated into the Polymer Main Chain of the COPs
 2.2.3 Fluorescent Carborane‐Containing Polymers
 2.2.4 Thermally Resistant Carborane‐Based Polymers
 2.2.5 Coordination Polymers and Nanoparticles Incorporating closo‐Carborane Clusters
 2.2.5.1 Carboxylate‐Functionalized Carboranes
 2.2.5.2 Phosphinate‐ and Phosphino‐Functionalized Carboranes
 2.2.5.3 Nanohybrid Materials Based on Functionalized Carboranes
 2.2.6 Conclusion and Outlook AcknowledgmentsReferences
 Chapter 3 Synthesis of Group 14 Metal‐Containing Polymers
 3.1 Introduction
 3.2 Organohydrides of Group 14, RnEH4−n
 3.3 Diorganodihydrides of Group 14, R2EH2, as Building Blocks for Chain‐Type Polymers
 3.3.1 Metal‐Catalyzed Dehydropolymerization
 3.3.2 Dehydrogenative Coupling Using an Amine Base
 3.3.3 Solvent‐ and Catalyst‐Free Dehydrogenative Coupling
 3.3.4 Condensation
 3.4 Monoorganotrihydrides of Group 14, REH3, as Building Blocks for 3D Polymers
 3.4.1 Metal‐Catalyzed Dehydropolymerization
 3.4.2 Dehydrogenative Coupling Using an Amine Base