Selected Problems in Physical Chemistry

Preface......Page 5
 Acknowledgment......Page 7
 Part I Mechanics......Page 11
   1.1 Calculation......Page 12
   1.1 Solution B  Strategy and Calculation......Page 13
   1.1 Solution  Strategy and Calculation......Page 15
  References......Page 16
  2  Mechanics of Gases......Page 17
   2.1 Calculation A......Page 18
   2.1 Solution B  Strategy......Page 19
   2.1 Calculation B......Page 20
   2.1 Solution  Calculation......Page 22
   2.1 Solution  Calculation......Page 24
   2.1 More calculation......Page 25
  Reference......Page 26
 Part II Basic Thermodynamics......Page 28
   3.1 Solution  Strategy......Page 29
   3.1 Solution  Calculation......Page 30
   3.1 Assumption 2......Page 32
   3.1 Solution  Strategy......Page 33
   3.1 Solution  Suggestions and Tips......Page 36
  References......Page 38
  4  Thermodynamics......Page 39
   4.1 Entropy......Page 40
   4.2 Example 4.1......Page 41
   4.2 Example 4.2......Page 42
   4.2 Solution  Strategy and Calculation......Page 45
   4.2 Gibbs Free Energy......Page 46
   4.3 Solution  Strategy and Calculation......Page 47
   4.3 Solution  Strategy and Calculation......Page 50
   4.3 Solution  Calculation......Page 51
  Reference......Page 53
 Part III Mixtures and Chemical Thermodynamics......Page 55
   5.1 Solution......Page 56
   5.1 Assumptions 1 and 2......Page 58
   5.1 Solution B  Calculation......Page 59
   5.1 Solution  Strategy and Calculation......Page 60
  References......Page 62
  6  Chemical Reactions and Gibbs Free Energy......Page 63
   6.1 Solution......Page 65
  References......Page 66
  7  Gibbs Free Energy and Chemical Equilibria......Page 67
   7.1 Solution A  Strategy......Page 69
   7.1 Solution B  Strategy and Calculation......Page 70
   7.1 Approximations......Page 71
   7.1 Receptor and Ligand Equilibria......Page 72
   7.2 Solution  Strategy......Page 73
   7.2 Solution  Calculation......Page 74
   7.2 Solution  Strategy......Page 75
   7.2 Solution A  Strategy and Calculation......Page 79
   7.2 Solution B  Strategy and Calculation......Page 82
   7.2 Solution C  Strategy and Calculation......Page 84
   7.2    Assumption       1......Page 86
   7.2 Solution  Calculation a and b......Page 87
   7.2 Solution  Strategy and Calculation C......Page 88
   7.2 Acids and Bases......Page 89
   7.3 Solution  Strategy and Calculation......Page 90
   7.3 Solution  Strategy and Calculation......Page 93
  References......Page 96
 Part IV Ionic Properties and Electrochemistry......Page 98
  8  Ions......Page 99
   8.1 Solution  Strategy and Calculation......Page 101
   8.1 Ion Activities......Page 102
   8.2 Solution  Strategy and Calculation......Page 104
   8.2 Solution  Strategy......Page 106
   8.2 Solution  Calculation......Page 107
  Reference......Page 109
   9.1 Solution  Background......Page 110
   9.1 Solution  Strategy and Calculation......Page 113
   9.1 Biological Electrochemistry......Page 117
   9.2 Solution  Strategy and Calculation......Page 118
   9.2 Solution (B)  Calculation......Page 121
   9.2 Solution (A) Strategy......Page 122
   9.2 Solution A More Strategy and Calculation......Page 123
   9.2 Solution B Hints and Suggestions......Page 124
  References......Page 125
 Part V Kinetics......Page 127
   10.1 Example......Page 128
   10.1 Solution A  Calculation......Page 130
   10.1 Solution B  Strategy and Calculation......Page 131
   10.1 Solution A  Calculation......Page 133
   10.1 Solution B  Strategy and Calculation......Page 134
   10.1 Solution  Strategy......Page 135
   10.1 Solution  Calculation......Page 136
   10.1 Enzyme Kinetics......Page 137
   10.2 Solution  Strategy......Page 139
   10.2 Assumptions......Page 140
   10.2 Solution  Calculation......Page 141
   10.2 Reaction Barriers......Page 142
   10.3 Solution  Strategy and Calculation......Page 145
  References......Page 146
 Part VI Structure of Matter: Molecular Spectroscopy......Page 149
   11.1 Simple Quantum Mechanics......Page 150
   11.2 Solution  Calculation......Page 153
   11.2 Assumption 1......Page 156
   11.2 Solution A Calculation......Page 157
   11.2 Solution B  Strategy and Calculation......Page 158
   11.2 Assumption 3......Page 160
   11.2 Solution  Hints and Suggestions......Page 162
  References......Page 164
   12.1 UV and Visible Spectroscopy......Page 165
    12.1.0 UV/Vis Spectrophotometry......Page 166
   12.2 Solution  Strategy and Calculation......Page 168
   12.2 Solution  Hints and Suggestions......Page 169
   12.2 Vibrational Spectroscopy......Page 170
   12.3 Solution  Strategy and Calculation......Page 172
    12.2.0 Isotopic Effects in Molecular Vibrations......Page 174
   12.3 Assumptions 1 and 2......Page 176
  12.3 Nuclear Magnetism and NMR Spectroscopy......Page 177
  Solution  Strategy......Page 180
   12.4 Solution  Calculation......Page 181
   12.4 Solution  Calculation......Page 182
   12.4 Level Population......Page 183
   12.5 Solution  Calculation......Page 184
   12.6 Solution  Strategy and Calculation......Page 186
   12.6 Solution  Strategy and Calculation......Page 189
   12.6 Assumption......Page 191
   12.6 A and B  Strategy......Page 192
   12.6 Solution A and B  Calculation......Page 193
  References......Page 195
  Index......Page 197
   12.4 Solution  Strategy......Page 0
   12.3 Nuclear Magnetism and NMR Spectroscopy......Page 178