Science and Technology in Catalysis 2002, Proceedings of the Fourth Tokyo conference on Advance Catalytic Science and Technology

Content: 
Board and committee
Pages v-vi

Acknowledgments
Page vii

Preface
Page xxv
Masakazu Anpo, Makoto Onaka, Hiromi Yamashita

1 New catalysts for controlled/living atom transfer radical polymerization (ATRP) Original Research Article
Pages 3-11
Krzystof Matyjaszewski

2 Plattenbau-automated synthesis of catalysts and materials libraries Original Research Article
Pages 13-20
Jens Scheidtmann, Jens W. Saalfrank, Wilhelm. F. Maier

3 From the internal combustion engine to the fuel cell: Moving towards the hydrogen economy Original Research Article
Pages 21-29
Robert J. Farrauto

4 Catalysis and applications of gold nanoparticles Original Research Article
Pages 31-38
Masatake Haruta

5 Synergetic design between the catalyst system and the reaction field-development of palladium—Lead intermetallic compound catalysts— Original Research Article
Pages 39-46
Setsuo Yamamatsu

6 Ethylene polymerization behavior of polymethylene-bridged bis (phenoxy-imine) Zr complexes Original Research Article
Pages 49-54
Sei-ichi Ishii, Makoto Mitani, Junji Saito, Sadahiko Matsuura, Rieko Furuyama, Terunori Fujita

7 Ionic liquids as new solvents and catalysts for petrochemical and refining processes Original Research Article
Pages 55-60
Hélène Olivier-Bourbigou, Vincent Lecocq

8 Modern refining concepts-an update on naphtha-isomerization to modern gasoline manufacture Original Research Article
Pages 61-66
Hartmut Weyda, Ernst Köhler

9 A novel process for solid acid catalyzed isobutane/butene alkylation Original Research Article
Pages 67-72
Andreas Feller, Alexander Guzman, Iker Zuazo, Johannes A. Lercher

10 Vapor phase beckmann rearrangement over a high silica MFI zeolite Original Research Article
Pages 73-78
Hiroshi Ichihashi

11 DFT and experimental studies of C-C and C-O bond cleavage in ethanol and ethylene glycol on Pt catalysts Original Research Article
Pages 79-84
R.R. Davda, R. Alcalá, J. Shabaker, G. Huber, R.D. Cortright, M. Mavrikakis, J.A. Dumesic

12 Design of solid base catalysts for the production of chemicals Original Research Article
Pages 85-90
Subramanian Sivasanker

13 Nanofabrication of zeolitic crystals with nanoglues by microwave Original Research Article
Pages 91-96
Sang-Eon Park, Dae Sung Kim, Young Kyu Hwang

14 Microreactors for measuring catalyst activity and determining reaction kinetics Original Research Article
Pages 97-102
Sameer K. Ajmera, Cyril Delattre, Martin A. Schmidt, Klavs F. Jensen

15 Steam reforming reaction of methanol with a membrane reactor catalysis-spillover-membrane Original Research Article
Pages 103-108
M.H. Rei, C.K. Tsui, C.W. Pan, Y.M. Lin

16 Converting natural gas to ethylene and propylene using the UOP/HYDRO MTO process Original Research Article
Pages 109-114
Paul T. Barger, Bipin V. Vora, Peter R. Pujadó, Qianjun Chen

17 Deep hydrodesulfurization: Reactions and catalysts Original Research Article
Pages 115-120
Michèle Breysse, Claude E. Hédoire, Catherine Louis, Guy Pérot

18 Effect of cyclopentadienyl fragment in polymerization of ethylene, propylene, and styrene by nonbridged half-metalloce type titanium and zirconium complexes of the type, Cp'MCl2 [N(2,6-Me2 C6 H3) (SiMe3)], -MAO catalyst systems Original Research Article
Pages 121-124
Kotohiro Nomura, Kensaku Fujii

19 Cp* TiCl3 catalyst supported on functionalized macroreticular resin bead for ethylene polymerization Original Research Article
Pages 125-128
Ki-Soo Lee, O-Yong Jeong, Son-Ki Ihm

20 Upporting effects of methylaluminoxane on propene polymerization with an alkyltitanium complex Original Research Article
Pages 129-132
Hitoshi Hagimoto, Takeshi Shiono, Tomiki Ikeda

21 A new polymer supported palladium complex as active, air stable and recyclable catalyst for carbon-carbon bond forming reactions Original Research Article
Pages 133-136
Maria Michela Dell'Anna, Piero Mastrorilli, Francesco Muscio, Cosimo Francesco Nobile

22 Enantiospecific heterogeneous catalysis without a chiral modifier Original Research Article
Pages 137-140
Päivi Mäki-Arvela, Tapio Salmi, Dmitry Yu. Murzin

23 A novel promotion system for carbonyl-ene reactions of styrenes with paraformaldehyde —The combined use of boron trifluoride and molecular sieves Original Research Article
Pages 141-144
Takahiro Okachi, Makoto Onaka

24 Catalytic direct 1,4-conjugate addition of aldehydes to vinylketones on N-methyl-3-aminopropylated FSM-16 Original Research Article
Pages 145-148
Kenrichi Shimizu, Hiromasa Suzuki, Tatsuya Kodama, Hisahiro Hagiwara, Yoshie Kitayama

25 Catalytic synthesis of dimethyltoluene-2,4-dicarbamate by the methoxycarbonylation of 2,4-toluene diamine with dimethyl carbonate using Zn (OAc)2·2H2O Original Research Article
Pages 149-152
Toshihide Baba, Akane Kobayashi, Tatsuya Yamauchi, Shinji Aso, Masamitsu Inomata, Yukio Kawanami

26 Electronic structure change on TiO2 surface due to UV light irradiation Original Research Article
Pages 153-156
Masaharu Komiyama, Donghong Yin, Yanjun Li

27 Time-resolved infrared absorption study of electron- and hole-capture reactions on photoexcited Pt/TiO2 in the presence of methanol-water vapor mixture Original Research Article
Pages 157-160
Akira Yamakata, Taka-aki Ishibashi, Hiroshi Onishi

28 The activity of TiO2 and heteropolytungstate-modified TiO2 in the photocatalytic degradation of aqueous cyanide Original Research Article
Pages 161-164
Jae-Hyun Kim, Ho-In Lee

29 Effect of 3d transition-metal (M) doping in In1-xMx TaO4 photocatalysts on water splitting under visible light irradiation Original Research Article
Pages 165-168
Zhigang Zou, Jinhua Ye, Ryu Abe, Kazuhiro Sayama, Hironori Arakawa

30 Ta3N5 and TaON as novel photocatalysts responding to visible light Original Research Article
Pages 169-172
Michikazu Hara, Go Hitoki, Tsuyoshi Takata, Junko N. Kondo, Hisayoshi Kobayashi, Kazunari Domen

31 Template synthesis, formation mechanism and catalysis of metal nanowires in mesoporous materials Original Research Article
Pages 173-176
Atsushi Fukuoka, Yuzuru Sakamoto, Hidenobu Araki, Shinji Inagaki, Noriaki Sugimoto, Yoshiaki Fukushima, Masaru Ichikawa

32 X-ray absorption fine structure utilizing a fluorescence spectrometer: Site selective structure determination of environmental catalysts and adsorbents Original Research Article
Pages 177-180
Yasuo Izumi, Fumitaka Kiyotaki, Hiroyasu Nagamori, Taketoshi Minato

33 Synthesis of Ru-M cluster compounds and their use as precursors for nanoparticle catalysts supported on mesopous silica Original Research Article
Pages 181-184
S. Hermans, T. Khimyak, R. Raja, G. Sankar, B.F.G. Johnson, J. Meurig Thomas

34 Preparation and characterization of highly dispersed metal nanoparticles on mesoporous silicate and aluminosilicate supports Original Research Article
Pages 185-188
Kuei-jung Chao, Chia-min Yang, Ya-chieh Chen, Pang-hung Liu, An-nan Kao

35 Formation of new re clusters in HZSM-5 and their catalytic property in propene selective oxidation/ammoxidation reactions Original Research Article
Pages 189-192
N. Viswandham, T. Shido, T. Sasaki, Y. Iwasawa

36 Preparation and characterization of polymer immobilized Nano-Au catalysts for oxidative carbonylation of aniline and its derivatives Original Research Article
Pages 193-196
Feng SHI, Youquan DENG

37 Catalytic activity of gallium-loaded ZSM-5 zeolite for synthesis of aniline from phenol and ammonia Original Research Article
Pages 197-200
Naonobu Katada, Tokuko Doi, Tatsuro Shinmura, Shuji Kuroda, Miki Niwa

38 Effects of reducing and oxidising pre-treatments on the state of gallium in Ga/H-ZSM-5 propane aromatisation catalysts Original Research Article
Pages 201-204
Izabela Nowak, Juliette Quartararo, Eric G. Derouane, Jacques C. Védrine

39 Qualitative and quantitative determination of acid sites on solid acid catalysts Original Research Article
Pages 205-209
Qi Zhao, Wen-Hua Chen, Shing-Jong Huang, Shang-Bin Liu

40 On the generation of basic properties of supported nitrates and carbonates of group 1 and group 2 elements Original Research Article
Pages 211-214
Tsutomu Yamaguchi, Yie Wang, Masa-aki Komatsu, Atsunari Suzuki, Masashi Ookawa

41 Preparation and catalytic application of cationic metal carbonyls Original Research Article
Pages 215-218
Qiang Xu, Yoshie Souma

42 Hydroisomerization of tetralin on zeolite beta: Influence of crystal size Original Research Article
Pages 219-222
Praveen Sharma, Yasutoshi Iguchi, Yasushi Sekine, Eiichi Kikuchi, Masahiko Matsukata

43 A new microporous zinc silicate Original Research Article
Pages 223-226
Asim Bhaumik, Nawal Kishor Mal

44 Comparative studies of TPD and TPR on the reaction between adsorbed NOx species and CH4 over Cu-ZSM-5 Original Research Article
Pages 227-230
Masahide Shimokawabe, Kohei Okumura, Nobutsune Takezawa

45 Preparation of copper-loaded MFI zeolites by solid-state ion exchange method and their catalytic activity for direct NO decomposition Original Research Article
Pages 231-234
Yasutake Teraoka, Hiroshi Furukawa, Isamu Moriguchi

46 In-situ UV-visible spectroscopic study for dynamic analysis of silver catalyst Original Research Article
Pages 235-238
Atsushi Satsuma, Junji Shibata, Akio Wada, Yoshio Shinozaki, Tadashi Hattori

47 NO reduction by CH4 over well-structured Pt nanocrystals supported on γ-Al2O3 Original Research Article
Pages 239-242
Ioan Balint, Akane Miyazaki, Ken-ichi Aika

48 Selective NO-H2-O2 reactions over Pt/TiO2-ZrO2 at<100°C Original Research Article
Pages 243-246
Masato Machida, Satoshi Ikeda, Tsuyoshi Kijima

49 NOx sorption-desorption mechanism of ZrO2-based oxide Original Research Article
Pages 247-250
Suzue Kikuyama, Izumi Matsukuma, Tatsuya Takeguchi, Ryuji Kikuchi, Koichi Eguchi, Kazunari Sasaki

50 Effect of titanium active site location on activity of phase boundary catalyst particles for alkene epoxidation with aqueous hydrogen peroxide Original Research Article
Pages 251-254
Shigeru Ikeda, Hadi Nur, Peng Wu, Takashi Tatsumi, Bunsho Ohtani

51 A green route to epoxides: Catalytic selective epoxidation of alkenes with 1 atm molecular oxygen with 10000 turnover number Original Research Article
Pages 255-258
Yoshiyuki Nishiyama, Testuya Hayashi, Yoshinao Nakagawa, Noritaka Mizuno

52 Cyclic carbonate synthesis from carbon dioxide and epoxide catalyzed by samarium oxychloride supported on zirconia Original Research Article
Pages 259-262
Hiroyuki Yasuda, Liang-Nian He, Toshiyasu Sakakura

53 Leaching features of Fe-MCM-41 during epoxidation of alkene with hydrogen peroxide Original Research Article
Pages 263-266
Ye Wang, Qinghong Zhang, Tetsuya Shishido, Katsuomi Takehira

54 Selective hydrogenation of unsaturated aldehydes into unsaturated alcohols: Role of metal-support interactions in platinum catalysts Original Research Article
Pages 267-270
Mohamed Abid, Fatima Ammari, Katerina Liberkova, Raymonde Touroude

55 A highly selective vanadyl pyrophosphate synthesized by exfoliation-reduction in mixed alcohols for n-butane oxidation Original Research Article
Pages 271-274
Toshio Okuhara, Naonori Ryumon, Naoki Yamamoto, Norihito Hiyoshi

56 High throughput experiment on the investigation of oxidation catalysts with gas sensor system Original Research Article
Pages 275-278
Yusake Yamada, Atsushi Ueda, Tetsuhiko Kobayashi

57 Characteristics of highly active PtRu/C anode catalysts for DMFC Original Research Article
Pages 279-282
Yoshio Takasu, Hiroyuki Itaya, Tomoyuki Kawaguchi, Wataru Sugimoto, Yasushi Murakami

58 Gas-phase electrocatalytic conversion of CO2 to fuels over gas diffusion membranes containing Pt or Pd nanoclusters Original Research Article
Pages 283-286
Gabriele Centi, Siglinda Perathoner, Zbigniew S. Rak

59 Continuous synthesis process of methanol at low temperature from syngas containing CO2 using alcohol solvent Original Research Article
Pages 287-290
Noritatsu Tsubaki, Yoshiharu Yoneyama, Kaoru Fujimoto

60 Simple GA program developed for optimization of methanol and dimethyl ether synthesis Original Research Article
Pages 291-294
Kohji Omata, Tetsuo Umegaki, Yuhsuke Watanabe, Munyeoshi Yamada

61 Preparation, characterization, and catalytic evaluation of first stage hydrocracking catalyst Original Research Article
Pages 295-298
Shakeel Ahmed, Syed A. Ali, Halim Hamid, Kosaku Honna

62 Elucidation of behavior of hydrogen on solid catalysts using a tritium tracer method Original Research Article
Pages 299-302
Eika W. Qian, Kei Iwata, Atsushi Ishihara, Tamotsu Imai, Toshiaki Kabe

63 Steam reforming catalysts for H2 production from ethanol Original Research Article
Pages 303-306
Fabien Aupretre, Claude Descorme, Daniel Duprez

64 Catalyst development for low temperature gasification of biomass: Function of char removal in fluidized bed reactor Original Research Article
Pages 307-310
Mohammad Asadullah, Tomohisa Miyazawa, Shin-ichi Ito, Kimio Kunimori, Keiichi Tomishige

65 Ultra-deep hydrodesulfurization of 4, 6-dimethyldibenzothiophene over Mo sulfide catalysts supported on TiO2-Al2O3 composite Original Research Article
Pages 311-314
Kazushige Takahashi, Youssef Saih, Kohichi Segawa

66 Hydrodesulfurization of dibenzothiophene and 4, 6-dimethyldibenzothiophene using fluorinated NiMoS/Al2O3 catalysts Original Research Article
Pages 315-318
Heeyeon Kim, Jung Joon Lee, Jae Hyun Koh, Sang Heup Moon

67 Activity and deactivation of HDS catalysts: Studying the active phase using CO as a probe molecule Original Research Article
Pages 319-321
Bas M. Vogelaar, Petr Steiner, A. Dick Van Langeveld, Sonja Eijsbouts, Jacob A. Moulijn

68 Structure and location of oxomolybdenum entities in zeolite-supported HDS oxidic precursors Original Research Article
Pages 323-326
Guillaume Plazenet, Edmond Payen, Bernadette Rebours, John Lynch

69 Thiophene hydrogenation with mesoporous smectite-type materials containing cobalt cations in octahedral sheets Original Research Article
Pages 327-330
Masayuki Shirai, Kazuo Torii, Nobuhiro Iwasa, Masahiko Arai

70 Mobility of sulfur in molybdenum sulfide clusters encaged in zeolite during hydrodeselenium reaction as studied by XAFS Original Research Article
Pages 331-334
Takeshi Kubota, Naoto Hosomi, Yuya Hamasaki, Yasuaki Okamoto

71 In-situ XAFS study of USY zeolite supported Pd-Pt catalysts under reduction and sulfidation conditions—Effect of Pt on structure of bimetallic Pd-Pt particles— Original Research Article
Pages 335-338
Kyoko K. Bando, Takashi Matsui, Lionel Le Bihan, Koichi Sato, Tomoaki Tanaka, Motoyasu Imamura, Nobuyuki Matsubayashi, Yuji Yoshimura

72 Effects of hydrogen pressure and H2/Oil ratio on deactivation of atmospheric residue hydrotreating catalysts at early process time Original Research Article
Pages 339-342
Hidehiro Higashi, Takeshige Takahashi, Takami Kai

73 Sonocatalytic desulfurization Original Research Article
Pages 343-346
Carlos E. Scottxe2, Jonathan R. Altafulla, Carmelo Bolivar, Caribay Urbina de Navarro

74 Adsorption of ethylamine on silica-supported nickel phosphide Original Research Article
Pages 347-350
S. Ted Oyama, Xianqin Wang, Rakesh Radhakrishnan

75 Controlling metal particle size in preparation of Pd/SiO2 catalysts Original Research Article
Pages 351-354
László Guczi, Anita Horváth, Andrea Beck, Antal Sárkány

76 Catalytic wet oxidation of dyehouse effluents with Cu/Al2O3 and Cu−Al pillared clay Original Research Article
Pages 355-358
Sung-Chul Kim, Dul-Sun Kim, Sang-Sin Oh, Dong-Keun Lee, Young-Kuk Yang

77 Catalytic liquid-phase oxidation by oxygen for purification of industrial wastewater Original Research Article
Pages 359-362
Marina Batygina, Nikolay Dobrynkin, Alexander Noskov

78 Probing into the surface chemistry of uranium oxides: The reactions of formic acid on UO2 (111) single crystal and polycrystalline surfaces Original Research Article
Pages 363-366
Sanjaya D. Senanayake, Shen V. Chong, Hicham Idriss

79 Microwaves assisted regeneration of catalytic filter for soot particulate Original Research Article
Pages 367-370
Paolo Ciambelli, Vincenzo Palma, Paola Russo, Matteo D'Amore

80 Adsorption structures and energetic of fluoro- and chlorofluorocarbons over faujasite—A first principle study Original Research Article
Pages 371-374
Abhijit Chatterjee, Takeo Ebina, Takashi Iwasaki

81 Gas-phase catalytic decomposition of mixtures of low-molecular-weight chlorinated VOCs Original Research Article
Pages 375-378
R. López-Fonseca, J.I. Gutiérrez-Ortiz, J.R. González-Velasco

82 Catalytic materials for the synthesis of hydrofluorocarbons Original Research Article
Pages 379-382
Valentina Giammetta, Rino Trabace, Ferruccio Trifiro, Paolo Cuzzato

83 Complete hydrodechlorination of chloro-aromatics catalyzed by Pd/TiO2 with H2 Original Research Article
Pages 383-386
Ichiro Yamanaka, Koji Nishikawa, Sakae Takenaka, Kiyoshi Otsuka

84 Oxide catalysts in indirect internal steam reforming of methane in SOFC Original Research Article
Pages 387-390
P. Aguiar, E. Ramírez-Cabrera, N. Laosiripojana, A. Atkinson, L.S. Kershenbaum, D. Chadwick

85 High selectivity preferential oxidation (PROX) catalysts for CO removal from hydrocarbon derived reformates for PEM fuel cells Original Research Article
Pages 391-394
E. Newson, T.B. Truong, N. De Silva, A. Fleury, R. Ijpelaar

86 Improving direct methanol fuel cell performance by using combinatorial electrochemistry and highly porous carbon support Original Research Article
Pages 395-398
Won Choon Choi, Yo Jin Kim, Seong Ihl Woo, Won Hi Hong

87 Removal of sulfur compounds from natural gas by adsorption on Ag-exchanged zeolites for PEFC Original Research Article
Pages 399-402
Shigeo Satokawa, Yuji Kobayashi, Hiroshi Fujiki

88 Skeletal isomerization of n-hexene: The influence of structure and acid distribution of molecular sieves Original Research Article
Pages 403-406
Mingfeng Li, Yang Chu, Hong Nie, Yahua Shi, Dadong Li

89 “Nebula”: A hydroprocessing catalyst with breakthrough activity Original Research Article
Pages 407-410
F.L. Plantenga, R. Cerfontain, S. Eijsbouts, F. van Houtert, G.H. Anderson, S. Miseo, S. Soled, K. Riley, K. Fujita, Y. Inoue

90 Catalytic combustion of 1,2-dichloroethane with hybrid catalysts composed of zeolite and Pt/Al2O3 Original Research Article
Pages 411-414
Wataru Kobayashi, Yukio Ito, Masao Nakano

91 Development of three-way catalyst using composite alumina-ceria-zirconia Original Research Article
Pages 415-418
Takaaki Kanazawa, Juji Suzuki, Toshihiro Takada, Tadashi Suzuki, Akira Morikawa, Akihiko Suda, Hideo Sobukawa, Masahiro Sugiura

92 New industrial process of PTMG catalyzed by solid acid supported on mesoporous material Original Research Article
Pages 419-422
Tohru Setoyama, Tooru Ookoshi, Izumi Ono, Mitsuharu Kobayashi, Yoshio Kabata, Tomohiro Kawai, Akio Nakanishi, Hiroshi Takeo

93 “Radical-controlled” oxidative polymerization of phenols Original Research Article
Pages 423-426
Hideyuki Higashimura, Kiyoshi Fujisawa, Yoshihiko Moro-oka, Masaaki Kubota, Akinobu Shiga, Hiroshi Uyama, Shiro Kobayashi

94 Influence of hydrogen supply on by-product formation during the hydrogenation of DNT to TDA Original Research Article
Pages 427-430
Jürgen G.E. Krauter, Michael Groß, Peter Panster

95 Unimodal porous spinel and its application to a new cataalyst material Original Research Article
Pages 431-434
Y. Okada, K. Imagawa, F. Yagi, S. Asaoka

96 Fast and efficient catalytic oxidation of n-hexane by aqueous H2O2 over TS-PQ™, a new titanium based silicate Original Research Article
Pages 435-438
Istvan Halasz, Mukesh Agarwal, Eric Senderov, Bonnie Marcus

97 A new vapour phase process to produce 2-hydroxyphenylalkylketones Original Research Article
Pages 439-442
Valerio Borzatta, Elisa Poluzzi, Angelo Vaccari