Reactivity of Solids

Front Matter....Pages i-xx
New Crystallographic Developments Applicable in Studies of Reactions in Solids....Pages 1-14
Reactions at Surfaces and Interfaces....Pages 15-42
Reaction Kinetics in the Ca-Mn-O System....Pages 43-48
Surface Reactivity Towards Olefin Oxidation of Cadmium Molybdate Doped with Transition Metal Ions....Pages 49-54
Chemisorption of Sulfur on Iron and Its Influence on Iron-Gas Reactions, Surface Self Diffusion and Sintering of Iron....Pages 55-61
The Influence of Intrinsic Defects on the Mechanism of the Solid State Reaction between CdTe and HgSe....Pages 63-68
Characterization and Surface Reactivity of Finely-Divided CoO-MgO Solid Solutions....Pages 69-76
The Reactivity of Some Tungsten Oxides....Pages 77-82
The Growth of Oxide Crystallites during the Oxidation of Iron in Carbon Dioxide within the Scanning Electron Microscope....Pages 83-88
The Reactivity of Metal Oxides and Sulfides with Lithium at 25°C — the Critical Role of Topotaxy....Pages 89-94
On the Reaction between Silver and Copper Iodide in Thin Evaporated Films....Pages 95-99
Oxygen Diffusion in Strontium Titanate Studied by Solid/Gas Isotope Exchange....Pages 101-106
Oxidation Behaviour of Zirconium Nitride in Oxygen....Pages 107-112
Oxidation Behaviour of Nickel Tellurides in the Composition Region Between NiTe 0.8 and NiTe 2.0 ....Pages 113-117
Reactions and Equilibrium Wetting in Titanium — Molten Glass Systems....Pages 119-123
Oxidation Kinetics Study of Finely Divided Magnetites Substituted for Aluminium and Chromium....Pages 125-129
Crystalline Solid Rearrangement Brought about by Gas Removal. Shape and Size of the Crystallites Obtained....Pages 131-136
Peroxide and Superoxide as Catalysts. a Model Based on Molten Salts Experiments....Pages 137-142
Carbon Formation on Ni Foils by Pyrolysis of Propene (290°–800°C)....Pages 143-147
Oxidation Reaction of Chromium Oxide (Cr 2 O 3 ) in the Presence of Mm’O 3 (M : Ca, Sr, Ba ; M’ : Ti, Zr)....Pages 149-153
Influence of a Foreign Gas in Heterogeneous Reactions....Pages 155-160
About the Use of a Solid State Electrochemical Oxygen Pump for Selective Oxidation of Organic Materials....Pages 161-166
On the High Temperature Reactivity in Air of Some Metal Powders and Their Relationship with the Self Sealing Coatings for the Protection of High-Temperature Metal Surfaces....Pages 167-170
Kinetic Aspects of Some Reactions between Metals and Gaseous Carbon Disulphide....Pages 171-176
Oxidation of Cobalt at High Temperatures and Self-Diffusion in Cobaltous Oxide....Pages 177-182
Cation Distribution in Spinel Solid Solutions and Correlations between Structural and Catalytic Properties....Pages 183-190
Thermal Decomposition of Mg-Al-Formate and Low Temperature Formation of Spinel Thereby....Pages 191-195
Reaction Between Cemented Carbides and Molten Copper....Pages 197-202
Kinetics of TiB Formation....Pages 203-207
Description of Solid-Gas Reactions. Conclusions of Thermoanalytical and Electron Optical Studies on Calcium Carbonate Thermal Decomposition....Pages 209-213
Dynamic Behaviour of Solid Surfaces....Pages 215-219
Nucleation Process in the Decomposition of Nickel Formate....Pages 221-226
Kinetic Study on the Phase Transformation of GeO 2 ....Pages 227-232
Kinetic Aspects on the Formation of Solid Solution....Pages 233-235
Influence of Structural Defects on the Reactivity of Solids....Pages 237-251
Studies on Non-Stoichiometric Strontium Ferrate, SrFeO 3-X ....Pages 253-259
Electron Microscopy of Ferroelectric Bismuthate Compounds....Pages 261-266
Some Observations on the Chemical Reactivity of Nickel Powder Mechanically Treated by Grinding....Pages 267-272
Defect Chemistry of La-Doped Barium Titanate....Pages 273-277
The Kinetic Processes of Equilibrium Restoration in La-Doped BaTiO 3 ....Pages 279-284
High Temperature Redox-Reactions of Co:α-Al 2 O 3 ....Pages 285-288
Structural Evolution in the FeF 3 -WO 3 System....Pages 289-295
Diffusion and Reactivity in Perovskite Materials of the Composition (Pb,La) (Zr,Ti)O 3 ....Pages 297-303
Formation of Large Defects in Neutron Irradiated Alkali Halide Crystals....Pages 305-310
Correlations between the Kinetics of Decomposition and the Crystal Structure for Some Inorganic Azide Single Crystals....Pages 311-317
Influence of $${P_{{O_2}}}$$ and $${P_{{H_2}}}_O$$ in the Atmosphere on the Rate of Changes in the System CaO-SiO 2 ....Pages 319-323
Autocatalytic Kinetics and Mechanism of the Reduction of Crystalline Cobalt Molybdate in hydrogen....Pages 325-329
An IR and EM Study of the Reactivity of Some Divalent Metal Hydroxides with Silica Gel....Pages 331-336
Unexpected Cases of Reactions between Solid Substances at Room Temperature and Normal Pressure. Four Different Examples....Pages 337-342
Dislocations and Their Role in the Thermal Dehydration of Ba(ClO 3 ) 2 ·H 2 O....Pages 343-347
New Insights on the Thermal Decomposition of Ammonium Perchlorate from Studies on Very Large Single Crystals....Pages 349-353
Trapping of Hydrogen by Structural Defects in α-Iron....Pages 355-360
Cation Diffusion, Point Defects and Reaction in the CoO-ß-Ga 2 O 3 System....Pages 361-366
The Texture and Heat Treatment of Hydrated Tin (IV) Oxides....Pages 367-372
Redox Processes of Manganese Ions Dispersed in Oxide Matrices....Pages 373-377
Studies by Electron Microscopy of the Reduction of MoO 3 ....Pages 379-383
Influence of Crystallographic, Magnetic Transformations and Structural Defects on the Reactivity of Simple and Combined Iron Oxides....Pages 385-389
Non-Quenchability of Some Transition-Metal Chalcogenides....Pages 391-396
About the Symmetry Lowering of Some Apatites as Evidenced by Their Infrared Spectrometric Study....Pages 397-401
Mechanism and Kinetics of Solid State Reaction in the System CuCr 2 O 4 — Cu 2 Cr 2 O 4 — CuO....Pages 403-407
Topotaxy and Solid-Gas Reactions....Pages 409-413
Microstrain and the Mechanism of the Reversible Monoclinic ⇌ Tetragonal Phase Transformation in Zirconia....Pages 415-419
Mechanical Damping of Ionic Crystals with Regard to MgO....Pages 421-425
Ferrite Formation Mechanism....Pages 427-432
Planar Defects and Reactivity of Perovskite-Like Compounds ABO 3+X : The Series (Na,Ca) n Nb n O 3n+2 (N > 4)....Pages 433-437
Electron Density Fluctuations at the Vicinity of the Surface Layers....Pages 439-442
Heterogeneous Ion-Exchange Reactions on Non-Stoichiometric Tungsten Oxide in Aqueous Media....Pages 443-448
Polymerization and Other Organic Reactions in the Crystalline State....Pages 449-456
Laser Induced Reactions in Doped Polymethylmethacrylate and Their Correlation with Results Obtained by X-Ray and UV Irradiation....Pages 457-474
Thermal Isomerisation of Cisazobenzene in the Solid State....Pages 475-479
Energy Transfer in the Solid State Photopolymerization of Diacetylenes....Pages 481-486
Solid-Gas Reactions. Part V. Bromination of Organic Solids....Pages 487-492
Mechanisms of Some Room Temperature Phosphorescence Phenomena in Doped Solid Polymer Matrices....Pages 493-497
Reactions in Vitreous Solids....Pages 499-503
Thermal Decomposition of Rhodium Oxide Gels....Pages 505-517
Polymerization Effects During the Crystallization of Silicate Glasses....Pages 519-524
The Use of Laser Raman Spectroscopy in the Study of the Formation of Oxide Glasses....Pages 525-527
Relations between Properties and Structural Evolution of Some Si, Ge, Sn Ternary Chalcogenides....Pages 529-534
High and Low Temperature Forms of Leucite....Pages 535-539
Desorption of Kr (or Kr 85 ) and SF 6 from Vitreous and Crystalline SiO 2 , and of Kr from B 2 O 3 and GeO 2 Glasses....Pages 541-545
Surface Crystallization in the SiO 2 -Al 2 O 3 -ZnO System by DTA....Pages 547-552
Some Recent Developments in the Investigation of Solid-State and Surface Reactions....Pages 553-558
The Investigation of Solid State Reactions with EPR....Pages 559-586
Computer Simulation of Crystal Dissolution....Pages 587-591
Study of the Initial Stage of the Oxidation Reaction of Pure Titanium and TA6V4 at High Temperature....Pages 593-598
Study of Oxygen Diffusion in Quartz by Activation Analysis....Pages 599-603
Theoretical Study of Simulated Dehydration of Crystal Silica Planes and Determination of Silica Gel Hydroxyl Distribution by NMR....Pages 605-609
Thermal Decomposition of Cobalt Oxalate....Pages 611-616
A Study of the Different Stages during Nickel Oxide Single Crystal Sulphurization by Hydrogen Sulfide....Pages 617-624
Oxygen Diffusion in NiO and ZnO....Pages 625-629
Sulfation Mechanism of CoO and NiO....Pages 631-634
High Resolution Electron Microscopy of Reacting Solids....Pages 635-639
The Electronic Structure of an Adsorbate Layer Studied by Angle Resolved Photoemission Spectroscopy....Pages 641-645
Thermal Decomposition of Alkaline Earth Chromates, Oxalates and Chromate-Oxalate Mixtures. The Ba, Sr, and Mg Compounds....Pages 647-651
High-Resolution Electron Microscopy Studies of Fluorite-Related Cerium Oxides....Pages 653-657
The Development of Simultaneous TA-MS for the Study of Complex Thermal Decomposition Reactions....Pages 659-662
The Status of Understanding Diffusion Controlled Solid State Sintering, Hot Pressing and Creep....Pages 663-668
Kinetic Study of the Reduction of Ni 2+ Ions in an X Type Zeolite....Pages 669-688
Development of Conductive Chains in RuO 2 -Glass Trick Film Resistors....Pages 689-694
Evaluation and Effects of Dispersion and Mixing Method of Reactant Particles on the Kinetics and Mechanism of Solid State Reactions....Pages 695-699
Carbothermal Reduction of Silica....Pages 701-705
Electrochemical Cells with Sulphate-Based Solid Electrolytes....Pages 707-711
Reversible Topotactic Redox Reactions of Layered Chalcogenides....Pages 713-718
Preparation and Properties of FeOC1-Pyridine Derivative Complexes and Their Reactivities with Methyl Alcohol....Pages 719-723
Formation and Properties of Some Subhalides of Tellurium....Pages 725-729
Thermal Studies on the Boron-Molybdenum Trioxide Pyrotechnic Delay System....Pages 731-735
The Kinetics of the Reaction between Magnesium Oxide and Iron (III) Oxide: The Effect of Sizes of Particles....Pages 737-741
Co-Precipitation of Metal Ions during Ferrous Hydroxide Gel Formation....Pages 743-748
Dehydration-Reduction Coupling Effects in the Transformation of Goethite to Magnetite....Pages 749-753
Steps in Low Temperature Dehydroxylation of Clay....Pages 755-759
Separation of Phases in Some Carbide Systems....Pages 761-765
Mass Transport by Self-Diffusion and Evaporation-Condensation in High Temperature Kinetic Processes in UO 2 .PuO 2 Nuclear Fuel....Pages 767-771
The Structural Degradation of Carbon Fibres in Nickel at Elevated Temperature....Pages 773-778
Solid State Reaction Studies on La 2 O 3 -NH 4 F and La(OH) 3 -NH 4 F....Pages 779-784
The Corrosion Resistance of Fe-Cr Alloys as Studied by ESCA....Pages 785-789
The Influence of Oxygen on the Current Potential Characteristics of Zn/- and Zno/Electrolyte Contacts....Pages 791-796
Back Matter....Pages 797-802
....Pages 803-810