Radicals Centered on Other Heteroatoms. Proton Transfer Equilibria

General introduction....Pages 1-1
10.0 Introduction....Pages 1-1
10.1 Boron centered radicals....Pages 2-11
10.2.1 Absolute reaction rates....Pages 12-28
10.2.2 Relative reaction rates....Pages 29-32
10.3 Phosphorus centered radicals....Pages 33-39
10.4.1.1 Self termination reactions....Pages 40-52
10.4.1.2 Fragmentation and rearrangement reactions....Pages 52-133
10.5 Chromium centered radicals....Pages 134-135
10.6 Manganese centered radicals....Pages 135-142
10.7 Iron centered radicals....Pages 143-143
10.8 Germanium centered radicals....Pages 144-155
10.9 Selenium centered radicals....Pages 155-158
10.10 Molybdenum centered radicals....Pages 158-160
10.11 Rhodium centered radicals....Pages 161-164
10.12 Tin centered radicals....Pages 164-177
10.13 Tungsten centered radicals....Pages 177-180
10.14 Rhenium centered radicals....Pages 180-202
References for 10....Pages 203-206
11.0 Introduction....Pages 207-213
11.1.1 Cation radicals by one-electron oxidation of hydrocarbons and derivatives: Deprotonation of CH-acids....Pages 214-248
11.1.2 Cation radicals by one-electron oxidation of hydrocarbons and related compounds: Formation of pseudo bases....Pages 248-253
11.1.3 Anion radicals by one-electron reduction of hydrocarbons and related compounds: C-protonation....Pages 253-258
11.1.4 Cation radicals by one-electron oxidation of ketones: Deprotonation of CH acids....Pages 258-260
11.1.5 Ketyl radicals....Pages 260-266
11.1.6 Semidione, semitrione, and related radicals....Pages 267-268
11.1.7 beta-Hydroxyalkyl radicals....Pages 268-268
11.1.8 alpha,beta-Dihydroxyalkyl and related radicals....Pages 269-271
11.1.9 Hydroxycyclohexadienyl radicals....Pages 271-278
11.1.10 Radicals from carboxylic acids....Pages 279-281
11.1.11 Radicals from esters....Pages 281-282
11.1.12 Radicals from amides and imides....Pages 282-283
11.1.14 Miscellaneous radicals....Pages 284-288
11.2 Oxyl and peroxyl radicals....Pages 288-289
11.3 Aroxyl and semiquinone radicals....Pages 290-315
11.4 Nitroxyl (aminoxyl) radicals....Pages 315-330
11.5 Nitrogen-centered radicals....Pages 330-349
11.6 Radicals by one-electron reduction of nitro compounds....Pages 349-355
11.7 Sulfur-centered radicals....Pages 356-362
11.8.1 Five-membered heterocycles....Pages 363-364
11.8.2.1 Pyridines....Pages 365-379
11.8.2.2 Diazines....Pages 380-384
11.8.2.3 Pyrimidine bases and related compounds....Pages 384-397
11.8.3.1 Indole and derivatives....Pages 398-405
11.8.3.2 10-Methylacridan and derivatives....Pages 405-415
11.8.3.3 Xanthene and derivatives....Pages 415-416
11.8.3.4 Phenothiazine and derivatives....Pages 417-419
11.8.3.5 Purine bases and related compounds....Pages 420-435
11.8.3.6 Pteridines and related compounds....Pages 435-435
11.8.3.7 Alloxazines....Pages 436-438
11.8.3.8 Flavins (Isoalloxazines)....Pages 438-444
11.8.3.9 Other condensed heterocycles....Pages 444-449
11.9 Radical ion pairs....Pages 450-462
11.10 Miscellaneous....Pages 462-464
References for 11....Pages 465-478
Remarks, TOCs of Vols. 13 and 18....Pages 1-8
I Organic and inorganic radicals....Pages 1-52
II Not completely identified e{-} and/or OH-adducts to compounds....Pages 1-3
III Radicals derived from polymers and from high molecular biological compounds....Pages 1-2
IV Biradicals....Pages 1-4
V Compounds with known redox potentials....Pages 1-4
VI Carbenes....Pages 1-3