Proceedings of the 8th International Conference on Coordination Chemistry: Vienna, 7.–11. September 1964

Front Matter....Pages N3-XV
Application of the Mössbauer-Effect in Coordination Chemistry....Pages 1-5
Investigations on the Electronic Structure of Transition Metal Complexes Using the Mössbauer Effect....Pages 5-8
Mössbauer Spectra of Iron Complexes with Thiosemicarbazone of Diacetyloxime and their Interpretation....Pages 8-11
The Mössbauer Effect and Chemical Theory....Pages 11-14
Raman Effect and Competitive Formation of Tetrahedral Mixed Halide Complexes by Ga 3+ in Solution....Pages 15-17
Determination of Constitution, Structure, and Bonding of Complex Ions in Solution by Raman Spectroscopy....Pages 17-21
Infrared Spectra and Metal-Ligand Force Constants in Coordination Compounds....Pages 21-25
Thermochemistry of some Transition-Metal Tetrahalocomplexes....Pages 25-29
Microcalorimetric Determination of the Enthalpy of Formation of the Complex Ions of Trivalent Plutonium, Americium and Lanthanium with EDTA....Pages 29-32
Thermochemistry of Some Adducts of Group III Elements....Pages 32-34
Some Calorimetric Measurements in Metal Complex Reactions....Pages 34-38
The Affinity of Cupric(Pyridine) Complex Towards a Fifth Ligand....Pages 38-40
Electron Paramagnetic Resonance of Certain Complex Combinations of Cu(II)....Pages 40-43
ESR Spectra of Cupric Complexes with Substituted Pyridines....Pages 43-46
Electron Paramagnetic Resonance Study of Ti(III) Chelate Complexes....Pages 46-49
Electron Transfer in Tris -2,2’ -Dipyridyl-Complexes as Studied by Electron Paramagnetic Resonance....Pages 49-52
Isotropic NMR Shifts in Paramagnetic Cobalt and Nickel Phosphine Complexes....Pages 52-57
Pure Quadrupole Resonance Studies on Hexahalorhenate(IV) and Hexachlorotungstate(IV)....Pages 57-60
PMR-Spektroskopische Untersuchungen an Aromat-Metall(O)-Tricarbonylen der VI. Nebengruppe....Pages 60-63
NMR Studies of Microscopic Sites of Protonation and Metal-Binding with Multidentate Complexing Agents....Pages 63-66
Das Valenzwinkelproblem in der Theorie der Spinvalenz....Pages 66-67
Optical Electronegativities....Pages 67-71
Spectra of Some Rh(III)- and Ir(III)-Complex Compounds....Pages 72-75
Dynamical Jahn-Teller Effects in d 4 Systems — Aqueous Manganese(III) and other Complexes of Mn(III) and Cr(III)....Pages 75-77
Observability of Splittings of Excited Energy Levels Caused by Spin-Orbit Coupling or Low Symmetry Components of the Core Field....Pages 77-81
Luminescence Spectra of Transition-Metal Complexes....Pages 81-83
Some Aspects of the Theory of Atom-Bridge Bonds....Pages 83-87
Polarized Crystal Spectra of Some Nickel(II)Cyanide Complexes....Pages 87-88
Spectra and Nature of Bonding in Metal -α -Diimine and Related Complexes....Pages 89-92
Chemical Structure Determination of Lantanides’ Coordination Compounds on the Basis of Their Absorption Spectra....Pages 92-95
Structure of a Synthetic Molecular Oxygen Carrier....Pages 95-97
Über Die Katalytische Wirksamkeit von Übergangsmetall-π-Allylverbindungen....Pages 98-99
Homogeneous Activation of Molecular Hydrogen by Four-, Five-, and Six-Coordinate Transition Metal Complexes....Pages 99-101
A New Method for the Determination of Circular Dichroism....Pages 101-103
Rotatory Strength and Absolute Configuration of Tris(Diamine) Transition Metal Complexes....Pages 103-107
Circular Dichroism of Cobalt(III) Complexes of Optically Active Amino Acids....Pages 107-109
The Electronic Spectra, Optical Rotatory Power, and Absolute Configuration of O-Phenanthroline and 2,2′-Dipyridyl Complexes....Pages 109-110
Optical Activity in Digonal Dihedral Transition Metal Complexes....Pages 110-111
Reaction Kinetics and Stereochemistry of Some Optically Active Transition Metal Complexes....Pages 111-114
The Crystal Structures of Some Mercuric Complexes....Pages 114-116
The Nature of Bonding in Some Pentacoordinated Molecules....Pages 116-120
Five Co -Ordination in Tin Compounds....Pages 120-121
Five Coordinate Compounds of Cobalt....Pages 122-123
The Influence of Steric and Electronic Effects Upon the Stereochemistry of Group VIII Metal Complexes....Pages 123-129
Distortions of Coordination Polyhedra....Pages 129-133
Electronic Structures of Square Planar Metal Complexes....Pages 133-135
Novel Stereochemical Effects in Certain Coordination Compounds....Pages 135-139
Stereo-Chemical Factors in Coordination Compounds of Nickel: Structure of Complex with Trimethylene Dinitramine....Pages 139-142
On Mutual Influence of Atoms and Groups in Complexes of Nitrosylruthenium....Pages 142-145
Decomposition of Substituted π-Allyl Palladium Halide Complexes....Pages 145-146
Complex Formation by Molybdenum(II)Chloride....Pages 146-147
Iodinetriammines and Tetrammines(CIS) of Pt(IV)....Pages 147-148
Metal-Metal Bonds in Complex Compounds....Pages 149-152
Compounds Containing Rhodium-Mercury, Osmium-Mercury or Iridium-Mercury Bonds....Pages 153-155
Crystal Structures of Some Compounds Containing Bonds between Dissimilar Metal Atoms....Pages 155-157
Platinum Complexes with Pt-Pt Interaction in Crystal and Solution....Pages 157-159
Macrocyclic Complexes of Germanium....Pages 160-161
Exchange of Molecular Parts between Coordination Compounds at Equilibrium....Pages 162-163
Zur Kristallchemie von Dimetatetrafluoroarsenaten; Einige Neuere Ergebnisse der Röntgenstrukturanalyse....Pages 163-166
Some New Adducts of Iodosilane....Pages 166-167
Coordination Chemistry of Organoheterosiloxanes and Related Compounds....Pages 168-170
Darstellung und Komplexchemisches Verhalten von Silylamiden Verschiedener Übergangsmetalle....Pages 171-173
Über Organofluorosilikate....Pages 173-176
Boron Hydride Fragments as Coordinating Ligands....Pages 177-178
Novel Coordination Compounds of Boron....Pages 178-180
Koordinations Verbindungen von Phosphino — und Amino-Boranen Sowie von Borazolderivaten....Pages 180-183
Reactions Between Nitriles and Some Organic Compounds of Boron and Aluminium....Pages 183-185
The Coordination Chemistry of Boron-Nitrogen Compounds....Pages 186-188
Some New Complexes of Rhenium....Pages 188-188
Dialkylaminofluorophosphines and Their Coordination Chemistry with Transition Metals....Pages 188-191
Transition Metal Complexes of Caged Phosphite Esters....Pages 191-193
Neueres Über P-Substituierte Schwermetallphosphide....Pages 193-196
Complexes of Xenon Hexafluoride....Pages 196-198
Coordination of Silicon and Germanium Tetrafluoride with Some Oxygen Donors....Pages 198-201
Neue Verbindungen mit der F 5 Te-Gruppe....Pages 201-202
The Preparation and Properties of Rare Earth Hexafluoroacetylacetonates....Pages 202-203
Multiply Bonded Oxo, Imido and Nitrido Complexes of Rhenium(V)....Pages 204-206
Some Novel Coordination Compounds of Group IV Metals....Pages 206-208
Some Complex Sulphur Compounds of Titanium and Vanadium....Pages 208-209
Hydrido and Carbonylhydridoiridium Compounds....Pages 210-214
The Preparation of Tris-2,2′-Bipyridyl-Iron(O) [Fe(bipy) 3- ]....Pages 214-217
Color and Variable Valence in Niobium and Tantalum Halides....Pages 217-218
Tetraphenylcyclobutadiene-Transition Metal Complexes....Pages 218-221
An Infrared and NMR Study of the Bonding between Olefins and Silver Ions....Pages 221-223
Olefin and Π-Allylic Complexes of Palladium, Platinum and Iridium....Pages 223-225
Π-Cyclopropenyl Derivatives of the Transition Metals....Pages 226-227
Biscyclopentadienyl Allyl Complexes of Titanium and Vanadium....Pages 227-228
Metalcomplexes of the Pentalene System....Pages 229-232
Π-Complexes with Biological Materials....Pages 232-234
Organic Radicals as Ligands....Pages 235-236
Recent Studies on Fulminate Complexes....Pages 236-239
Über Eine σ-Phenyl-Vanadin(II)-verbindung....Pages 240-242
Structures and Bonding of New Types of Transition Organometallic Complexes....Pages 242-244
The Reaction of Hexacarbonylvanadium with Aromatic Hydrocarbons....Pages 244-245
Novel Acetylene Tungsten Carbonyl Complexes....Pages 245-249
Bonding in some Novel Organometallic Complexes of the First and Second Row Transition Metal Ions....Pages 249-250
Donator-Akzeptor-Komplexe von Monosubstituierten Benzolen C 6 H 5 X mit Organischen Donatorverbindungen....Pages 250-252
Coordination Polymers....Pages 253-255
Polynuclear Carbonyls of Manganese, Technetium and Rhenium (1a)....Pages 255-257
Unusual Carbon Bridging Groups in Binuclear Complexes....Pages 257-258
Alkyne- Substituted Iron Carbonyls of Formula RC 2 R’Fe x (CO) y ....Pages 258-259
Sulfur-Containing Cobalt Carbonyl Derivatives....Pages 260-261
Thiocyanato Metal Carbonyls....Pages 262-264
New Organosulfur Derivatives of Metal Carbonyls....Pages 264-267
Electron Transfer Reactions Between Co(III), Rh(III) and Ir(III) Complexes and Cr(II) Through Bridging Groups....Pages 268-271
Electron Transfer Reactions of Pentacyanocobaltate(II)....Pages 271-274
Metal Coordination - A Key to Oxidative Stability.....Pages 274-278
Etude Polarographique des Solutions Aqueuses D’ Aquopentacyanoferrate(II)....Pages 279-284
The Lifetimes of Chloride Ion and Water Molecules in the First Coordination Sphere of Ferric Ion as Measured by Nuclear Magnetic Resonance....Pages 284-286
Some Recent Studies of Rapid Reactions of Metal Complexes in Aqueous Solution....Pages 286-289
Effect of Coordinated Ligands on the Kinetics of Substitution Reactions in Metal Complexes....Pages 289-292
Further Studies on the Kinetics and Mechanism of Hydrolysis of Co(III) Diacido Chelate Complexes....Pages 293-295
Kinetic Study of the Isotopic Exchange of EDTA Complexes of the Gallium Group Elements....Pages 295-298
The Aquation and Base Hydrolysis of Chlorobis(Ethylenediamine)Cobalt(III) Cations Containing Ammonia Derivatives as Orienting Ligands....Pages 298-300
Kinetics and Mechanism of Thermal Decomposition of Mn(III) Complex Oxalates in Solution....Pages 301-305
Metal Ion and Metal Chelate Catalysis of Salicyl Phosphate Hydrolysis....Pages 305-308
Catalytic Hydrogenation by Pentacyanocobaltate(II): π- and σ- Allylic Complex Intermediates....Pages 308-312
Kinetic Studies of Some Rh(III) Complexes....Pages 313-315
Hard and Soft Acids and Bases....Pages 315-320
Interaction of Lewis Acids with Transition Metal Complexes....Pages 320-322
The Nature of Solutions of Transition Metal Salts of Very Strong Acids in Non-Aqueous Solvents....Pages 322-324
Auto-Coordination in Solid Phosphorylchloride....Pages 325-327
The Crystal Structures of Some Solvates of Seleninyldichloride....Pages 328-330
Coordination Problems of Nitrogen-Iodine-Compounds in Liquid Ammonia....Pages 330-332
Calorimetric Titrations for the Study of Stepwise Equilibria in Solutions....Pages 332-334
Bestimmung der Bildungskonstanten und Reaktionsenthalpien Mehrstufiger Komplexbildungs — Gleichgewichte Durch Thermometrische Titration....Pages 334-338
Configurational Equilibria of Some Transition Metal Complexes in Solution....Pages 338-340
The Relative Stability of Octahedral and Tetrahedral Complexes of Transition Metal Ions....Pages 340-343
Formation and Stability of Mixed and Polynuclear Complexes in Non-Aqueous Solutions....Pages 343-345
The Formation of Metal Complexes in Solution....Pages 345-349
Iron(III) and Proton Associations with Some Singly Substituted Phenolate Ions in Aqueous Solution....Pages 349-353
Stability of Some Metal Complexes Containing Oxygen, Sulfur, or Selenium as Donor Atoms....Pages 353-357
Stabilitäts- und Dissoziationskonstanten Einiger o-Diphenol -Germanium-Verbindungen....Pages 357-360
Stepwise Formation of Metal Complexes in Non-Aqueous Solvents....Pages 360-362
Methoxide Complexes of Metal Ions in Methanol....Pages 362-364
Coordination Chemistry of Sulphur Trioxide with Oxygen Bases....Pages 364-366
Metal Complexes of Thio-Derivatives of β-Diketones....Pages 366-369
Co-Ordination Chemistry of Metal Complexes of Salicylideneimines and β-Ketoimines....Pages 370-373
Glycine Derivatives of the Quadrivalent Platinum....Pages 373-375
Selenium and Sulfur Analogs of 8-Quinolinol and Their Metal Chelates....Pages 375-379
An Investigation on some Sulphato Complexes in Aqueous Solution with Infrared Spectroscopy....Pages 379-382
The Use of NMR for the Study of Metal Chelates in Aqueous Solution....Pages 383-384
Nuclear Resonance Studies of Structural Equilibria in Solutions of Nickel(II) Complexes....Pages 385-386
The Nature of Molybdic Acid in Perchlorid Acid Medium....Pages 386-388
Study of the Complex Formation with Rare Metals by the High Frequency Method....Pages 388-391
Isomerism and Reduction Products of the Molybdic Heteropolyacids....Pages 391-393
The Nature of the Halide Complexes of Fe(III), Co(II), Ga(III) and In(III) Extracted from Aqueous Chloride Media by High Molecular Weight Substituted Alkyl Ammonium Compounds....Pages 394-396
Di-Coordinate Anion Complexes of Hydrogen....Pages 396-399
Halide Complexes of Ions with Electronic Structures 4d 10 5s 2 and 5d 10 6s 2 ....Pages 399-402
Complex Formation in Tertiary Amine Extraction of Trivalent Metals....Pages 403-405
Extraction Species of Niobium and Tantalum with Some Novel Extracting Agents....Pages 406-407
The Coordination Behavior of Co, Ni, Cu and Zn in a Chelating Ion-Exchange Resin (1)....Pages 407-409
Zur Magnetochemie des Systems Fe/Porphyrin/Protein....Pages 410-415
A Comparison Between the Reactivity of Iron in Ferrymyoglobin and Cobalt in Some Vitamin B 12 Derivatives....Pages 415-417
Structures and Reactivities of Complexes Between Bivalent Cations and Nucleotides....Pages 418-421
N,N-Dimethylacetamide (DMA) Complexes of Uranium (IV) Mixed Halides....Pages 422-423
On the Complex Phosphates of Some Rare Metals....Pages 424-426
Kinetics and Mechanism of Nucleophilic Substitution in an Acido-Pentammine-Cobalt(III) Complex in Aqueous Solution....Pages 426-426
Unusual Stabilities of the Pyruvate-Glycinate Mixed Complexes with Some Divalent Metal Ions....Pages 427-429
Trans-Configuration in Dimethyltin and Dimethyllead Bis(Acetylacetonates)....Pages 429-432
Some Recent Results on the Hydrolysis Equilibria of Metal Ions....Pages 432-434
Chloro-Complexes of Pentavalent Niobium, Tantalum, Protactinium, Tungsten and Uranium....Pages 434-437
Possible Kinetic Consequences of Entropy Correspondence....Pages 437-439
Back Matter....Pages 439-444
....Pages 445-449