Polymer Electrolytes for Energy Storage Devices

Cover
Half Title
Title Page
Copyright Page
Dedication Page
Table of Contents
Foreword
Editors
Contributors
Abbreviations
Chapter 1 Electrochemical Energy Storage Systems: The State-of-the-Art Energy Technologies
	1.1 Introduction
	1.2 Types of Electrochemical Energy Storage Devices
	1.3 Batteries and Their Classification
		1.3.1 Primary (Non-Rechargeable) Batteries
			1.3.1.1 Types of Primary Batteries
		1.3.2 Secondary (Rechargeable) Batteries
			1.3.2.1 Lead-Acid Batteries
			1.3.2.2 Nickel-Cadmium Batteries
			1.3.2.3 Ni-Metal Hydride Batteries
			1.3.2.4 Lithium-Ion Batteries
			1.3.2.5 Magnesium-Ion Batteries
			1.3.2.6 Fluoride-Ion Batteries
			1.3.2.7 Sodium-Ion Batteries
			1.3.2.8 Ion-Ion Batteries
	1.4 Principles and Types of Lithium-Ion Batteries
		1.4.1 Lithium Iodide Battery
		1.4.2 Lithium Air Battery
		1.4.3 Lithium Redox Flow Battery
		1.4.4 Lithium Sulfur Battery
	1.5 Supercapacitors
	1.6 Fuel Cells
		1.6.1 Basic Structure of Fuel Cell
		1.6.2 Classification of Fuel Cells
			1.6.2.1 Polymeric Electrolyte Membrane Fuel Cells (PEMFC
			1.6.2.2 Direct Methanol Fuel Cells (DMFCs
			1.6.2.3 Alkaline Fuel Cells (AFCs
			1.6.2.4 Phosphoric Acid Fuel Cell (PAFC
			1.6.2.5 Molten Carbonate Fuel Cells (MCFC
			1.6.2.6 Microbial Fuel Cells (MFC
	1.7 Conclusion
	Acknowledgment
	References
Chapter 2 The Great Nobel Prize History of Lithium-Ion Batteries: The New Era of Electrochemical Energy Storage Solutions
	2.1 Introduction
	2.2 Development of Energy Storage Devices
	2.3 Classification of Batteries
	2.4 History of Lithium-Ion Batteries
	2.5 Structure of Lithium-Ion Batteries
	2.6 Principle of Lithium-Ion Batteries
	2.7 Other Types of Battery Based on Lithium-Ion Technology
	2.8 Challenges of Next-generation Lithium-Ion Batteries
	2.9 The Nobel Prize: The New Era of Lithium-Ion Batteries
		2.9.1 Prof. John Bannister Goodenough
		2.9.2 Prof. Michael Stanley Whittingham
		2.9.3 Prof. Akira Yoshino
	2.10 The Draper Prize and Lithium-Ion Battery (2014
		2.10.1 Prof. Rachid Yazami
		2.10.2 Mr. Yoshio Nishi
	2.11 Summary
	Acknowledgment
	References
Chapter 3 Polyethylene Oxide (PEO)-Based Solid Polymer Electrolytes for Rechargeable Lithium-Ion Batteries
	3.1 Introduction
	3.2 Preparation of PEO-Based Solid Polymer Electrolytes
	3.3 Copolymer-Based PEO Solid Polymer Electrolytes
	3.4 Conclusions
	Acknowledgment
	References
Chapter 4 Polymer Nanocomposite-Based Solid Electrolytes for Lithium-Ion Batteries
	4.1 Introduction
	4.2 Active Ceramic Filler-Based PNSEs
		4.2.1 Garnet-Type Ceramic Fillers for PNSEs
		4.2.2 NASICON-Type Ceramic Fillers for PNSEs
		4.2.3 Perovskite-Type Ceramic Fillers for PNSEs
		4.2.4 Anti-Perovskite-Type Ceramic Fillers for PNSEs
		4.2.5 Sulfide-Type Ceramic Fillers for PNSEs
	4.3 Inactive Ceramic Oxide-Based PNSEs
	4.4 Metal-Organic Frameworks (MOFs) as Fillers for PNSEs
	4.5 Biopolymers as Fillers for PNSEs
		4.5.1 Cellulose
		4.5.2 Chitosan
		4.5.3 Proteins
		4.5.4 Starch
	4.6 Conclusions and Future Perspectives
	References
Chapter 5 Poly(Vinylidene Fluoride) (PVdF)-Based Polymer Electrolytes for Lithium-Ion Batteries
	5.1 Introduction
	5.2 Structure and Ionic Interactions with Lithium Ions
	5.3 Methods of Preparation of PVdF-Based Electrolytes
		5.3.1 Solvent Casting
		5.3.2 Phase Inversion
		5.3.3 Electrospinning
	5.4 Conclusion
	Acknowledgment
	References
Chapter 6 Poly(Vinylidene Fluoride-co-Hexafluoropropylene) (PVdF-co-HFP)-Based Gel Polymer Electrolyte for Lithium-Ion Batteries
	6.1 Introduction
		6.1.1 Crystal Phases of PVdF-co-HFP
	6.2 Preparation of PVdF-co-HFP-Based Polymer Electrolytes
		6.2.1 PVdF-co-HFP-Based Electrolytes Prepared by Solution Casting
			6.2.1.1 Pure PVdF-co-HFP-Based Polymer Electrolytes
			6.2.1.2 PVdF-co-HFP-Based Polymer Blend Electrolytes
			6.2.1.3 PVdF-co-HFP-Based Ceramic Filler Composite
 Polymer Electrolytes
		6.2.2 Preparation of PVdF-co-HFP-Based Polymer Electrolytes by
 Phase Inversion
			6.2.2.1 Pure PVdF-co-HFP-Based Polymer Electrolytes
			6.2.2.2 PVdF-co-HFP-Based Polymer Blend Electrolytes
			6.2.2.3 PVdF-co-HFP Ceramic Composite Electrolytes
		6.2.3 PVdF-co-HFP-Based Polymer Electrolytes Prepared by
 Electrospinning
	6.3 Conclusion
	Acknowledgment
	References
Chapter 7 Polyacrylonitrile (PAN)-Based Polymer Electrolyte for Lithium-Ion Batteries
	7.1 Introduction
	7.2 Mechanism of Ionic Conductivity in Polyacrylonitrile-Based Polymer
 Electrolytes
	7.3 Methods of Preparation of Polyacrylonitrile-Based Polymer Electrolytes
		7.3.1 Polyacrylonitrile-Based Gel Polymer Electrolytes Prepared by
 Solvent Casting
		7.3.2 Polyacrylonitrile-Based Polymer Electrolytes Prepared by Phase
 Inversion
		7.3.3 Polyacrylonitrile-Based Polymer Electrolytes Prepared by
 Electrospinning
	7.4 Polyacrylonitrile-Based Polymer Blend Electrolytes
	7.5 Polyacrylonitrile-Based Ceramic Composite Polymer Electrolytes
	7.6 Conclusion
	Acknowledgment
	References
Chapter 8 Polymer Blend Electrolytes for High-Performance Lithium-Ion Batteries
	8.1 Introduction
	8.2 Polymer Blend Electrolytes
		8.2.1 PVdF and PVdF-co-HFP-Based Polymer Blend Electrolytes
		8.2.2 Polymethyl Methacrylate (PMMA Based) Polymer Blend
 Electrolytes
			8.2.2.1 Polymethyl Methacrylate (PMMA Based) Polymer
 Blend Electrolytes by Solvent Casting
			8.2.2.2 Polymethyl Methacrylate (PMMA Based) Polymer
 Blend Electrolytes by Phase Inversion
			8.2.2.3 PMMA Based Polymer Blend Electrolytes by
 Electrospinning
		8.2.3 Polyethylene Oxide (PEO Based) Polymer Blend Electrolytes
			8.2.3.1 Polyethylene Oxide (PEO)-Based Polymer Blend
 Electrolytes by Phase Inversion
			8.2.3.2 Polyethylene Oxide (PEO Based) Polymer Blend
 Electrolytes by Electrospinning
		8.2.4 Polyvinyl Chloride (PVC Based) Polymer Blend Electrolytes
			8.2.4.1 Polyvinyl Chloride (PVC Based) Polymer Blend
 Electrolyte by Solvent Casting
			8.2.4.2 Polyvinyl Chloride (PVC Based) Polymer Blend
 Electrolyte by Electrospinning
	8.3 Conclusion
	Acknowledgment
	References
Chapter 9 Polymer Clay Nanocomposite Electrolytes for Lithium-Ion Batteries
	9.1 Introduction
	9.2 Ion Transport in Polymer/Clay Nanocomposites
	9.3 Polyvinylidene Difluoride (PVdF)-Clay Composite Polymer Electrolytes
	9.4 PVdF-co-HFP/Clay Composite Polymer Electrolytes
	9.5 Polyacrylonitrile/Clay Composite Polymer Electrolytes
	9.6 Polymethyl Methacrylate/Clay Composite Polymer Electrolytes
	9.7 Conclusion
	Acknowledgment
	References
Chapter 10 Polymer Silica Nanocomposite Gel Electrolytes for Lithium-Ion Batteries
	10.1 Lithium-Ion Batteries (LIB): A Brief Introduction
	10.2 Gel Polymer Electrolytes for Lithium-Ion Batteries
	10.3 Silica-Based Gel Polymer Electrolytes for Lithium-Ion Batteries
		10.3.1 Fumed Silica-Based Gel Polymer Electrolytes
		10.3.2 Nanosilica-Based Gel Polymer Electrolytes
		10.3.3 In-Situ-Generated Silica-Based Gel Polymer Electrolytes
		10.3.4 Surface-Modified (Functionalized) Silica-Based Gel Polymer
 Electrolytes
	10.4 Conclusion
	Acknowledgment
	References
Chapter 11 Polymer-Ionic Liquid Gel Electrolytes for Lithium-Ion Batteries
	11.1 Introduction
	11.2 Properties of Polymer-Ionic Liquid Gel Electrolytes (PILGEs
	11.3 Types of Polymer-Ionic Liquid Gel Electrolytes (PILGEs
	11.4 Conclusion and Future Perspectives
	References
Chapter 12 Biopolymer Electrolytes for Energy Storage Applications
	12.1 Introduction
	12.2 Polymer Electrolytes and Their Classifications
		12.2.1 Solvent-Free Polymer Salt Complexes
		12.2.2 Polyelectrolytes
		12.2.3 Gel Polymer Electrolytes
		12.2.4 Composite Polymer Electrolytes
	12.3 Characteristics of the Polymer Electrolyte
	12.4 Biopolymer-Based Polymer Electrolytes and Their Properties
		12.4.1 Chitosan-Based Polymer Electrolytes
		12.4.2 Starch-Based Polymer Electrolytes
		12.4.3 Carrageenan-Based Polymer Electrolytes
	12.5 Biopolymer-Based Electrolytes in Lithium Batteries
	12.6 Biopolymer-Based Electrolytes for Supercapacitors
	12.7 Biopolymer-Based Electrolytes for Fuel Cells
	12.8 Conclusion
	References
Index