Platinum Group Metals and Compounds

Title......Page 1
Copyright......Page 2
Series Information......Page 3
FOREWORD......Page 4
PREFACE......Page 5
1 Magnetic Properties of the Platinum Metals and Their Alloys......Page 6
Local Moments......Page 9
Ordered Alloys......Page 12
Platinum Metal—Rare Earth Alloys......Page 18
Literature Cited......Page 21
2 Platinum Metal Chalcogenides......Page 22
Literature Cited......Page 31
3 Synthesis and Crystal Chemistry of Some New Complex Palladium Oxides......Page 33
Results......Page 34
Sr2PdO3......Page 36
SrPd304 , CaPd304 , and CdPd304......Page 39
Literature Cited......Page 42
4 Reaction of Platinum Dioxide with Some Metal Oxides......Page 44
Equipment and Procedure......Page 45
a-Pt02......Page 46
b-Pt02......Page 48
Pb02......Page 51
Rare Earth Sesquioxides......Page 52
Smaller Trivalent Ions......Page 53
M2Pt04  Compounds......Page 54
MPt306  Compounds......Page 56
Literature Cited......Page 58
5 Nitrido Complexes of the Platinum Group Metals......Page 59
Terminal Osmium Nitrido Complexes......Page 60
Anionic Complexes......Page 61
Cationic Complexes......Page 62
Vibrational Spectra......Page 64
Electronic Spectra......Page 66
Trinuclear Osmium Complex......Page 67
Trinuclear Iridium Complexes......Page 68
Comparison of the Vibrational Spectra of Oxy and Nitrido Complexes......Page 69
Literature Cited......Page 70
6 Hydrido Complexes of Platinum Group Metals......Page 71
Literature Cite......Page 77
7 Ultraviolet Spectroscopic Qualities of Platinum Group Compounds......Page 79
Spectra of Hexahalo-Complexes in Aqueous Solutions......Page 80
Spectrum of PtCl42......Page 86
Effects of Reduction in Symmetry......Page 92
Spectra in Organic Media......Page 94
Spectrum of Dichlorο (ethylene diamine) platinum (II). Evidence for Metal—Metal Interactions......Page 97
Direction of Current Research......Page 99
Literature C......Page 101
8 NM R Spectra of Compounds of the Platinum Group Metals......Page 103
Bonding Problems......Page 104
Stereochemistry......Page 110
Solvation and Solvent Effects......Page 114
Dynamic Systems......Page 117
Summary......Page 122
Literature Cited......Page 123
9 Crystal Structures of Complexes of the Platinum Group Metals......Page 125
02 Adducts......Page 126
S02  and CS2  Adducts......Page 128
Stereochemistry and Bond Lengths in Pt(II) Complexes......Page 129
Structures of Delocalized π-Systems Involving Pt Metals......Page 134
Literature Cited......Page 137
10 195Pt—A Survey of Mossbauer Spectroscopy......Page 140
The 99 keV State......Page 142
Lattice Dynamics......Page 143
Hyperfine Interaction......Page 148
Debye Temperatures for Platinum in Pt, Be, Cu, and Ir......Page 151
Isomeric Shift......Page 152
Literature Cited......Page 153
Double Bond Migra......Page 155
Selectivity Among Olefinic Types......Page 156
Migration to Inaccessible Positions......Page 157
Changes in the Organic Function......Page 158
Catalyst Inhibition......Page 159
Hydrogenolysis of Carbon-Carbon Bonds......Page 160
Disproportionation......Page 161
Stereochemistry......Page 162
Partial Hydrogénation of Aromatic Rings......Page 163
Reductive Coupling......Page 164
Partial Reduction to Ketones......Page 165
Literature Cited......Page 166
INDEX......Page 168