Photochemistry and Photophysics of Coordination Compounds

Front Matter....Pages I-XI
Front Matter....Pages 1-1
Polarized Luminescence of (Pt(CN) 2 bipy) Single Crystals-Magnetic Field and Temperature Effects....Pages 3-7
Light-Induced Excited Spin State Trapping in Iron(II) Complexes....Pages 9-15
Infrared Luminescence Spectroscopy of V 3+ Doped Cs 2 NaYX 6 (X=C1,Br)....Pages 17-20
Recent Progress in Uranyl Photo-Physics....Pages 21-24
Effects of Macrocyclic and Cryptand Ligands on Photophysics of Eu 3+ Ions....Pages 25-28
Front Matter....Pages 29-29
Ligand Field Analysis of the Doublet Excited States in Chromium(III) Trischelated Complexes....Pages 31-34
Quenching of Three Photoaquation Modes of a Chromium(III) Acidoammine....Pages 35-38
Stereochemical Constraints on the Excited State Behavior of Chromium(III)....Pages 39-42
Excited State Behavior as a Probe of Ground-State Ion-Pair Interactions in Chromium(III)-Polypyridyl Complexes....Pages 43-47
Counterion Effects on Doublet Splittings of Chromium(III) Complexes....Pages 49-54
Spectrum-Structure Correlations in Hexacoordinated Transition Metal Complexes....Pages 55-60
Multiphoton-Induced Picosecond Photophysics of Chromium(III)- Polypyridyl Complexes....Pages 61-67
Front Matter....Pages 69-69
On the Orbital Nature of the Luminescent Excited State of Orthometalated Transition Metal Complexes....Pages 71-77
Correlations Between Optical and Electrochemical Properties of RU(II)- Polypyridine Complexes: Influence of the Ligand Structure....Pages 79-83
Towards a Dynamic Model for the RU(BPY) 3 2+ System....Pages 85-91
Broad-Band Emission and Zero-Phonon Lines of Single-Crystal [Ru(bpy) 3 ] (PF 6 ) 2 - A Comparison....Pages 93-100
Magnetic-Field Effects and Highly Resolved Vibronic Structure of [Ru(bpy) 3 ] 2+ ....Pages 101-106
Highly Resolved Optical Spectra of [Os(bpy) 3 ] 2+ Doped into [Ru(bpy) 3 ]X 2 ....Pages 107-112
Excited State Behaviors of Ruthenium(II) Complexes as Studied by Time Resolved and Temperature and Solvent Dependent Emission Spectra....Pages 113-118
The Lowest Excited States of (Ru(2,2’-bipyrazine) (2,2’-bipyridine) 2 ) 2+ ....Pages 119-124
Front Matter....Pages 69-69
Quenching of Excited $$\\text{R}\\text{u} (\\text{b}\\text{p}\\text{y})_3^{2+}$$ with Methylviologen at Low Temperatures....Pages 125-128
Kinetics of the Chemiluminescent Oxidation of Aqueous Br - by $${\\text{R}\\text{u} (\\text{b}\\text{i}\\text{p}\\text{y}\\text{r})_3}^{3+}$$ ....Pages 129-133
Synthesis and Photophysical Studies of Ortho-Metalated Pd(II) Complexes Including two Novel Pd(II)/Rh(III) Dimers....Pages 135-140
Photoproperties of Ortho-Metalated Ir(III) and Rh(III) Complexes....Pages 141-146
Ground and Excited State Interactions in Multimetal Systems....Pages 147-150
Photophysical and Photochemical Properties of Ruthenium(II) Mixed-Ligand Complexes: Precursors to Homonuclear and Heteronuclear Multimetal Complexes Containing Ruthenium(II), Platinum(II), Rhenium(I) and Rhodium(III)....Pages 151-158
Ground- and Excited-State Acid-Base Equilibria of (2,2’-Bipyridine)Tetracyanoruthenate(II)....Pages 159-164
Front Matter....Pages 165-165
Kinetics and Mechanism of Photochemical Formation of a Pyrazine Bridged Fe(II) Protoporphyrin Polymeric Compound....Pages 167-170
Charge-Transfer States and Two-Photon Photochemistry of $${\\text{C}\\text{u} (\\text{N}\\text{N})_2}^+$$ Systems....Pages 171-176
Photoinduced Multielectron Redox Reactions in the (PtC1 6 ) 2- /Alcohol System: Visible Light Reduction of Platinum Centers....Pages 177-180
Dynamic and Static Outer-Sphere and Inner-Sphere Quenching Processes....Pages 181-184
Photochemistry and Spectroscopy of Ion Pair Charge Transfer Compounds....Pages 185-188
Backward Electron Transfer within Geminate Radical Pair Formed in the Electron Transfer Quenching....Pages 189-191
Photochemistry of Copper Complexes and Its Catalytic Aspects....Pages 193-196
Intramolecular Excited State Electron Transfer from Naphthalene to Cobalt(III)....Pages 197-203
Photochemistry of Coordination Compounds of Main Group Metals. Reductive Elimination of Thallium(III) Complexes....Pages 205-209
Front Matter....Pages 211-211
Photophysics and Photochemistry of Tungsten Carbyne Complexes....Pages 213-216
The Photoisomerization and Photosubstitution Reactions of the Ruthenium Cluster HRu 3 (Co) 10 (μ-Coch 3 )....Pages 217-220
Multiple Emission from (η 5- C 5 H 5 (Re(CO) 2 L (L = A Substituted Pyridine) Complexes in Room-Temperature Solution....Pages 221-224
Photochemically Induced C-C-Bond Formation in the Coordination Sphere of Transition Metals....Pages 225-230
Front Matter....Pages 211-211
Triplet Quenching by Metal Carbonyls....Pages 231-234
Photoexcitation of W(CO) 6 Solutions Containing α-Diimine Ligands. Kinetics and Mechanism of Chelation for a Series of Photoproduced W(CO) 5 (α-Diimine) Intermediates....Pages 235-238
Kinetics and Mechanism of C-H Activation Following Photoexcitation of (η 5 -C 5 H 5 ) Ir(CO) 2 in Hydrocarbon Solutions....Pages 239-242
Identification of H 2 -, D 2 -, N 2 - Bonded Intermediates in the Cr(CO) 6 Photocatalyzed Hydrogenation Reactions....Pages 243-246
Spectroscopy and Photochemistry of Ni(CO) 2 (α-Diimine) Complexes....Pages 247-252
Fe(CO) 3 (R-DAB), a Complex with Two Close-Lying Reactive Excited States....Pages 253-258
The Photocatalytic Metathesis Reaction of Olefins....Pages 259-262
Photochemical Generation of Nineteen-Electron Organometallic Complexes and their Use as Reducing Agents in Micellar Systems....Pages 263-266
Probing Organometallic Photochemical Mechanisms with Quinones: Photolysis of Mn 2 (Co) 10 ....Pages 267-270
Laser Flash Photolysis of Phosphine-Substituted Dimanganese Carbonyl Compounds....Pages 271-274
Front Matter....Pages 275-275
Electron Trapping in Colloidal TiO2 Photocatalysts: 20 ps to 10 ns Kinetics....Pages 277-283
The Radiation Sensitivity of Select Metal Chelate Polymers: Mechanistic Changes at Higher Energies....Pages 285-290
Temperature Dependent Emission of Copper Porphyrins in Liquid Solution....Pages 291-294
Pressure Effects on Nonradiative Deactivation from Metal Complex Excited States in Solution....Pages 295-300
Heterogeneous Photocatalysis by Metal Sulfide Semiconductors....Pages 301-306
Inorganic Photoinitiators for Photolithographic Applications....Pages 307-312
Photochemical Behaviour of Luminescent Dyes in Sol-Gel and Boric Acid Glasses....Pages 313-316
Industrial Applications of Organometallic Photochemistry....Pages 317-322
Synthesis and Characterization of A μ-oxo-diruthenium Complex as a Precursor to an Efficient Water Oxidation Catalyst....Pages 323-326
The Application of Diffuse Reflectance Laser Flash Photolysis to Metal Phthalocyanines in an Opaque Environment....Pages 327-330
Front Matter....Pages 275-275
Quenching of Singlet Oxygen by Cobalt Complexes....Pages 331-333
Recent Advances in Inorganic and Organometallic Photolithography....Pages 335-338
Back Matter....Pages 339-343