Photocatalytic Production of Energy-Rich Compounds. Energy from Biomass 2

BOOK COVER......Page 1
HALF-TITLE......Page 2
TITLE......Page 4
COPYRIGHT......Page 5
PREFACE......Page 6
2nd EEC Workshop on Photochemical and Photobiological Processes for Producing Energy Rich Compounds Seville, Spain; September 22nd-25th, 1987......Page 7
CONTENTS......Page 8
INTRODUCTION......Page 12
STABILISATION OF Si PHOTOANODES BY SiON COATINGS......Page 13
ATTEMPTED SYNTHESIS OF BINUCLEAR Co COMPLEXES FOR (PHOTO)-ELECTROCHEMICAL REDUCTION OF CO2......Page 14
REFERENCES......Page 17
INTRODUCTION......Page 19
Outstanding problems......Page 20
TECHNIQUES......Page 21
The light harvesting complex LHC2......Page 22
Reaction centres of Photosystem 2......Page 23
REFERENCES......Page 26
INTRODUCTION......Page 27
PHOTOSYSTEM-I REACTION CENTER......Page 28
PHOTOSYSTEM-II REACTION CENTER: COUPLING WITH THE ANTENNA......Page 30
REFERENCES......Page 31
INTRODUCTION......Page 33
MATERIALS AND METHODS......Page 34
RESULTS AND DISCUSSION......Page 36
ACKNOWLEDGEMENTS......Page 41
REFERENCES......Page 43
1. Introduction.......Page 44
2. New Photosensitizers: Isocyanide Bipyridine Mixed-ligand Ruthenium(II) complexes.......Page 45
3. Cyano-bridged Supramolecular Systems Containing the Ru(bpy)22+ Photosensitizer Unit.......Page 46
3.1. Intramolecular Electron Transfer.......Page 47
3.2. Intramolecular Energy Transfer.......Page 49
REFERENCES......Page 50
INTRODUCTION......Page 52
RESULTS AND DISCUSSION......Page 54
REFERENCES......Page 58
INTRODUCTION......Page 60
RESULTS AND DISCUSSION......Page 61
REFERENCES......Page 65
INTRODUCTION......Page 68
REACTIONS OF TiO2 SURFACES WITH FERROCYANIDE IONS......Page 70
PHOTOCHEMICAL BEHAVIOR OF TiO2 SURFACES DERIVATIZED WITH FERROCYANIDE......Page 71
DERIVATIZATION OF TiO2 SURFACES WITH METAL CYANIDES......Page 72
ACKNOWLEDGMENT......Page 73
REFERENCES......Page 74
INTRODUCTION......Page 77
RESULTS......Page 78
REFERENCES......Page 80
2. MONO- AND MULTILAYERS FROM PREPOLYMERIZED AMPHIPHILES......Page 81
3.1. Photoreactions of the Benzvlammoniumsalts......Page 82
3.2. Amphiphilic quarternary Benzylammoniumsalts......Page 83
3.3. LB- Multilayers from prepolymerized Benzylammoniumamphiphiles......Page 85
3.4. Photoreaction of Benzylammoniumsalts in LB -Multilayers......Page 86
REFERENCES......Page 87
EXPERIMENTAL......Page 91
RESULTS......Page 92
DISCUSSION......Page 93
REFERENCES......Page 96
1.1.- Literature......Page 97
1.3.- Some mechanistics considerations......Page 99
EARLY RESULTS AND THEIR INTERPRETATION......Page 100
REFERENCES......Page 103
INTRODUCTION......Page 105
THE Ru(II)-POLYPYRIDINE FAMILY......Page 106
THE Co(sep)3+ COMPLEX......Page 107
CONCLUSIONS......Page 108
REFERENCES......Page 109
INTRODUCTION......Page 110
1. Adduct formation.......Page 111
2. CO2 coupling reactions......Page 112
REFERENCES......Page 113
INTRODUCTION......Page 114
EXPERIMENTAL......Page 115
RESULTS......Page 116
DISCUSSION......Page 118
REFERENCES......Page 121
INTRODUCTION......Page 122
RESULTS AND DISCUSSION......Page 123
INTERPRETATIONS AND MODELS......Page 128
SUMMARY......Page 129
REFERENCES......Page 130
INTRODUCTION......Page 131
RESULTS AND DISCUSSION......Page 132
REFERENCES......Page 136
INTRODUCTION......Page 137
EXPERIMENTAL......Page 138
EXPERIMENTAL RESULTS......Page 139
DISCUSSION AND CONCLUSIONS......Page 142
ACKNOWLEDGEMENTS......Page 144
INTRODUCTION......Page 146
Transduction of redox energy into acid-base energy......Page 147
REDOX AND ACID-BASE CHARACTERIZATION OF CYTOCHROME b-559 IN THYLAKOIDS AND PS II PARTICLES......Page 148
MECHANISM OF ENERGY—COUPLING BY CYTOCHROME b-559......Page 149
REFERENCES......Page 152
INTRODUCTION......Page 153
RESULTS......Page 154
DISCUSSION......Page 157
REFERENCES......Page 158
INTRODUCTION......Page 160
RESULTS......Page 161
REFERENCES......Page 162
ABSTRACT......Page 165
INTRODUCTION......Page 166
ULTRASTRUCTURAL INVESTIGATIONS......Page 167
DETERGENT FRACTIONATION......Page 169
ACKNOWLEDGEMENTS......Page 174
REFERENCES......Page 175
ABSTRACT......Page 177
REFERENCES......Page 179
INTRODUCTION......Page 180
MATERIALS AND METHODS......Page 181
RESULTS AND DISCUSSION......Page 182
ACKNOWLEDGMENTS......Page 186
REFERENCES......Page 187
INTRODUCTION......Page 189
RESULTS AND DISCUSSION......Page 190
REFERENCES......Page 192
INTRODUCTION......Page 194
RESULTS AND DISCUSSION......Page 195
REFERENCES......Page 198
INTRODUCTION......Page 200
STRUCTURE OF THE HYDROGEN ACTIVATING SITE......Page 201
STABILITY VERSUS MOLECULAR OXYGEN......Page 202
ELECTRON TRANSFER PATHWAYS......Page 203
THE BIOSYNTHESIS OF HYDROGENASE HOLOENZYME......Page 204
REFERENCES......Page 205
List of Participants......Page 206