Organic C-Centered Radicals

General introduction....Pages 1-4
3.0 Introduction....Pages 5-6
H(CH2)nC.H2....Pages 7-15
RCH2CH2C.H2....Pages 15-21
RRCHCH2C.H2....Pages 21-22
RCH2C.H2....Pages 22-36
RCH(CH3)C.H2....Pages 37-39
RCHRC.H2....Pages 40-43
RC(CH3)2C.H2....Pages 43-44
RRC(CH3)C.H2....Pages 45-45
Part 1....Pages 46-56
Part 2....Pages 57-68
Part 3....Pages 69-80
RCH2C.HCH3....Pages 80-87
RRCHC.HCH3....Pages 87-89
RC.HCH3....Pages 89-104
RCH2C.HCH2R....Pages 104-109
RRCHC.HCH2R....Pages 109-111
Part 1....Pages 111-122
Part 2....Pages 123-145
RRCHC.HR....Pages 145-158
Part 1....Pages 159-168
Part 2....Pages 169-178
Part 1....Pages 179-186
Part 2....Pages 187-196
RCH2C.(CH3)R....Pages 196-204
RRCHC.(CH3)R....Pages 204-205
RC.(CH3)R....Pages 206-216
RCH2C.(R)CH2R....Pages 216-218
RCH2C.RR....Pages 218-230
RRCHC.RR....Pages 230-237
RC.RR....Pages 237-253
3.1.4.1 Alkyl radicals from three-membered rings....Pages 253-256
3.1.4.2 Alkyl radicals from four-membered rings....Pages 256-258
3.1.4.3 Alkyl radicals from five-membered rings....Pages 259-271
3.1.4.4.1 Homocyclic compounds....Pages 271-277
3.1.4.4.2 Radicals from pyrimidine bases and related compounds....Pages 277-289
3.1.4.4.3 Radicals from other heterocyclic compounds....Pages 289-293
3.1.4.5 Alkyl radicals from seven-, eight-, and nine-membered rings....Pages 294-295
3.1.5 Polycyclic alkyl radicals....Pages 295-303
3.2.1 Vinyl-type radicals....Pages 303-310
3.2.2 Aryl radicals....Pages 310-317
3.2.3 Acyl radicals....Pages 318-324
62Kou1 - 71Bir1....Pages 325-333
71Bir2 - 76Lis1....Pages 334-341
4.1 Introduction....Pages 342-344
4.2.1 Allyl and deuterated allyl radicals....Pages 345-346
4.2.2 Alkyl-substituted allyl radicals....Pages 346-353
4.2.3 Allyl radicals containing F, Cl, Br....Pages 354-357
4.2.4.1 Oxygen in alpha-position....Pages 358-367
4.2.4.2 Oxygen in beta-positions....Pages 367-375
4.2.4.3 Oxygen in gamma- and delta-positions....Pages 375-377
4.2.5 Allyl radicals containing S....Pages 377-380
4.2.6 Allyl radicals containing N and P....Pages 380-383
4.2.7 Allyl radicals containing Si, Ge, and Sn....Pages 383-387
4.2.9 Iminoallyl radicals....Pages 387-388
4.2.10 Phenyl- and aryl-substituted allyl radicals....Pages 389-400
4.2.11 Aza-allyl and phospha-allyl radicals....Pages 401-402
4.2.12 Semicyclic allyl radicals (isocyclic and heterocyclic)....Pages 402-404
4.2.13 Cyclopropenyl radicals....Pages 404-405
4.2.14 Isocyclic allyl radicals (cyclobutenyl, cyclopentenyl, ⋯)....Pages 405-414
4.2.15 Heterocyclic allyl radicals....Pages 414-426
4.2.16 Bicyclic and tricyclic allyl radicals....Pages 426-430
4.2.18 Allenyl (propargyl) radicals....Pages 430-434
4.3.1 Pentadienyl radicals....Pages 435-437
4.3.3 Semicyclic pentadienyl radicals....Pages 437-437
4.3.4 Cyclopentadienyl radicals....Pages 438-451
4.3.5 References to further papers concerning ESR studies on cyclopentadienyl radicals....Pages 451-451
4.3.6.1 Cyclohexadienyl radicals without substituents at C(1)....Pages 452-463
Part 1....Pages 463-475
Part 2....Pages 476-484
4.3.6.3 Cyclohexadienyl radicals with two substituents at C(1)....Pages 484-492
4.3.6.4 Aza-cyclohexadienyl radicals....Pages 492-494
4.3.7 References to further papers concerning ESR studies on cyclohexadienyl radicals....Pages 494-494
4.3.8 Pyryl radicals....Pages 495-505
4.3.10 Thiapyryl radicals....Pages 505-508
4.3.11.1 1-H-pyridinyl radicals....Pages 509-521
4.3.11.2 1-Alkyl-pyridinyl radicals....Pages 521-525
4.3.11.3 1-Trimethylsilyl- and 1-trichlorosilyl-pyridinyl radicals....Pages 525-529
4.3.11.4 1-Trimethylgermyl-pyridinyl radicals....Pages 529-530
4.3.11.5 Aza-pyridine radicals....Pages 530-531
4.3.13 Phosphorinyl radicals....Pages 531-535
4.4.1 Heptatrienyl radicals....Pages 535-536
4.4.2 Cycloheptatrienyl radicals....Pages 537-542
4.4.4.1 Benzyl radicals without substituents at the exo-cyclic carbon atom C(7)....Pages 543-551
4.4.4.2 Benzyl radicals with one substituent at C(7)....Pages 551-558
4.4.4.3.1 7,7-Dialkyl-benzyl radicals....Pages 558-563
4.4.4.3.2 7-Methylene-benzyl radicals....Pages 563-564
4.4.4.3.3 Benzyl radicals with halogens and halogen containing substituents at C(7)....Pages 564-565
4.4.4.3.4 Benzyl radicals with O and O containing substituents at C(7)....Pages 566-576
4.4.4.3.5 Benzyl radicals with S and S containing substituents at C(7)....Pages 576-580
4.4.4.3.6 Benzyl radicals with N containing substituents at C(7)....Pages 580-592
4.4.4.3.7 Benzyl radicals with Si containing substituents at C(7)....Pages 592-596
4.4.4.3.8 Benzyl radicals with Ge and Sn-containing substituents at C(7)....Pages 597-600
4.4.4.3.9 Benzyl radicals with Cr, Mo, W containing substituents at C(7)....Pages 600-601
4.4.5 Benzyl-type radicals containing heterocyclic 6 pi-electron ring systems....Pages 601-613
4.4.6 Bicyclic benzyl-type radicals derived from indanone and phthalide....Pages 613-615
4.4.7 References to further papers concerning ESR studies on benzyl radicals....Pages 615-615
4.5.2 Indenyl and related radicals....Pages 616-617
4.5.3 alpha-Hydronaphthyl and related radicals....Pages 617-620
4.5.4 Cyclohexadienyl-type radicals derived from indole and carbazole....Pages 620-621
4.5.5 beta-Hydronaphthyl and related radicals....Pages 621-622
4.5.6 Quinolinyl and related radicals....Pages 622-624
4.5.7 Cyclohexadienyl-type radicals derived from anthracene and phenanthrene and related to hydro-naphthyl....Pages 625-625
4.6 Radicals with 11 conjugated pi-electrons....Pages 626-627
4.7.1 Phenalenyl (perinaphthenyl) radicals....Pages 627-635
4.7.2.1 Diphenylmethyl radicals without substituents at the central carbon atom C(7)....Pages 635-639
4.7.2.2.1 7-Alkyl-diphenylmethyl radicals....Pages 639-641
4.7.2.2.2 7-Chloro-diphenylmethyl radicals....Pages 641-643
Part 1....Pages 643-651
Part 2....Pages 652-662
Diphenylmethyl radicals with other O containing substituents at C(7)....Pages 662-662
4.7.2.2.4 Diphenylmethyl radicals with S and S containing substituents at C(7)....Pages 663-666
4.7.2.2.5 Diphenylmethyl radicals with N containing substituents at C(7)....Pages 666-666
4.7.2.2.6 Diphenylmethyl radicals with P containing substituents at C(7)....Pages 667-668
4.7.2.2.7 Diphenylmethyl radicals with Si containing substituents at C(7)....Pages 668-671
4.7.2.2.8 Diphenylmethyl radicals with Ge, Sn, W containing substituents at C(7)....Pages 671-673
4.7.2.3 Phenylindanyl and related radicals....Pages 673-674
4.7.3 Fluorenyl radicals....Pages 674-688
4.7.4 Dibenzocyclohexadienyl and related radicals....Pages 689-690
4.7.5 Dibenzocycloheptatrienyl and related radicals....Pages 690-691
4.7.7 Xanthyl radicals....Pages 692-698
4.7.8 Thioxanthyl and related radicals....Pages 699-703
4.7.9 Selenoxanthyl and related radicals....Pages 703-704
4.7.10 Acridinyl and related radicals....Pages 704-705
4.7.12 Diphenylmethyl-type radicals containing heterocyclic 6 pi-electron ring systems....Pages 706-718
Part 1....Pages 718-728
Part 2....Pages 729-740
Part 3....Pages 741-750
4.8.2 9-Phenylfluorenyl radicals....Pages 751-753
4.8.3 9-Phenylxanthyl radicals....Pages 753-756
4.8.4 9-Naphthylxanthyl radicals....Pages 756-757
4.8.5 Dioxydehydrocoranthryl and sesquixanthydryl....Pages 757-757
4.8.6 9-Phenylthioxanthyl....Pages 758-759
4.8.7 9-Phenylselenoxanthyl....Pages 760-760
4.8.9 Triphenylmethyl-type radicals containing 5-membered ring systems especially thiophene....Pages 761-764
4.8.10 References to further papers concerning ESR studies on triphenylmethyl radicals....Pages 764-764
55Wer1 - 71Pau1....Pages 765-773
71Pon1 - 77Zie1....Pages 774-782